Chem Exam 3

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The oxidizing agent in a redox reaction is itself

reduced

gain of electrons

reduced

In Cl2(g) + 2NaBr(aq) -> Br2(aq) + 2NaCl(aq) Br

reduced; oxidizing agent

In S(s) + O2(g) -> SO2(g) sulfur

reducing agent

The substance that causes the reduction is

reducing agent

in equilibrium expression, square brackets

refer to molar concentrations

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 0.92%(m/v) NaCl solution

remain unaffected

in a solution, solutes

remain uniformly distributed & will not settle out w time

When 60.0 mL of a 1.00 M solution is diluted by adding 30.0 mL of water, the amount of solute present

remains the same

conjugate base is the species that

remains when proton is removed from Bronsted-lowry acid

displacement reaction aka

replacement reaction

in HA(aq) + H2O(l) <=> H3O+(aq) + A-(aq) A (in HA)

represents any acid

Breaking the bonds of the reactants

requires energy; bond formation releases energy

Predict the solubility of each of the following solutes in the solvent indicated. Na2SO4 (an ionic solid) in water

soluble

Predict the solubility of each of the following solutes in the solvent indicated. ethyl alcohol (a polar liquid) in chloroform (a polar liquid)

soluble

Predict whether the following compound is soluble or insoluble in water: CuBr2

soluble

Predict whether the following compound is soluble or insoluble in water: NH4Br

soluble

C6H6(g) + 3H2(g) -> C6H12(g) + heat Indicate if the following will shift the equilibrium to the right or left. Also indicate if the changes will change the value of Keq. Increasing the concentration of H2

right; no

C6H6(g) + 3H2(g) -> C6H12(g) + heat Indicate if the following will shift the equilibrium to the right or left. Also indicate if the changes will change the value of Keq. Increasing the pressure

right; no

Identify the solute in: salt (NaCl) in water

salt

KCl is an example of

salt

NH4Br is an example of

salt

Na2SO4 is an example of

salt

NaCl is an example of

salt

Indicate whether the osmotic pressure of a 0.1 M NaCl solution will be less than, the same as, or greater than that of each of the following solutions. 0.1 M NaBr

same

ALPHA PARTICLE

same as helium nucleus w no electrons

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 0.28 M glucose

same size

Will red blood cells swell, remain the same size, or shrink when placed in 0.14 M in both glucose and sucrose

same size

Will red blood cells swell, remain the same size, or shrink when placed in 0.28 M glucose

same size

Will red blood cells swell, remain the same size, or shrink when placed in 0.92%(m/v) NaCl solution

same size

Predict whether the following compound is soluble or insoluble in water: Pb(NO3)2

soluble

Classify each of the following solutions as saturated, unsaturated, or supersaturated based on the following observations. excess undissolved solute is present at the bottom of the solution container.

saturated

Classify each of the following solutions as saturated, unsaturated, or supersaturated based on the following observations. heating the solution causes excess undissolved solute present to dissolve.

saturated

Using Table 8-2, classify each of the following types of ionic compounds using the solubility categories soluble, soluble with exceptions, insoluble, or insoluble with exceptions. nitrates

soluble

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. Cu(NO3)2

soluble

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. CuCl2

soluble

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. CuSO4

soluble

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. ammonium phosphate

soluble

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. calcium nitrate

soluble

A compound has a solubility in water of 35 g/L at 0°C. If 25 g of this compound is added to 0.5 L of water at 0°C, is the resulting solution saturated or unsaturated?

saturated solution

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. sodium phosphate

soluble

Zn(NO3)2 is a

soluble ionic compound

Using Table 8-2, classify each of the following types of ionic compounds using the solubility categories soluble, soluble with exceptions, insoluble, or insoluble with exceptions. chlorides

soluble with exceptions

In the common case of solid-in-liquid solutions in which

solute is ionic compound, "like dissolves like" is not adequate.

Dialysis is the movement of

solutes across semipermeable membrane

When a substance produces charged particles when dissolved in water

solution conducts electricity & substance is classified as electrolyte

A solution is made by dissolving 34.0 g of NaCl in 100 g of H2O at 0°C. Based on the data in Table 8-1, should this solution be characterized as saturated or unsaturated

unsaturated

Classify each of the following solutions as saturated, unsaturated, or supersaturated based on the following observations. The amount of solute dissolved is less than the maximum amount that could dissolve under the conditions at which the solution exists.

unsaturated

supersaturated solution

unstable solution that temporarily contains more dissolved solute than that present in saturated solution

Almost all radionuclides

used in nuclear medicine are synthetic radionuclides.

the more acidic you are, pKa

value goes down

If the temperature changes,

value of Keq also changes

For CO(g) + 2H2(g) <- ——> CH3OH(g) At this new equilibrium state,

value of [H2] will be lower bc more has reacted w added CO & value of [CH3OH] will be higher

Adding a nonvolatile solute to a pure solvent produces which of the following effects? a. vapor-pressure lowering b. freezing-point elevation c. boiling-point depression d. no correct response

vapor-pressure lowering

Solution has

variable composition

Predict whether the following solutes are very soluble or slightly soluble in water. CH3OH (a polar liquid)

very soluble

%(v/v)

volume of solute/volume of solution x 100

Ionizing radiation is radiation

w sufficient energy to remove electron from atom or molecule.

Identify the solute in: a solution containing 50.0 mL of methanol and 30.0 mL of water

water

Identify the solvent in: CO2(g) in water

water

Identify the solvent in: a solution containing 10.0 g of LiBr and 100.0 g of water

water

Identify the solvent in: a solution containing 3.0 g of AgNO3 and 15 mL of water

water

Identify the solvent in: a solution of 3.0 x 10^1% ethanol and 7.0 x 10^1% water

water

Identify the solvent in: salt (NaCl) in water

water

For each solute, identify the better solvent: water or carbon tetrachloride CH2O

water (H2O)

For each solute, identify the better solvent: water or carbon tetrachloride CaCl2

water (H2O)

With Osmosis,

water always moves in direction to dilute things

when red blood cells are placed in physiological saline solution, a 0.92%(m/v) sodium chloride solution,

water flow is balanced [neither hemolysis nor crenation occurs]

When salt water is taken into the stomach,

water flows out of stomach wall membranes & into stomach; [tissues become dehydrated]

Osmosis is the process in which

water flows through semipermeable membrane (ex: cell membrane) from lower concentration of ions to higher concentration of ions

Why is O2 soluble in water?

water has a dipole; oxygen has only london forces [so oxygen is just a little soluble in water]

Why does the use of a salt solution in Kimchi act as a preservative against bacterial decay?

water passes into salt solution, dehydrating bacterial cells and making them harmless

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other CH3COOH

weak acid

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other HCN

weak acid

a small percentage of its protons are transferred to water

weak acid

Combo for good buffer is

weak acid & equal amount of its conjugate base

Buffer solutions contain either

weak acid & salt of that weak acid or weak base & salt of that weak base.

HF is a

weak acid but will kill you bc yanks calcium out of you

Buffers are composed of a __________ and its ____________.

weak acid, conjugate base

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other (CH3)3N

weak base

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other NH3

weak base

Classify these compounds as strong electrolytes, weak electrolytes or nonelectrolytes H2CO3

weak electrolyte

HF(aq) <=> H^+(aq) + F^-(aq)

weak electrolyte

You get conjugate acid/base

when dissolve acid/base in water

A special group of physical properties that change

when solute is added are colligative properties.

The value of the equilibrium constant tells us

whether have mostly reactants or mostly products or nearly equal amount of each.

Value of Ka tells you

whether or not comes apart when put in water

you have to be told

whether reaction releases gamma ray [can't predict]

The concentrations of pure liquids and pure solids,

which are constants, are never included in equilibrium expression.

in 238U92 -> 4He2 + 234Th90

written same as 12C6 [atomic number on bottom]

Does the following ion form a compound with Pb2+ that is soluble in water? C2H3O2^-

yes

Does the following ion form a compound with Pb2+ that is soluble in water? NO3^-

yes

Identify whether or not the following set contains an acid-base conjugate pair HNO2 and NO2^-

yes

Identify whether or not the following set contains an acid-base conjugate pair HS^- and H2S

yes

Identify whether or not the following set contains an acid-base conjugate pair NH3 and NH4^+

yes

Indicate whether or not each of the following chemical reactions represents a combustion reaction. ( 4Fe + 3O2 -> 2Fe2O3

yes

Indicate whether or not each of the following chemical reactions represents a combustion reaction. ( 4NH3 +3O2 -> 2N2 +6H2O

yes

Indicate whether or not each of the following chemical reactions represents a combustion reaction. ( C2H6O + 3O2 -> 2CO2 + 3H2O

yes

Indicate whether or not product formation increases if the size of the reaction container is increased for each of the equilibrium systems in 2KClO3(s) + heat <=> 2KCl(s) + 3O2(g)

yes

Indicate whether or not product formation increases w increasing temperature in each of the following equilibrium systems 2KClO3(s) + heat <=> 2KCl(s) + 3O2(g)

yes

Indicate whether or not product formation increases w increasing temperature in each of the following equilibrium systems N2(g) + 2O2(g) + heat <=> 2NO2(g)

yes

Indicate whether or not product formation increases w increasing temperature in each of the following equilibrium systems heat + 2N2(g) + 6H2O(g) <=> 4NH3(g) + 3O2(g)

yes

Indicate whether or not the two members of each of the following pairs of compounds have like solubility (both soluble or both insoluble). CaCO3 and Ca3(PO4)2

yes

Indicate whether or not the two members of each of the following pairs of compounds have like solubility (both soluble or both insoluble). KNO3 and K2SO4

yes

Indicate whether or not the two members of each of the following pairs of compounds have like solubility (both soluble or both insoluble). NH4Cl and NH4Br

yes

Indicate whether or not the two members of each of the following pairs of compounds have like solubility (both soluble or both insoluble). Ni(OH)2 and Ni3(PO4)2

yes

Will the following combination make a buffer solution? H2CO3 and NaHCO3

yes

Will the following combination make a buffer solution? HC2H3O2 and KC2H3O2

yes

Will the following increase the rate of reaction? increasing the concentration of a reactant

yes

if you remove H,

you remove its positive charge

if you get more oxygen,

you're oxidized

If you lose oxygens,

you're reduced

in Cl2(g) + 2NaBr(aq) -> Br2(aq) + 2NaCl(aq) what is the charge of Br2 (on the product side)

zero bc bromine is in elementary state [not an ion]

