Chemistry Chapter 4-7

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Octet rule

each element must fullfill 8 valence electrons

Chemical Bond

force that holds together a compound

nonmetals (blank) electrons

gain, anion

Empirical Formula

give the relative number of atoms of each element in a compound

Molecular Formula

gives actual number of atoms of each element in a compound

Electron Groups

lone pairs, single bonds, multiple bonds, single electrons

metal (blank) electrions

lose, cation

Chemical Formula

shows the elements there, # of atoms for each, metallic element first

Lewis Model

shows valence electrons represented with dots

Calculating Empirical Formula

1) Convert % to grams ex) 24.5% of something- 24.5 grams 2)Convert mass(grams) to mols 3) Divide by smallest number of moles 4)Now multiply all mole rations by the smallest mole number

Formal Charge

A ficticious charge something would have if all bonding electrons were shared equally.

Dipole Moment

Anytime there is a separation of positive and negative charges

Nonpolar Bonds

Atoms with the same EN, share electrons equally

Atomic Mass

Average mass of an atom

Ionic bond

Bond between a metal and non metal, electrons are transfered

Covalent Bond

Bond between two or more nonmetals, electrons are shared, results in molecular compounds

Molecular Compound

Composed of two ore more nonmetals

(0-0.4) En

Covalent Bond

Common Unit used for dipole moments

Debye (D)

Calculating Molecular Formula

Empirical formula x n ex) CH2O= CnH2nOn n=molar mass/empirical molar mass

VESPR

Idea that electron groups repel one another through coulombic forces

(2.0+) En

Ionic Bond

Five basic arrangements of electron groups

Linear, Trigonal Planar, Tetrahedral, Bipyramidal, Octahedral

Calculating a Dipole Moment

Magnitude of Charge (Q) x Distance between the charges (d)

Formula Mass

Mass of all atoms in formula added together

Calculating Percent Ionic Character

Measure of dipole moment of bond/Dipole moment if electron were transfered ****100

Odd-Electron Species

Molecules or ions with an odd number of electrons

Incomplete Octets

Molecules or ions with fewer than eight electrons, mostly metalloids an H atoms

Expanded Octets

Molecules or ions with more than eight electrons

(0.4-2.0) En

Polar Covalent Bond

Resonance Structure

Same skeletal formula, but different electron arrangement

Electronegativity

The ability of an atom to attract bonding electrons to itself, the larger the difference in EN, the more polar the bond.

Bond Angles

The character angels in the shapes

Percent Ionic Character

The ratio of a bond's actual dipole moment to the dipole moment it would have if the electron were to be completely transfer from one atom to another

Calculating Molar Mass

The sum of the atomic masses ex)SO= 32+16

Calculating Percent Composition

Used to find how much in % of an atom there is in a compound (n)x molar mass of element//// molar mass of compound

Structural formula

Uses lines to represent covalent bonds and molecular geometry.

Resonance

When two or more valid Lewis Structures can be drawn for the same compound

Lewis Structure: Lone Pair

a pair only associated with one atom and not bonding

Lewis Structure: Bonding Pair

a shared pair of electrons


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