Chapter 4 Chemistry Review

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What are the possible values for the spin quantum number?

+1/2 or -1/2

Determine the highest occupied energy level of He.

1

How many orbital orientations are possible for sublevel s?

1

For the following values of n, indicate the numbers and types of sublevels possible for taht main energy level 1) n=1 2) n=2 3) n=3 4) n=4 5) n=7

1) 1; s 2) 2; s, p 3) 3; s, p, d 4) 4; s, p, d, f 5) 7

How many electrons could be contained in energy level 3?

18

Determine the highest occupied energy level of Be.

2

How many electrons could be contained in energy level 1?

2

How does n relate to the number of electrons allowed per main energy level?

2n^2

Determine the highest occupied energy level of Al.

3

How many orbital orientations are possible for sublevel p?

3

What is the speed of all forms of electromagnetic radiation in a vacuum?

3.00 x 10^8 m/s Or 3 x 10^10 cm/s

How many electrons could be contained in energy level 4?

32

What is an orbital?

3D region around the nucleus that indicated the highest probable location of an electron

How many total orbitals are contained in the third main energy level?

3^2=9

Determine the highest occupied energy level of Ca.

4

What frequency range of visible light?

4.29x10^14 to 7.5x10^14 Hz

What is the wavelength range of visible light?

400 to 700 nm

Determine the highest occupied energy level of Sn.

5

How many orbital orientations are possible for sublevel d?

5

How many total orbitals are contained in the fifth main energy level?

5^2=25

How many orbital orientations are possible for sublevel f?

7

How many electrons could be contained in energy level 6?

72

How many electrons could be contained in energy level 7?

98

What is the electromagnetic spectrum?

A combination of all equerries or wavelengths of electromagnetic radiation arranged according to increasing wavelength

What are sublevels?

A division of principle energy levels

What are inner-shell electrons?

All the electrons not in principle quantum number

Describe the major similarities and differences between Schrödinger's model of the atom and the model proposed by Bohr.

Bohr estimated where the atom was and you can't do that

What types of compounds are used to provide color in fireworks?

Chloride salts

What is the basis of Hund's rule?

Electron repulsion

What analytical technique utilizes the emission of light from excited atoms?

Flame test

What are the noble gases?

Group 18 or 8

What is meant by the highest occupied energy level of an atom?

Highest principle quantum number

What units are used to express frequencies of electromagnetic waves?

Hz

State Hund's rule.

If the sublevel has equal energy, it is occupied by one electron before any orbital is occupied by a second electron

What is the principle quantum number?

Indicates the main energy level

How are energy and wavelength of electromagnetic radiation related?

Indirectly proportionate (E=hc/upside down y)

How are wavelength and frequency of electromagnetic radiation related?

Inversely proportionate (c=upside down y x fancy v)

What information is given by the noble-gas notation [Ne]3s^2?

It accounts for the 10 e- and the rest are in the 3rd energy level

What element is represented by [Ne]3s^2?

Magnesium

Which travels at a greater speed: ultraviolet light or infrared light?

Neither! It's the same speed!! Hahaha gotcha

State the Pauli exclusion principle.

No two electrons in the same atom can have four quantum numbers

What are shells?

Orbitals within the main energy level

What information is given by the magnetic quantum number?

Orientation around the axis

Which theory of light (the wave theory or the particle theory) best explains the emission of electromagnetic radiation by an excited atom?

Particle theory

Which theory of light (the wave theory or the particle theory) best explains the photoelectric effect?

Particle theory

How does noble-gas notation simplify writing an atom's electron configuration?

Preceding noble gas takes care of everything before it

What are the colors of light in the visible spectrum in order of increasing frequency?

Red, orange, yellow, green, blue, violet

What information is given by the angular momentum quantum number?

Shape of orbital

Explain the meaning of Aufbau principle in terms of an atom with many electrons.

Start at the lowest energy level and fill up from there

What is noble-gas configuration?

Taking the preceding noble gas and start from there with electron configuration

What information is given by the spin quantum number?

Tells which way it spins (clockwise or counter clockwise)

State the Aufbau principle.

The lowest energy level that can accept the electron is where it stays

Describe an orbital in terms of an electron cloud.

The orbitals are swirling around the nucleus like bees around a hive

How do a 2px and a 2py orbital differ?

They are at right angles to each other

How do the electron configurations of chromium and copper contradict the Aufbau principle?

They're called irregular atoms and don't fill up outer shell first as predicted

List 5 examples if electrinagnetic radiation.

Visible light, x-rays, ultra violet, infared, and radio

Which theory of light (the wave theory or the particle theory) best explains the interference of light?

Wave theory

How are the energy and frequency of electromagnetic radiation related?

When frequency increases, energy increases (E=h x fancy v)

Which has a higher frequency: an X ray or a microwave?

X ray

Which has a longer wavelength: yellow light or green light?

Yellow

What is the significance of the spin quantum number?

You can have 2 as long as they spin different ways

What units are used to express wavelength?

m, cm, nm, dm

How is the principle quantum number symbolized?

n

What is the relationship between n and the total number of orbitals in a main energy level?

n^2


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