What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular compound) to the following amounts of water? 500 g (0.500 kg)

-3.7 degrees celsius

What is the freezing point of the solution 3.00 moles of glucose (a molecular compound)

-5.58 degrees celsius

What is the freezing point of the solution 3.00 moles of lactose (a molecular compound)

-5.58 degrees celsius

What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular compound) to the following amounts of water? 250 g (0.25 kg)

-7.4 degrees celsius

What is the oxidation number of S in each of the following molecules? S8

0

pH ranges between

0 to 14 in aqueous solutions at 24°C.

The concentration of bilirubin in a blood sample is found to be 0.55 mg/dL. express this concentration in the following units: g/100 mL

0.00055 g/100 mL

The concentration of bilirubin in a blood sample is found to be 0.55 mg/dL. express this concentration in the following units: mass-volume percent

0.00055% (m/v)

What is the molarity of the solution prepared by diluting 25.0 mL of 0.220 M NaCl to each of the following final volumes? 2.00 L

0.00275 M

The concentration of bilirubin in a blood sample is found to be 0.55 mg/dL. express this concentration in the following units: g/L

0.0055 g/L

For each of the following NaOh solutions, the volume of the solution and its molarity are given. Calculate the number of moles of NaOh present in each solution. 125 mL solution, 0.125 M

0.0156 moles

In a sulfuric acid (h2SO4)-sodium hydroxide (NaOh) acid-base titration, 17.3 mL of 0.126 M NaOh is needed to neutralize 25.0 mL of h2SO4 of unknown concentration. Find the molarity of the h2SO4 solution, given that the neutralization reaction that occurs is H2SO4(aq) +2NaOH(aq) -> Na2SO4(aq) + 2H2O(l)

0.0436 mol/L

How many moles of NaCl are present in 225 mL of a 0.355 M NaCl solution?

0.0799 moles

If 200.0 mL of a 0.40 M NaCl solution is diluted with water to form 800.0 mL of solution, the molarity of the new solution is

0.10 M

What has a higher solute concentration between 0.10 M glucose and 0.07 M glucose solution?

0.10 M glucose

The hCl in a 0.10 M hCl solution is 100% dissociated. What are the molar concentrations of hCl, h3O+, and Cl− in the solution?

0.10 M in both H3O^+ and Cl^- ions and zero in HCl

The number of grams of NaCl present in 10.0 g of a 1.00 %(m/m) NaCl solution is

0.100 g

Which of the following solutions is isotonic with respect to red blood cells? a. 0.20 M lactose b. 0.28 M lactose c. 0.35 M lactose d. no correct response

0.28 M lactose

What is the molarity of 0.500 L of NaOH solution if it contains 6.00 g of NaOH?

0.300 M

Normal saline solution that is used to dissolve drugs for intravenous use is 0.92%(m/v) NaCl in water. how many grams of NaCl are required to prepare 35.0 mL of normal saline solution?

0.32 g NaCl

Determine the molarities of the following solutions. 20.0 g of NaOH are dissolved in enough water to give 1.50 L of solution.

0.333 mole NaOH/L solution

A solution contains 0.23 mole of sulfate ion (SO4^2−). how many equivalents of SO4^2− ion are present in the solution?

0.46 Eq SO4^2-

The concentration of bilirubin in a blood sample is found to be 0.55 mg/dL. express this concentration in the following units: mg/100 mL

0.55 mg/100 mL

Calculate the mass, in grams, of K2SO4 needed to prepare 32.00 g of 2.000%(m/m) K2SO4 solution.

0.6400 g

How many moles of KCl are present in 355 mL of a 2.50 M KCl solution?

0.888 moles

For each of the following hCl solutions, the moles or grams of solute present and the total solution volume are given. Calculate the molarity of each solution. 30.0 g HCl, 875 mL solution

0.940 M

For each of the following hCl solutions, the moles or grams of solute present and the total solution volume are given. Calculate the molarity of each solution. 1.40 moles HCl, 1.45 L solution

0.966 M

For each of the following hCl solutions, the moles or grams of solute present and the total solution volume are given. Calculate the molarity of each solution. 0.850 mole hCl, 0.867 L solution

0.980 M

The results of dissolving these solutes in water are: NaCl

1 mole of NaCl produces 2 moles of particles [ions] bc soluble ionic solutes dissociate into ions

The results of dissolving these solutes in water are: glucose [molecular solute]

1 mole of glucose produces 1 mole of particles [molecules] bc molecular solutes remain in molecular form in solution

For ions with a charge of 2 (plus or minus) the mole-equivalent relationship is

1 mole of ion = 2 equivalents of ion

Monoprotic acids supply

1 proton [H+ ion] during acid- base reaction

For a complete neutralization reaction between 0.10 M Ca(OH)2 and 0.10 M HNO3, the base and the acid will react in which of the following molar ratios?

1 to 2

Major types of chemical reactions:

1) Combination 2) Decomposition 3) Displacement 4) Exchange 5) Combustion

Sources of Background Radiation

1) Cosmic radiation 2) Rocks/soil & minerals in body 3) Food & drink 4) Radon seepage in buildings [55%]

Ways to recognize redox reactions?

1) Gain or loss of oxygen 2) Gain or loss of electrons

Identify the conjugate acid-base pairs associated with the following acid-base reaction. HC2H3O2 + H2O -> H3O+ + C2H3O2−

1) HC2H3O2 and C2H3O2^- 2) H2O and H3O^+

HCN + NH2^- <=> CN^- + NH3 Name the conjugate pairs

1) HCN and CN^- 2) NH2^- and NH3

What are the commonly encountered strong acids?

1) HCl 2) HBr 3) HI 4) HNO3 5) HClO3 6) HClO4 7) H2SO4

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) what are the 2 conjugate acid-base pairs related by the loss/gain of H^+

1) HF and F^- 2) H3O^+ and H2O

Theraputic criteria are

1) Hi energy 2) Short duration 3) Internal or external

Diagnostic examples

1) Identification [infection/tumor] 2) Function [heart/thyroid]

Tell me the factors that increase chemical reaction rate

1) Increase in State of Subdivision 2) Increase in Reactant Concentration 3) Increase in temp 4) addition of catalyst

What are the group IA strong hydroxide bases?

1) LiOH 2) NaOH 3) KOH 4) RbOH 5) CsOH

What are the commonly encountered strong hydroxide bases?

1) LiOH 2) NaOH 3) KOH 4) RbOH 5) CsOH 6) Ca(OH)2 7) Sr(OH)2 8) Ba(OH)2

What are the 3 different ways to represent percent concentration?

1) Percent by mass 2) Percent by volume 3) Mass-volume percent

2 methods of expressing concentration:

1) Percent concentration 2) Molarity

Tell me the 4 factors that affect reaction rate

1) Physical nature of reactants 2) Reactant concentrations 3) Reaction temp 4) Presence of catalysts

Name some salts

1) Sodium chloride [table salt] 2) Sodium bicarbonate [baking soda]

Name some colligative properties

1) Vapor-pressure lowering 2) Boiling-point elevation 3) Freezing-point depression 4) Osmotic pressure

How can you tell if a redox reaction is occurring?

1) When ions are involved, determine if there is change in charges 2) For reactions w metals & nonmetals, predict gain or loss of electrons

Types of radioactive emissions

1) alpha (α) particle 2) beta (β) particle 3) gamma (γ) ray

What are the three central concepts associated with collision theory?

1) collision orientation 2) activation energy 3) molecular collisions

examples of ionizing radiation

1) cosmic rays 2) X rays 3) UV light

Detection of radiation

1) film badges 2) geiger counters

What controls how fast a reaction goes?

1) physical reaction [s, l, g] 2) high concentration reacts faster 3) high temp reacts faster

Examples of non-ionizing radiation

1) radiowaves 2) microwaves 3) infrared light 4) visible light

List the four major sources of low-level exposure to background radiation for an average American.

1) radon seepage 2) cosmic radiation 3) rocks & minerals 4) food & drink

Components of a solution

1) solvent 2) solute

What are the factors affecting the rate of solution formation?

1) state of subdivision of solute 2) degree of agitation during solution preparation 3) temp of solution components

how do nuclear equations differ from chemical equations?

