Chem Chp 1-3

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electron configuration with charges

- (+) minus - (-) add

how to determine amount of protons, neutrons and electrons of an isotope ex 133^Cs

- 133 = mass number - Cs has atomic # of 55 > 55 protons and 55 electrons - 133 = 55 + x to find 78 neutrons

what orbtal electron config is not possible

4p^7

How many electrons are shared between two atoms in a triple bond?

6 electrons. Two electrons shared between two atoms in an individual bond, therefore triple bond 2 × 3 = 6 electrons are shared.

what is a physical change

A change in the state/property of matter w/o any accompanying change in chemical identities ex: water is boiled in a microwave

The first five ionization energies of an element are as follows (in kJ/mol): 577.9, 1820, 2750, 11600, 14800. Which of the following elements is most likely to have these ionization energy values?

Al - large increase in ionization energies from third to fourth ionization suggests relatively easy to remove three electrons.

Write the chemical formula for the carbonate ion

CO₃²⁻

___ Acid needs what in the front of the formula

H

Write the chemical formula for hydrobromic acid

HBr

Write the chemical formula for acetic acid

HC₂H₃O₂

Write the chemical formula for mercury(I) sulfide

Hg₂S

Write the chemical formula for oxalic acid

H₂C₂O₄

Write the chemical formula for sulfuric acid

H₂SO₄

write chemical formula for hydroxide ion

OH-

converting celcius into kelvin

add 273.15

determining mass number for an atom

add protons and neutrons together

matter

anything that takes up space and has mass - solid = fixed shape and vl - liquid = shape of container, forms horizontal surface, has fixed vl - gas = expands to fill container

when given protons and electrons, indentify element (39 p and 36 e)

atomic number is 39 and contains 39 protons but (+3) charge is subtracted

why is n = 0, l = 1, m(l) = 0, and m(s) = +½ not possible

cause n can never = 0 - 1, 2, 3...

chemical property

change of 1 type of matter into another (or ability to change types of matter) - ex: Ne gas prop: it is inert (can not be measured w/o chemically changing substance)

Ionic

composed of a metal and nonmetal - SrCl2

Polyatomic ions

composed of multiple covalently bonded atoms - ex: NaOH - ex: MgCO3

molecular

composed of two or more nonmetals - P205

significant figures

counts if non-zero, 0 between sig digits and 0s following a sig digit in a decimal - does not: trailing (unless decimal) or leading

trend for ionization energy

decreases down a group and increases left to right across a period

What is the correct IUPAC name for S₂F₈?

disulfur octafluride

ion

elctron and proton count are not equal - equal # makes it a neutral atom

determining partial positive charge

element further to the left - negative closer to the right

add or subtract sig figs

fewest number of decimal places in answer

plasma

gaseous state of matter w/electrically charged particles

what is the correct IUPAC name for HIO₃(aq)?

iodic acid

which is the lowest temp: kelvin, c or f

kelvin

What is the correct IUPAC name for Li₂S?

lithium sulfide

how to determine ion of an element

look at group (ex group 15) and see how many more till noble gases (-3) - for group 1+2 it is a positive number

converting celsius to farenheit

multi by 9/5 and then add 32

A single electron in an orbital has quantum numbers n = 3, ℓ = 0, mℓ = 0, ms =-½. What are the quantum numbers for the next electron added to this orbital

n = 3, ℓ = 0, mℓ = 0, ms = +½

What is the correct IUPAC name for HNO₂(aq)?

nitrous acid

Pauli Exclsuion Principle

no two electrons in a given atom can share the same set of four quantum numbers (n, ℓ, mℓ, ms)

Trend for atomic radius

radius decreases moving left to right across a period and increase down a group

microscopic

size scale so small we cannot sense or percept directly - molecules, atoms, bacteria

symbolic domain

specialized language used to represent components of micro and macro domain - g, s, l

law

statement about an observed phenomeon or unifying concept - not an explanation > statement

What is the correct IUPAC name for H₂SO₃(aq)

sulfurous acid

hypothetis

tentative explanation of observations that guide future experiments - must be testable

as the atomic radii decreases from left to right in a period

the nuvlear charge increases in that direction

why does the atomic mass of Ge a fracion between 72 and 73

the presence of different isotopes - atomic mass rep the abundance of each isotope

macroscopic domain

things observed by senses

Which of the following best describes what happens when an ionic bond forms?

two atoms, one atom which is more electronegative than the other, exchange electrons and the charges hold the atoms together.

covalent compounds

two nonmetals - ex: NO2

Single, double, or triple covalent bonds in a carbon atom are formed from

valence electrons

theory

well est comprehensive and testable explanation - always subject to change if new evidence suggests


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