1) symbols in nuclear equations stand for nuclei rather than atoms. 2) Mass numbers & atomic numbers [nuclear charge] are always specifically included in nuclear equations 3) elemental symbols on both sides of equation frequently are not same in nuclear equations.

Consider the solution of NaOH made by dissolving 100.0 g of solute in 250.0 mL of solution. Calculate the molarity.

10.00 M

Give me a conversion factor for the percent concentration 25%(m/v) sucrose solution

100mL solution/25g sucrose

What is the boiling point of a solution that contains 1.00 kg of water and each of the following quantities of solute? 3.00 moles of glucose (a molecular compound)

101.53 degrees celsius

What is the boiling point of a solution that contains 1.00 kg of water and each of the following quantities of solute? 3.00 moles of lactose (a molecular compound)

101.53 degrees celsius

how many grams of glucose must be added to 275 g of water in order to prepare each of the following percent- by-mass concentrations of aqueous glucose solution? 31.0%

124 g

how many grams of glucose must be added to 275 g of water in order to prepare each of the following percent- by-mass concentrations of aqueous glucose solution? 5.00%

14.5 g

For each of the following solutions, how many milliliters of water should be added to yield a solution that has a concentration of 0.100 M? 50.0 mL of 3.00 M NaCl

1450 mL

"there are 15g of NaCl in 100g of solution"

15 is measured; 100 is not [so 2 sig figs]

how many meq of hCO3− are present in a solution that also contains 75 meq of Na+, 83 meq K+, 10 meq Ca2+, and 153 meq Cl−?

15 mEq

Calculate the mass-volume percent of MgCl2 in each of the following solutions. 85 g of MgCl2 in enough water to give 580 mL of solution

15% (m/v)

A solution is prepared by adding 15.0 g C6H12O6 to 75.0 g H2O. What is the mass percentage of C6H12O6 in this solution?

16.7%

Calculate the number of grams of NaOH needed to prepare each of the following amounts of solution. 2.00 L of 2.00 M NaOH

160. g

115 g of CaCl2 are needed to make 276.4 g of a solution that is 41.5% calcium chloride in water. How many grams of water are needed to make this solution?

161 g H2O

State the composition of an alpha particle in terms of protons and neutrons.

2 protons & 2 neutrons

What is the ratio of the osmotic pressures of 0.30 M NaCl and 0.10 M CaCl2?

2 to 1

Which member of each of the following pairs of compounds has the higher boiling point? 1.0 M KBr or 2.0 M KBr

2.0 M KBr

Calculate the mass-volume percent of MgCl2 in each of the following solutions. 5.0 g of MgCl2 in enough water to give 250 mL of solution

2.0% (m/v)

Calculate the number of grams of NaOH needed to prepare each of the following amounts of solution. 0.100 L of 0.50 M NaOH

2.00 g

After all of the water is evaporated from 10.0 mL of a CsCl solution, 3.75 g of solid CsCl remains. Calculate the original concentration of the CsCl solution in the following units. molarity

2.23 M

Calculate the ph for each of the following solutions. [H3O+] = 5.70 × 10^−3

2.244

25.0 g of C2H4O2 are added to enough water to produce 175.0 mL of solution. What is the molarity of this solution?

2.38 M

For each of the following aqueous NaCl solutions, the mass of solute and the mass of solvent present are given. Calculate the mass percent of NaCl present in each solution. 520.0 mg NaCl, 2.00 g H2O

20.6% (m/m)

If 100.0 mL of 8.0 M NaCl solution is diluted with water to form a 4.0 M solution, what is the volume, in mL, of the new solution?

200.0 mL

Approximately how many laboratory-produced radionuclides are known?

2000

For the reversible reaction: A(g) <=> B(g) which K values would indicate that there is more B than A at equilibrium? A) K = 5 x 10^-5 B) K = 0.4 C) K = 2000 D) K = 1 x 10^9

2000 & 1 x 10^9

Which of the following is the daughter nuclide for the alpha decay of 212Po84

208Pb82

A typical dose of iron(II) sulfate (FeSO4) used in the treatment of iron-deficiency anemia is 0.35 g. how many milliliters of a 0.10 M iron(II) sulfate solution would be needed to supply this dose?

23 mL solution

How many grams of sucrose are needed to make 775 mL of a 30.0% (w/v) sucrose solution?

233 g sucrose

Isopropyl alcohol is mixed with water to produce a 33.0% (v/v) alcohol solution. How many milliliters of each component are present in 705 mL of this solution?

233 mL alcohol & 472 mL water

Beta Particle Decay (β):

234Th90 -> 234Pa91 + 0e-1

Alpha particle decay (α)

238U92 -> 4He2 + 234Th90

Gamma Ray Emission (γ):

238U92 -> 4He2 + 234Th90 + 2 0Y0

For the reaction H2(g) + I2(g) -> 2HI(g) The equilibrium concentrations at 25°C are [H2] = 0.0510 mol/L, [I2] = 0.174 mol/L and [HI] = 0.507 mol/L. Use the equilibrium expression to determine the value of Keq at 25°C.

29.0

Consider the following equilibrium system. N2(g) + O2(g) <=> 2NO(g) Write the chemical equation for the reverse reaction.

2NO(g) -> N2(g) + O2(g)

Determine the final concentration of each of the following solutions after 20.0 mL of water has been added. 30.0 mL of 5.0 M AgNO3 solution

3.0 M

Determine the final concentration of each of the following solutions after 20.0 mL of water has been added. 30.0 mL of 5.0 M NaCl solution

3.0 M

What is the final concentration when 0.50 L of 6.0 M HCl stock solution is diluted to a final volume of 1.0 L?

3.0 M

The ph of a solution with [h3O+] = 2.2 × 10^−4 is between

3.0 and 4.0

If you have a 0.150 M solution of Na2SO4 what is the concentration of Na^+ ions?

3.00 x 10^-1 moles Na^+

A solution is prepared by dissolving 10.0 grams of glucose in enough water to give 325 mL of solution. What is the mass-volume percent concentration of glucose in the solution?

3.08% (m/v)

How many milliliters of 11.0 M HCl(aq) are needed to prepare 345.0 mL of 1.00 M HCl(aq)?

3.14 x 10^1 mL

Calculate the pKa for HF given that the Ka for this acid is 6.8 × 10^-4

3.2

If pH = 4.50 then [H3O+] =

3.2 x 10^-5

How many moles of NaOH are present in 27.5 mL of 0.120 M NaOH?

3.30 x 10^-3 mol

For each of the following aqueous NaCl solutions, the mass of solute and the mass of solvent present are given. Calculate the mass percent of NaCl present in each solution. 20.0 g NaCl, 565.0 g H2O

3.42% (m/m)

What is the pH of a solution with a [H+] of 3.2 x 10 - 4 M.

3.49

how many grams of glucose must be added to 275 g of water in order to prepare each of the following percent- by-mass concentrations of aqueous glucose solution? 1.30%

3.62 g

If 1.50 gram of a 2.00-gram sample of a radioactive substance undergoes decay in 60 minutes, then the half-life of the sample is

30 minutes

For each of the following pairs of solutions, select the solution for which solute solubility is greatest. Table salt in water with P = 1 atm and T = 60°C Table salt in water with P = 1 atm and T = 50°C

60 degrees celsius

how many grams of glucose must be added to 275 g of water in order to prepare each of the following percent- by-mass concentrations of aqueous glucose solution? 20.0%

68.8 g

Give me a conversion factor for the percent concentration 6%(v/v) methanol solution

6mL methanol/100mL solution

How many strong acids are there?

7 [three Halo & 4 others]

how many liters of a 0.100 M solution can be prepared from 60.0 g of each of the following solutes? NaNO3

7.06 L

Calculate the mass percent of solute in the following solutions. 6.50 g of NaCl dissolved in 85.0 g of H2O

7.10% (m/m)

Calculate the ph for each of the following solutions. [H3O+] = 7.23 × 10^−8

7.141

Calculate the number of grams of NaOH needed to prepare each of the following amounts of solution. 552 mL of 0.333 M NaOH

7.35 g

For each of the following pairs of solutions, select the solution for which solute solubility is greatest. Table sugar in water with P = 2 atm and T = 40°C Table sugar in water with P = 1 atm and T = 70°C

70 degrees celsius

The ph for a solution with [Oh−] = 1.0 × 10^−6 is

8.00

What is the molarity of a solution when 25.0 mL of 0.500 M NaCl is diluted to 150.0 mL?

8.33 x 10^-2 M

What is the pH of an aqueous solution with a hydrogen ion concentration of [H^+] = 4.1 x 10^-9 M

8.39

What is the percent-by-mass, %(m/m), concentration of sucrose (table sugar) in a solution made by dissolving 7.6 g of sucrose in 83.4 g of water?

8.4%

Calculate the pH of a solution that is 0.129 M HCl

8.894 x 10^-1

Calculate the value of the equilibrium constant for the equilibrium system 2NO(g) -> N2(g) + O2(g) at 1000°C, given that the equilibrium concentrations are 0.0026 M for NO, 0.024 M for N2, and 0.024 M for O2.

85

For each of the following solutions, how many milliliters of water should be added to yield a solution that has a concentration of 0.100 M? 1.45 L of 6.00 M NaCl

85,600 mL

A solution is 0.0030 M in PO4^3− ion. What is this ion concentration in mEq/L?

9.0 mEq PO4^3-/L

Calculate the mass percent of solute in the following solutions. 12.5 g of KNO3 dissolved in 125 g of H2O

9.06% (m/m)

how many liters of a 0.100 M solution can be prepared from 60.0 g of each of the following solutes? HNO3

9.52 L

A 125-mL sample of a mouthwash contains 12 mL of ethyl alcohol. What is the percent-by-volume concentration of ethyl alcohol in the mouthwash?

9.6% (v/v)

The beta decay of 234Th90 produces a nuclide of which of the following elements?

91

What is the highest-atomic-numbered naturally occurring element?

92

Which of the following combinations of substances would produce a buffer? a. a strong acid and a salt of the strong acid b. a weak acid and a salt of the weak acid c. a salt of a strong acid and a salt of a weak acid d. no correct response

a weak acid and a salt of the weak acid

Strong acids yield

a weak conjugate base

What is the oxidation number of chlorine in each of the following chlorine-containing compounds? a) NaClO b) NaClO3 c) HClO4 d) PCl3

a) +1 b) +5 c) +7 d) -1

A solution contains 48 meq of Ca ion. Based on this information, a. how many eq of Ca2+ ion are present? b. how many moles of Ca2+ ion are present?

a) 0.048 Eq b) 0.024 mole

Determine the molarity of a NaOh solution when each of the following amounts of acid neutralizes 25.0 mL of the NaOh solution. a. 5.00 mL of 0.250 M hNO3 b. 20.00 mL of 0.500 M h2SO4 c. 23.76 mL of 1.00 M hCl d. 10.00 mL of 0.100 M h3pO4

a) 0.0500 M b) 0.800 M c) 0.950 M d) 0.120 M

The half-life of an isotope is 2.5 hours. How much, in grams, of a 1.00 g sample of this isotope will remain after A) a period of 4 lives? B) a period of 10 hours?

a) 0.0625 b) 0.0625

Indicate the number of equivalents in each of the following molar quantities of ions. a. 1 mole Na+ b. 1 mole NO3− c. 1 mole Mg2+ d. 1 mole hCO3−

a) 1 Eq b) 1 Eq c) 2 Eq d) 1 Eq

indicate how many acidic hydrogen atoms and how many nonacidic hydrogen atoms are present in a) hClO3 (chloric acid) b. hC3h5O4 (glyceric acid) c. h3C6h5O7 (citric acid) d. h3pO4 (phosphoric acid)

a) 1 acidic; 0 nonacidic b) 1 acidic; 5 nonacidic c) 3 acidic; 5 nonacidic d) 3 acidic; 0 nonacidic

Without writing an equation, specify the molecular ratio in which each of the following acid-base pairs will react. a. hNO3 and NaOh b. h2SO4 and NaOh c. h2SO4 and Ba(Oh)2 d. hNO3 and Ba(Oh)2

a) 1 to 1 b) 1 to 2 c) 1 to 1 d) 2 to 1

What is the [h3O+] value in solutions with each of the following ph values? a) 5.00 b) 7.00 c) 3.45 d) 7.15

a) 1.0 x 10^-5 M b) 1.0 x 10^-7 M c) 3.5 x 10^-4 M d) 7.1 x 10^-8 M

Determine the half-life of a radionuclide if after 5.4 days the fraction of undecayed nuclides present is a. 1/16 b. 1/64 c. 1/256 d. 1/1024

a) 1.4 days b) 0.90 day c) 0.68 day d) 0.54 day

What is [Oh−] in aqueous solutions with the following [h3O+] concentrations? a. 5.5×10^−2 b. 9.4×10^−5 c. 2.3×10^−7 d. 6.6 × 10^−12

a) 1.8 x 10^-13 M b) 1.1 x 10^-10 M c) 4.3 x 10^-8 M d) 1.5 x 10^-3 M

Write balanced nuclear equations for the beta decay of each of the following nuclides. a) 10Be4 b) carbon-14 c) 21F9 d) sodium-25

a) 10Be4 -> 0B-1 + 10B5 b) 14C6 -> 0B-1 + 14N7 c) 21F9 -> 0B-1 + 21Ne10 d) 25Na11 -> 0B-1 + 25Mg12

Write nuclear equations for each of the following radioactive decay processes. a. Beta emission produces mercury-199 as a product. b. palladium-109 undergoes beta emission. c. Alpha emission produces terbium-148 as a product. d. Fermium-249 undergoes alpha emission.

a) 199Au79 -> 0B-1 + 199Hg80 b) 109Pd46 -> 109Ag47 + 0B-1 c) 152Ho67 -> 148Tb65 + 4a2 d) 249Fm100 -> 245Cm98 + 4a2

how many ions, per formula unit, are produced when each of the following soluble salts (strong electrolytes) dissolves in water? a) NaCl b) Mg(NO3)2 c) K2S d) NH4CN

a) 2 b) 3 c) 3 d) 2

Indicate the number of equivalents in each of the following molar quantities of ions. a. 2 moles K+ b. 3 moles h2pO4− c. 2 moles hpO42− d. 7 moles Ca2+

a) 2 Eq b) 3 Eq c) 4 Eq d) 14 Eq

What is the molar hydronium ion concentration in aqueous solutions with the following hydroxide ion concentrations? a. 3.5 × 10^−3 M b.4.7×10^−6M c. 1.1 × 10^−8 M d. 8.7 × 10^−10 M

a) 2.9 x 10^-12 M b) 2.1 x 10^-9 M c) 9.1 x 10^-7 M d) 1.1 x 10^-5 M

Write a balanced nuclear equation for each of the reactions a. polonium-210 decays to lead-206 b. thorium-225 decays to protactinium-225 c. parent = pt-190; daughter = Os-186 d. parent = O-19; daughter = F-19

a) 210Po84 -> 4a2 + 206Pb82 b) 225Th90 -> 225Pa91 + 0B-1 c) 190Pt78 -> 186Os76 + 4a2 d) 19O8 -> 19F9 + 0B-1

Calculate the pKa value for each of the following acids. a. Nitrous acid (hNO2), Ka = 4.5 × 10−4 b. Carbonic acid (h2CO3), Ka = 4.3 × 10−7 c. Dihydrogen phosphate ion (h2pO4−), Ka = 6.2 × 10−8 d. Sulfurous acid (h2SO3), Ka = 1.5 × 10−2

a) 3.35 b) 6.37 c) 7.21 d) 1.82

How many protons and neutrons are present in each of the following nuclides? a) 10Be4 b) 23Na11 c) silver-108 d) S-34

a) 4,6 b) 11, 12 c) 47, 61 d) 16, 18

Supply a complete symbol, with superscript and subscript, for each of the following types of radiation. a. Alpha particle b. Beta particle c. Gamma ray

a) 4a2 b) 0B-1 c) 0Y0

Supply the missing nuclear symbol in each of the following equations for bombardment reactions. a. 24Mg12 + ? -> 27Si14 + 1n0 b. 27Al13 + 2H1 -> ? + 4a2 c. 9Be4 + ? -> 12C6 + 1N0 d. 6Li3 + ? -> 4He2 + 3He2

a) 4a2 b) 25Mg12 c) 4a2 d) 1p1

Calculate the ph of solutions with the following hydronium ion concentrations. a. 1.00 × 10^−5 M b. 1.00 × 10^−8 M c. 4.75×10^−6M d. 8.88×10^−8M

a) 5.000 b) 8.000 c) 5.323 d) 7.052

Using Table 11-2 as your information source, determine how many of the transuranium elements have a half-life a. greater than 1 year b. less than 1 day

a) 7 b) 17

What is the molar hydronium ion concentration in solutions with each of the following ph values? a. 3.13 b. 3.25 c. 3.50 d. 3.75

a) 7.4 x 10^-4 M b) 5.6 x 10^-4 M c) 3.2 x 10^-4 M d) 1.8 x 10^-4 M

Write a balanced nuclear equation for the decay of each of the following radioactive nuclides. The mode of decay is indicated in parentheses. a. 70Ga31 (beta emission) b. 144Nd60 (alpha emission) c. 248Fm100 (alpha emission) d. 113Ag47 (beta emission)

a) 70Ga31 -> 0B-1 + 70Ge32 b) 144Nd60 -> 4a2 + 140Ce58 c) 248Fm100 -> 4a2 + 244Cf98 d) 113Ag47 -> 0B-1 + 113Cd48

A buffer solution has a ph value of 8.2. Which value in the set of ph values 7.1 8.1 8.2 8.3 9.3 is the most likely value for the buffer solution ph after a. a small amount of strong acid has been added? b. a small amount of strong base has been added?

a) 8.1 b) 8.3

For the generalized chemical reaction A(g) + B(g) -> C(g) + D(g) determine whether the concentration of A in an equilibrium mixture will (1) increase, (2) decrease, or (3) not change when each of the following changes is effected. a. concentration of B is increased b. concentration of C is decreased c. concentration of D is increased d. concentration of D is decreased

a) decrease b) decrease c) increase d) decrease

Indicate whether each of the solutions are acidic, basic, or neutral. (these are the H3O^+) a. 5.5×10^−2 b. 9.4×10^−5 c. 2.3×10^−7 d. 6.6 × 10^−12

a) acidic b) acidic c) acidic d) basic

Indicate whether each of the following samples is acidic, basic, or neutral. a. milk, ph 6.4 b. seawater, ph 8.5 c. drinking water, ph 7.2 d. strawberry, ph 3.4

a) acidic b) basic c) basic d) acidic

Classify each of the following decay reactions as alpha decay or beta decay. a. polonium-210 decays to lead-206 b. thorium-225 decays to protactinium-225 c. parent = pt-190; daughter = Os-186 d. parent = O-19; daughter = F-19

a) alpha b) beta c) alpha d) beta

Indicate whether each of the solutions are acidic, basic, or neutral. (these are the OH) a. 3.5 × 10^−3 M b.4.7×10^−6M c. 1.1 × 10^−8 M d. 8.7 × 10^−10 M

a) basic b) basic c) acidic d) acidic

Which of the naturally occurring radiation types (alpha, beta, and gamma) have the ability to "pass through" a. a thick sheet of paper b. 1 cm thick Al foil c. 5 cm thick concrete d. outer layers of human skin

a) beta, gamma b) gamma c) gamma d) gamma

Indicate whether solutions of each of the following substances contain ions, molecules, or both. a. acetic acid, a weak acid b. sucrose, a nonelectrolyte c. sodium sulfate, a soluble salt d. hydrofluoric acid, a weak electrolyte

a) both b) molecules c) ions d) both

Consider the following four solutions: (1) apple juice, ph 3.8, (2) pickle juice, ph 3.5, (3) carbonated beverage, ph 3.0, and (4) drinking water, ph 7.2. a. Which solution has the highest [h3O+]? b. Which solution has the highest [Oh−]? c. List the solutions in order of increasing acidity. d. List the solutions in order of decreasing basicity.

a) carbonated beverage b) drinking water c) drinking water, apple juice, pickle juice, carbonated beverage d) drinking water, apple juice, pickle juice, carbonated beverage

What is the effect of alpha decay on the a. atomic number of the parent nuclide b. mass number of the parent nuclide

a) decrease by 2 b)decrease by 4

Which of the following reactions are endothermic, and which are exothermic? a) C2H4 +3O2 -> 2CO2 + 2H2O + heat b) N2 +2O2 +heat -> 2NO2 c) 2H2O+ heat -> 2H2 +O2 d) 2KClO3 -> 2KCl + 3O2 + heat

a) exothermic b) endothermic c) endothermic d) exothermic

In a certain chemical reaction, the average energy of the products is lower than the average energy of the reactants. a. Is the chemical reaction exothermic or endothermic? b. Is energy released or absorbed in the chemical reaction?

a) exothermic b) released

For each of the following pairs of solutions, indicate whether the first listed solution has a higher or lower ph than the second listed solution. a. 1.0 M NaOh and 1.0 M hCl b. 1.0 M hNO3 and 0.10 M hNO3 c. 0.10 M hClO4 and 0.10 M hCN d. [h3O+] = 3.3 × 10−3 and [h3O+] = 9.3 × 10−3

a) higher b) lower c) lower d) higher

Indicate whether each of the following pairings of concepts is a correct or an incorrect pairing. a) reducing agent and gain of electrons b) substance oxidized and loss of electrons c) oxidizing agent and increase in oxidation number d) oxidizing agent and substance oxidized

a) incorrect b) correct c) incorrect d) incorrect

For each of the changes listed will the rate of the following chemical reaction increase, decrease, or remain the same? Cu(s) + H2SO4(aq) -> CuSO4(aq)+ H2(g) a) the concentration of H2SO4 is increased b) the copper is ground into a powder c) the mixture is stirred rapidly d) the temperature of the solution is increased

a) increase b) increase c) increase d) increase

For the reaction C6H6 (g) + 3H2 (g) -> C6H12 (g) + heat determine in what direction the equilibrium will be shifted by each of the following changes. a. Increasing the concentration of C6H12 b. Decreasing the concentration of C6H6 c. Increasing the temperature d. Decreasing the pressure by increasing the volume of the container

a) left b) left c) left d) left

Compare the two acids below 1. Acetic acid dissolved in water CH3COOH (aq) + H2O (l) ⇔ H3O+ (aq) + CH3COO - (aq) 2. Carbonic acid dissolved in water H2CO3 (aq) + H2O (l) ⇔ H3O+ (aq) + HCO3- (aq) Based on the value of Ka in the table, which is the stronger acid acetic acid or carbonic acid?

acetic acid

Indicate if the following is a Brønsted-Lowry acid, base or neither. H2CO3

acid

Indicate if the following is a Brønsted-Lowry acid, base or neither. HNO3

acid

In each conjugate pair,

acid is one w more hydrogen atoms

polyprotic =

acid that has more than one hydrogen

define polyprotic acid

acid that supplies 2 or more protons [H+ ions] during acid-base reaction

In an Arrhenius acid-base theory context, the compounds hCl, hNO3, and NaOh, when dissolved in water, are, respectively, which of the following?

acid, acid, base

The [H3O+] concentration of a solution is 2.5 x 10^-4 Is this solution acidic or basic?

acidic

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral [H^+] = 3.8 x 10^-3

acidic

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral [OH^-] = 2.3 x 10^-8

acidic

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral pH = 5.87

acidic

if H3O^+ is 1.0 x 10^-2 M and OH^- is 1.0 x 10^-12, type of solution is

acidic

if H3O^+ is 2.5 x 10^-5 M and OH^- is 4.0 x 10^-10, type of solution is

acidic

pH < 7

acidic

[H3O+] > [OH-]

acidic solution

The minimum combined kinetic energy reactant molecules must possess in order for their collision to result in a chemical reaction is called the

activation energy

Which of the following factors will influence the rate of a chemical reaction? A) changing the surface area B) changing the temperature C) changing the concentration of the reactants D) adding a catalyst

all of the above

There are 7 strong acids

all other acids are weak

the strong bases are hydroxides of groups IA and IIA [metal hydroxides]

all other bases are weak

Acids, bases, and soluble salts

all produce ions in solution [all produce solutions that conduct electricity]

Which of the following types of radioactive emissions has a subatomic particle compo-sition of two protons and two neutrons?

alpha particle

Which of the following correctly orders the three types of naturally occurring radiation in terms of increasing penetrating power into matter?

alpha, beta, gamma

Major damage occurs when

alpha-emitting radionuclides are ingested [contaminated food]

results that agree with "like dissolved like" are nearly

always obtained in cases of gas-in-liquid & liquid-in-liquid solutions & for solid-in-liquid solutions in which solute is not ionic compound

concentration of a solution

amount of solute in specified amount of solution

Define concentration

amount of solute present in specified amount of solution

Concentration=

amount of something/some unit of volume

Water is something

amphiprotic [bc can behave as acid or base]

What weak acid would be best to use when preparing a buffer solution with a pH of 8.00?

an acid with Ka = 1.0 x 10^-8

in a chemical reaction, The chemical reactivity of

an element depends on element's state of combination [free element, compound, etc]

Weak acids have?

an equilibrium [like HF]

Keq is used to denote

an equilibrium constant

Kw = [H3O+] [OH-] This value is

an equilibrium constant

IONIZATION: The process whereby, in

aqueous solution, positive & negative ions are produced from molecular compound.

Not all hydrogens

are acidic

in a nuclear equation, mass numbers and atomic numbers (nuclear charge)

are always specifically included in nuclear equations

All common soluble salts

are completely dissociated into ions in solution

Two components [in buffers]

are in equilibrium

in a nuclear reaction, Reaction rates

are independent of temp, pressure, catalysts & reactant concentrations.

CO2 and H2O

are low energy [stable]

All solutions

are mixtures [but only homogeneous mixtures are solutions]

in a chemical system in an equilibrium state product molecules

are reacting w each other

in a chemical system in an equilibrium state reactant molecules

are reacting with each other

The particles that are allowed to pass through semipermeable membrane (usually just solvent molecules like water)

are relatively small.

If both substances (in a solution)

are same state, substance present in greatest amount is generally considered solvent

All nitrates

are soluble

Most chlorides & bromides

are soluble [except w silver, lead(II) and mercury(I)]

in equations with strong electrolytes

arrow only to right

pH decreases

as [H^+] increases

What is the relationship between gas pressure and solubility?

as pressure of gas above liquid increases, solubility of gas increases

Using collision theory, indicate why each of the following factors influences the rate of a reaction. Temperature of reactants

as temp increases, so does number of collisions per second

explain how each of the following radionuclides is used in diagnostic medicine. Thallium-201

assessment of blood flow in heart muscle

When a percent concentration is given without specifying which of the three types of percent concentration it is,

assumed to mean percent by mass.

in a hyperbaric chamber,

atmospheric pressure is increased & controlled

# of protons tells you

atomic number & what it is

Hydrogen stays

attached to water

Opposite charges

attract

Which of the following chemical reactions is a nonredox reaction? a. Ca + S -> CaS b. SO3 + h2O -> h2SO4 c. 2NO+O2 -> 2NO2 d. no correct response

b

Which of the following is not a balanced nuclear equation? a. 121Sn50 -> 0B-1 + 121Sb51 b) 238U92 - 4a2 + 232Th90 c) 10Be4 -> 10B5 + 0B-1 d) no correct response

b

HNO3 (aq) + H2O (l) → H3O+ (aq) + NO3- (aq) here water is

base

Indicate if the following is a Brønsted-Lowry acid, base or neither. Cl^-

base

Using the Arrhenius theory, classify the following as either an acid or a base: Al(OH)3

base

Using the Arrhenius theory, classify the following as either an acid or a base: CsOH

base

Determining the concentration of an acid using an acid-base titration involves completely reacting a measured volume of the acid with a measured volume of

base of known concentration

The selectivity of a semipermeable membrane is

based on size differences of molecules.

A solution with pH = 8.5 is defined as

basic

The [H3O+] concentration of a solution is 2.5 x 10^-9 Is this solution acidic or basic?

basic

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral [H^+] = 1.5 x 10^-10

basic

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral [OH^-] = 6.1 x 10^-4

basic

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral pH = 9.59

basic

if H3O^+ is 1.0 x 10^-8 M and OH^- is 1.0 x 10^-6, type of solution is

basic

if H3O^+ is 5.0 x 10^-11 M and OH^- is 1.0 x 10^-4, type of solution is

basic

pH > 7

basic

If H3O^+ is 2.5 x 10^-9 and OH^- is 4.0 x 10^-6 is this solution acidic or basic?

basic bc OH is higher

[H3O+] < [OH-]

basic solution

Why does H2CO3 and CO3^2- not contain an acid-base conjugate pair?

bc differs by 2 hydrogens

in NH3 + H2O -> NH4 + OH^- why is NH4^+ the conjugate acid?

bc getting one proton [so get its positive charge]

Why is CH3OH soluble in water?

bc has a hydrogen bond

Why does a reaction happen faster with a high concentration?

bc more stuff = more chance of collision

Most acid base reactions reach equilibrium

bc most acids are too "weak" to completely ionize & donate all their protons

If you add hydrogen to H2(g) + I2(g) <=> HI(g) value of Keq will not change. Why?

bc only thing that can change Keq value is temp

for osmosis, why is the rate of flow into the concentrated solution is greater than the rate of flow in the other direction

bc presence of solute molecules diminishes ability of water molecules to cross membrane.

in C6H6(g) + 3H2(g) -> C6H12(g) + heat why would increasing the pressure shift equilibrium to the right?

bc right has fewer moles of gas

buffers work

bc there's an equilibrium

in a nuclear reaction, Elements may

be changed into other elements during nuclear reactions.

Le Chatelier's Principle says If more products have

been produced as result of disruption, equilibrium has shifted to right

H at the

beginning of formula are acidic hydrogens

Which of the following types of radioactive emissions has a charge and mass identical to that of an electron?

beta particle

Internal exposure to

beta radiation is as serious as internal alpha exposure

Water has a

big dipole

acetic acids have

bigger value for Ka than carbonic acid [means more product]

At 24°C, the molar concentrations of H3O+ and OH− ions in pure water are

both 1.00 × 10^−7 M

An amphiprotic substance is a substance that can function as

both a Brønsted-Lowry acid and a Brønsted-Lowry base

in HC2H3O2 and H3C6H5O7

both acidic & nonacidic hydrogen atoms are present

13C6 and 14C6

both are unstable [both spontaneously change into another element]

polyprotic acid includes

both diprotic and triprotic acids

Film badges, worn by technicians working with radiation, can detect

both extent and type of radiation exposure

Film badges

both low & high energy

When an ionic solute dissolves in water, the water molecules hydrate

both positive ions & negative ions

Solution formation occurs more rapidly at higher temperatures because molecules of

both solute & solvent move more rapidly

The term nuclide is a term used to describe

both stable and unstable atoms

Reactions go

both ways

alpha particle is like

bowling ball

In which of the following pairs of acids are both members of the pair strong acids? a. H2CO3 and H2SO4 b. HCl and HF c. HCl and HNO3 d. no correct response

c

In which of the following pairs of substances are both members of the pair salts? a. NaCl and NaOH b. HBr and NaBr c. KNO3 and KCN d. no correct response

c

Which of the following changes will decrease the reaction rate for the chemical reaction S(s) + O2(g) -> SO2(g) a. increase the state of subdivision of the solid-state S b. increase the amount of O2 present in the reaction mixture c. decrease the amount of S present in the reaction mixture d. no correct response

c

Which of the following changes will shift the position of the equilibrium to the left for the chemical reaction N2(g) + 3H2(g) -> 2NH3(g) a. decrease the concentration of Nh3 b. increase the concentration of h2 c. decrease the concentration of N2 d. no correct response

c

Which of the following does not describe an acidic solution at 24°C? a. the ph is less than 7.0 b. the [h3O+] is greater than the [Oh−] c. the [h3O+] is 1.0 ×10^−8 d. no correct response

c

Which of the following hypothetical solutions of ions is out-of-balance relative to ion charge? a. 1.0 meq Na+, 2.0 meq Ca2+, and 3.0 meq Cl− b. 2.0 meq Mg2+, 1.0 meq Cl−, and 1.0 meq NO3− c. 2.0 meq Na+, 2.0 meq K+, and 2.0 meq pO43− d. no correct response

c

Which of the following ions cannot be present in a salt? a. Na+ b. SO4^2− c. OH− d. no correct response

c

Which of the following is a conjugate acid-base pair? a. H2CO3/CO3^2− b. H3PO4/PO4^3− c. HCN/CN^− d. no correct response

c

Which of the following is an inappropriate designation for a salt? a. insoluble salt b. completely dissociated salt c. weak salt d. no correct response

c

Which of the following is not a characteristic of a chemical system in an equilibrium state? a. product molecules are reacting with each other b. reactant molecules are reacting with each other c. product molecules are reacting with reactant molecules d. no correct response

c

Which of the following is not a general property of radionuclides used is diagnostic medical procedures? a. must be detectable by instrumentation placed outside the body b. must have a known mechanism for elimination from the body c. must have a long half-life d. no correct response

c

Which of the following molar amounts of an ion is not equal to one equivalent of ion? a. 1.0 mole Cl^− b. 0.50 mole SO4^2− ion c. 0.50 mole Nh4+ ion d. no correct response

c

Which of the following produces a alpha particle? a) 68Ga31 + 0e-1 -> 68Zn30 b) 62Cu29 -> 0e+1 + 62Ni28 c) 212Fr87 -> 4He2 + 208At85 d) 129Sb51 -> 0e-1 + 129Te52

c

Which of the following will produce a compound with sulfate that is not soluble. lithium calcium ammonium sodium

calcium

More than one solute

can be present in same solution.

If you have two cups and one looks like it has more

can be same amount but diff concentration [diff amount of water]

in a solution, solute generally

can be separated from solvent by physical means such as evaporation

Solutes and solvents

can be solids, liquids or gases

It's an acid if

can donate a hydrogen

Define amphiprotic substance

can either lose or accept proton [can function as either bronsted-lowry acid or bronsted-lowry base]

Unsaturated solution is like

can jam more stuff into it

in ionizing radiation,

can remove electrons so it's bad

in dilution problems,

can use any unit as long as they match

Classify each of the following reactions as (1) a redox reaction (2) a nonredox reaction or (3) "can't classify" because of insufficient information A displacement reaction in which both of the reactants are compounds

can't classify

Na^+ and Pb^+

can't make a compound bc both positive

What is happening in Fe2O3(s) + 3CO(g) -> 2Fe(s) + 3CO2(g)

carbon got oxidized [reducing agent]; iron got reduced [oxidizing agent]

ethanol is a polar solvent and carbon tetrachloride is a nonpolar solvent. In which of these two solvents are each of the following solutes more likely to be soluble? Cooking oil, nonpolar

carbon tetrachloride

For each solute, identify the better solvent: water or carbon tetrachloride C6H14

carbon tetrachloride (CCl4)

The hydrogen atoms

carry partial positive charge

Determining the concentration of an acid using an acid-base titration involves what

carrying out an acid-base neutralization reaction

Using collision theory, indicate why each of the following factors influences the rate of a reaction. presence of a catalyst

catalyst lowers activation energy

gamma ray can?

cause burn on skin

Increasing the temperature at which a chemical reaction occurs will cause which of the following effects?

cause more reactant collisions to take place within a given time

A hypotonic solution can be used to

cause water to flow from blood into surrounding tissue [decrease bp]

Adding a solute to a pure solvent

causes solvent's physical properties to change

in physiological saline solution,

cells neither swell nor shrink [an isotonic solution]

Concentrated sodium chloride solution is hypertonic with respect to red blood cell fluid,

cells undergo crenation when placed in it

Distilled water is hypotonic with respect to red blood cell fluid,

cells will hemolyze when placed in it

Suppose that a sample of red blood cells are placed into a solution of brine (salt water). What is the expected effect on the cells?

cells will shrivel as water flows out of cells into brine solution

Properties of a solution

change as ratio of solute to solvent is changed

What can change the value of an equilibrium constant?

change in reaction temp

N2(g) + 3H2(g) <- ——> 2NH3(g) what happens here ultimately?

changes offset each other so value of equilibrium constant K remains constant

With concentration changes!

changes offset each other so value of equilibrium constant K remains constant

Tell me what a neutralization reaction is

chemical reaction between acid & hydroxide base in which salt & water are products

exchange reaction [double displacement]

chemical reaction in which 2 substances exchange parts w another & form 2 diff substances

Displacement reaction

chemical reaction in which atom or molecule displaces atom or group of atoms from compound

Combination reaction

chemical reaction in which single product is produced from 2 or more reactants

Decomposition reaction

chemical reaction in which single reactant is converted into 2 or more simpler substances [elements or compounds]

Nonoxidation-Reduction (Nonredox) Reaction

chemical reaction; no transfer of electrons from 1 reactant to another reactant

Oxidation-Reduction (Redox) Reaction

chemical reaction; transfer of electrons from 1 reactant to another reactant

Elements maintain their identity in

chemical reactions but not in nuclear reactions.

Ch1-10 has been

chemistry of electrons

The more you...

chop things up, more soluble

electrons

circle around nucleus

The effect of 1 mole of CaCl2 on

colligative properties will be 3x that of 1 mole of glucose on colligative properties

Classify each of the following chemical reactions as a combination, decomposition, dis- placement, exchange, or combustion reaction. 3Mg + N2 -> Mg3N2

combination

Classify each of the following chemical reactions as a combination, decomposition, displacement, exchange, or combustion reaction. HCl(g) + NH3(g) → NH4Cl(s)

combination

Classify each of the following reactions as a combination, decomposition, displacement, exchange, or combustion reaction. 2P + 3H2 -> 2PH3

combination

Classify each of these reactions: CaO + CO2 -> CaCO3

combination [synthesis]

Classify the following reaction: CaO + CO2 -> CaCO3

combination [synthesis]

2H2 + O2 -> 2H2O

combination reaction

X + Y -> XY

combination reaction

Indicate to which of the following types of reactions each of the statements listed applies: combination, decomposi- tion, displacement, exchange, and combustion. More than one answer is possible for a given statement. A compound may be a product.

combination, decomposition, displacement, exchange, & combustion.

Indicate to which of the following types of reactions each of the statements listed applies: combination, decomposi- tion, displacement, exchange, and combustion. More than one answer is possible for a given statement. A compound may be a reactant.

combination, decomposition, displacement, exchange, & combustion.

Indicate to which of the following types of reactions each of the statements listed applies: combination, decomposition, displacement, exchange, and combustion. More than one answer is possible for a given statement. An element may be a reactant.

combination, displacement, combustion

Buffers are a

combo of 2 things you add to water so pH doesn't change

Classify each of the following chemical reactions as a combination, decomposition, displacement, exchange, or combustion reaction. 4NH3 + 5O2 → 4NO + 6H2O

combustion

What type of reaction is shown below? 2C2H6 + 7O2 → 4CO2 + 6H2O

combustion

C3H8 + 5O2 → 3CO2 + 4H2O

combustion reaction

pH = -log[H3O^+]

compact way to represent solution acidity

if reaction goes to right,

concentration is higher

Substances burn more rapidly in pure oxygen than in air. explain why.

concentration of O2 has increased from 21% 100%

CSVS = CDVD

concentration of stock solution x volume of stock solution = concentration of diluted solution x volume of diluted solution

For solid solutions,

concentrations are expressed as percent by mass concentration %(m/m)

For liquid solutions,

concentrations are expressed as percent by volume concentration %(v/v)

tell me about strong electrolytes

conduct strong electric current in water [salts, strong acids & bases]

tell me about weak electrolytes

conduct weak electrical current [weak acids & bases]

Every bronsted-lowry base has

conjugate acid

Every bronsted-lowry acid has

conjugate base

In determining which pair of molecules will mix together to form a homogeneous solution,

consider intermolecular forces

Weak bases tend to

contain nitrogen

Any compound that

contains a group 1 cation is soluble

The half-life of cobalt-60 is 5.2 years. This means that after 5.2 years a cobalt-60 sample

contains half as many cobalt-60 atoms as it did originally

What does the term reversible reaction mean?

conversion of reactants to products and conversion of products to reactants occur simultaneously

Identify the solvent in: bronze (an alloy of 95% copper and 5% tin)

copper

C6H12O6 is!

covalent

Acids are!

covalent [but sometimes H comes off & attaches itself to water]

HF is what?

covalent [so should not come apart in water]

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 0.28 M NaCl

crenate

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 0.28 M in both glucose and sucrose

crenate

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 5.0%(m/v) NaCl solution

crenate

In which of the following pairs of bases are both bases weak bases? a. NaOH and KOH b. Ca(OH)2 and Ba(OH)2 c. LiOH and Sr(OH)2 d. no correct response

d

Which of the following produces a beta particle? a) 68Ga31 + 0e-1 -> 68Zn30 b) 62Cu29 -> 0e+1 + 62Ni28 c) 212Fr87 -> 4He2 + 208At85 d) 129Sb51 -> 0e-1 + 129Te52

d

Drano is

dangerous to you

The greater the

decay rate for radionuclide, shorter its half-life.

Classify each of the following chemical reactions as a combination, decomposition, dis- placement, exchange, or combustion reaction. 2KNO3 -> 2KNO2 + O2

decomposition

If the ph of a solution increases from 4.0 to 6.0 the hydronium ion concentration [h3O+]

decreases by a factor of 100

We use polarity to

describe covalent compounds

Hemolysis

destruction of RBC

Film Badges are used to

detect person's exposure to radiation

explain how each of the following radionuclides is used in diagnostic medicine. Barium-131

detection of bone tumors

explain how each of the following radionuclides is used in diagnostic medicine. potassium-42

determination of intercellular spaces in fluids

two factors rather than one

determine number of particles present.

Number of sig figs in [H3O+] or [OH-] value

determines number of digits past l decimal in pH value

Contrast the behavior of different isotopes of an element in nuclear and chemical reactions.

diff isotopes of element have same chemical properties but diff nuclear properties

Conjugate base pairs...

differ by a hydrogen

The members of a conjugate acid-base pair

differ from each other through loss or gain of proton

You never start

dimensional analysis problems w conversion factors

2 protons per molecule transferred in an acid-base reaction

diprotic acid

H2CO3 would be an example of

diprotic acid

H2SO4 would be an example of

diprotic acid

why does vapor pressure decrease when solute is added

direct consequence of some of solute molecules or ions occupying positions on surface of liquid [presence decreases probability of solvent molecules escaping]

Stirring solution components

disperses solute particles more rapidly, increasing possibilities for solute- solvent interactions [rate of solution formation is increased]

Classify each of the following chemical reactions as a combination, decomposition, dis- placement, exchange, or combustion reaction. Zn + 2AgNO3 -> Zn(NO3)2 + 2Ag

displacement

Classify each of the following chemical reactions as a combination, decomposition, displacement, exchange, or combustion reaction. Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)

displacement

Classify each of the following reactions as a combination, decomposition, displacement, exchange, or combustion reaction. 3CuSO4 + 2Al -> Al2(SO4)3 + 3Cu

displacement

Classify each of these reactions: ZnSO4 + Mg -> Zn + MgSO4

displacement & redox

Classify the following reaction: ZnSO4 + Mg -> Zn + MgSO4

displacement [single replacement]

X + YZ -> Y + XZ

displacement reaction

Zn + 2HCl -> ZnCl2 + H2

displacement reaction

Arrhenius theory says a base

dissociates in water to produce hydroxide ions

nonpolar + nonpolar

dissolve

Nonpolar solvents

dissolve nonpolar solutes

Polar solvents

dissolve polar & ionic solutes

Although possible, a reaction at equilibrium

does not necessarily have equal concentrations of products & reactants

Stable nucleus

does not readily undergo change

example: HA(aq) + H2O(l) <=> H3O+(aq) + A-(aq) you

don't put pure water in equilibrium expressions bc concentration can't change

A bronsted lowry acid is a substance that can

donate a proton [H^+ ion] to some other substance

A Brønsted-Lowry acid is a substance that can

donate a proton to some other substance

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) in this acid-base reaction, an acid HF

donates H^+ to form its conjugate base [F^-]

in HCl + H2O -> Cl^- + H3O^+ HCl

donates proton

Acid does what

donates proton when put in water

exchange reaction aka

double displacement

Classify each of these reactions: NaNO2 + HCl -> NaCl + HNO2

double displacement [exchange/metathesis]

Classify the following substance & description as an electrolyte or nonelectrolyte a soluble ionic compound

electrolyte

Classify the following substance & description as an electrolyte or nonelectrolyte potassium iodide, KI

electrolyte

Classify the following substance & description as an electrolyte or nonelectrolyte sodium chloride, NaCl

electrolyte

Classify the following substance & description as an electrolyte or nonelectrolyte sodium hydroxide, NaOH

electrolyte

swell

enlarge in size

What are the catalysts in the human body?

enzymes

Use the given Keq value and the terminology in Table 9-2 to describe the relative amounts of reactants and products present in each of the following equilibrium situations. 2HCl(g) <=> H2(g) + Cl2(g) Keq at 25 degrees celsius = 3.2 x 10^-34

essentially all reactants

if Value of Keq is very small (10^−30) what is Relative Amount of Products and Reactants & Description of Equilibrium Position

essentially all reactants & far to the left

Identify the solute in: a solution of 3.0 x 10^1% ethanol and 7.0 x 10^1% water

ethanol

ethanol is a polar solvent and carbon tetrachloride is a nonpolar solvent. In which of these two solvents are each of the following solutes more likely to be soluble? LiNO3, ionic

ethanol

Identify the solute and the solvent in solutions composed of the following: 60.0 mL of methyl alcohol and 20.0 mL of ethyl alcohol

ethyl alcohol solute; methyl alcohol solvent

If you dissolve HCl in water, precedes 100% to right

every molecule of HCl comes completely apart bc HCl is very strong

When we dissolve 1 mole of CaCl2 in 1 liter of water we have 1 mole of chemical and 3 moles of charge (1 mole of Na+ and 2 mole of Cl -).

example of why we care about electrolytes

All reactions

except explosions go forward and then back

Classify each of the following chemical reactions as a combination, decomposition, dis- placement, exchange, or combustion reaction. Ni(NO3)2 + 2NaOh -> Ni(Oh)2 + 2NaNO3

exchange

Classify each of the following reactions as a combination, decomposition, displacement, exchange, or combustion reaction. 2AgNO3 + K2SO4 -> Ag2SO4 + 2KNO3

exchange

Classify the following reaction: NaNO2 + HCl -> NaCl + HNO2

exchange [double replacement]

AX + BY -> AY + BX

exchange reaction [double displacement]

Na2SO4(aq) + Pb(NO3)2(aq) → 2NaNO3(aq) + PbSO4(s)

exchange reaction [double displacement]

heat energy production is a characteristic of

exothermic chemical reactions

CH4 + O2 -> CO2 + H2O + heat is example of

exothermic reaction [bc energy is product]

Indicate whether each of the following statements about the general properties of solutions is true or false. The solutes present in a solution will "settle out" with time if the solution is left undisturbed.

false

Is the following statement concerning a saturated solution true or false? undissolved solute must be present

false

true or false: Solutions readily separate into solute and solvent if left undisturbed for 24 hours.

false

true or false: at equilibrium, the concentrations of reactants and products are equal

false

true or false: to determine whether a collision between 2 reactant molecules will result in a reaction, the energies of the colliding particles must be equal to each other

false

true or false: to determine whether a collision between 2 reactant molecules will result in a reaction, the particles must be charged

false

true or false? the activation energy is the energy difference between the energy of the products and the energy of the reactants

false

true or false? when the activation energy is low, the reaction rate is slow

false

Why do technicians who work around radiation usually wear film badges?

films record extent of exposure to radiation

If a solute and solvent can

find any way to interact w each other, then it can be dissolved

Pure substance =

fixed composition

Consider two solutions, A and B, separated by an osmotic semipermeable membrane that allows only water to pass through Based on each of the following identities for solutions A and B, indicate whether the liquid level in compart- ment A, with time, will increase, decrease, or not change. A = 5.0%(m/v) glucose solution and B = 4.0%(m/v) glucose solution

increase

Indicate whether each of the following actions will increase or decrease the rate of dissolving of a sugar cube in water. Breaking the sugar cube up into smaller "chunks"

increase

Will the changes listed increase or decrease the rate of the following chemical reaction? 2CO + O2 -> 2CO2 Adding a catalyst to the reaction mixture

increase

Will the changes listed increase or decrease the rate of the following chemical reaction? 2CO + O2 -> 2CO2 Adding some O2 to the reaction mixture

increase

How does reactant concentration influence chemical reaction rate?

increase in concentration of reactant causes increase in rate of reaction.

Indicate the effect of the following on the rate of this reaction: 3H2 (g) + N2 (g) -> 2NH3 (g) Add a catalyst

increase rate

What is the effect of temperature on solids?

increase temp = most solids become more soluble in water

For reactants in the solid state, reaction rate

increases as subdivision of solid increases.

High temperature

increases energy of collision

Subdivision

increases solid-state surface areas.

If we add hydrogen to H2(g) + I2(g) <=> HI(g)

initially H2 go up, I2 down, HI up [value of Keq will not change]

A compound has a solubility in water of 250 mg/L at 25°C. Should this compound be characterized as a soluble or insoluble compound at 25°C?

insoluble

Predict the solubility of each of the following solutes in the solvent indicated. AgCl (an ionic solid) in water

insoluble

Predict the solubility of each of the following solutes in the solvent indicated. Methane (a nonpolar gas) in water

insoluble

Predict whether the following compound is soluble or insoluble in water: BaSO4

insoluble

Predict whether the following compound is soluble or insoluble in water: FeCO3

insoluble

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. Cu(OH)2

insoluble

Using Table 8-2, indicate whether each of the following ionic compounds is soluble or insoluble in water. silver chloride

insoluble

Using Table 8-2, classify each of the following types of ionic compounds using the solubility categories soluble, soluble with exceptions, insoluble, or insoluble with exceptions. carbonates

insoluble with exceptions

Using Table 8-2, classify each of the following types of ionic compounds using the solubility categories soluble, soluble with exceptions, insoluble, or insoluble with exceptions. phosphates

insoluble with exceptions

Why do oil and water not mix?

intermolecular forces between water molecules are so strong that after oil-water mixture is shaken, water layer re-forms, squeezing out oil molecules

"100% dissociation for electrolytes" means

ion pairing can be ignored

Kw

ion product constant for water

NaCl is!

ionic

The rule "like dissolves like" is not adequate when predicting solubility in water when the solute is a(n)

ionic solid

Hydrogen atoms can

ionize to form H^+/H3O^+

Strong electrolytes do what?

ionize/dissociate 100% in water, producing positive & negative ions

A Geiger counter operates on the principle that radiation

ionizes atoms and molecules

Weak electrolytes do what?

ionizes/dissociates only slightly in water

in Fe2O3(s) + 3CO(g) -> 2Fe(s) + 3CO2(g)

iron gained 3 electrons

Why is Fe(s) + Cu^2+ -> Fe^2+ Cu(s) a redox reaction?

iron gave up 2 electrons; gave them to copper

Fe2O3

iron(III) oxide

vitamin C

is an acid

The only thing that changes the value of Keq

is change in temp

Typically, a buffer system

is composed of weak acid & its conjugate base.

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 0.28 M glucose

isotonic

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 0.14 M in both glucose and sucrose

isotonic

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 0.92%(m/v) NaCl solution

isotonic

osmolarity relative to body fluids is equal

isotonic

osmotic effect on cells is: equal water flow into and out of cells

isotonic

osmotic pressure relative to body fluids is equal

isotonic

An atom or ion is reduced if

it gains electrons

if a formula ends in COOH,

it is an acid

Why does seawater evaporate more slowly than fresh water at the same temperature?

it's more concentrated solution so has lower vapor pressure

Water-water hydrogen bonds

keep water from mixing w nonpolar molecules

for equilibrium constant, 29

kind of in middle [50-50 reaction]

As the temperature of a solution increases,

kinetic energy of molecules increases

Synthetic radionuclides are now

known for each of naturally occurring elements.

Strong acids have a ______ value of Ka and the equlibrium for the reaction with water lies far to the _______.

large, right

C6H6(g) + 3H2(g) -> C6H12(g) + heat Indicate if the following will shift the equilibrium to the right or left. Also indicate if the changes will change the value of Keq. increasing the concentration of C6H12

left; no

For the reaction H2 + I2 <---> 2HI if the value of Keq is 0.001 then the equilibrium lies to the _______ and the reaction contains mostly ____________.

left; reactants

C6H6(g) + 3H2(g) -> C6H12(g) + heat Indicate if the following will shift the equilibrium to the right or left. Also indicate if the changes will change the value of Keq. Increasing temperature

left; yes

For exothermic chemical reactions the average energy of the products is

less than that of the reactants

The polarity of water

lets it dissolve compounds

"radiation" =

light

"Activation energy" is like

lighting a flame

What is the main solubility rule?

like dissolves like

The word "like" in the solubility rule "like dissolves like" refers to

like polarity

explain how each of the following radionuclides is used in diagnostic medicine. a. Gallium-67

locate sites of infection

Indicate whether each of the following substances loses or gains electrons in a redox reaction. The reducing agent

loses

Indicate whether each of the following substances loses or gains electrons in a redox reaction. The substance undergoing oxidation

loses

the reducing agent does what?

loses electrons

in terms of electron transfer: oxidation

loss of electrons

What are characteristics of the process of oxidation?

loss of one or more electrons & oxidation number increase

hydrocarbons have

lots of energy

Excitation

low energy radiation excites electron from electron from occupied orbital into empty, higher-energy orbital.

If almost everything comes apart

low pH; strong acid

Alpha Particle Effects have

low penetrating power & cannot penetrate body's outer layers of skin

A nonvolatile solute is one that has

low vapor pressure & therefore low tendency to vaporize

Catalysts are substances that

lower activation energy for chemical reaction

High concentration of hydrogen ions means

lower pH

Identify the solvent in: a solution containing 50.0 mL of methanol and 30.0 mL of water

methanol

What definition best describes the term activation energy?

minimum kinetic energy that particles must possess for chemical reaction to occur

Two substances that

mix w each other are said to be miscible

Osmolarity is the

molarity × i [i is number of particles produced from dissociation of 1 formula unit of solute]

The three core concepts upon which collision theory is based are:

molecular collisions, collision orientation, activation energy

Methanol is a

molecular compound & does not produce ions when dissolved in water

Nonelectrolytes do not conduct an electric current

molecular compounds [not acids]

Chemical reactions occur when what happens?

molecules or atoms collide, bonds between atoms are broken & new bonds are formed

Moles of solute before dilution =

moles of solute after dilution

Molarity

moles of solute in solution divided by liters of solution

Molarity (M) =

moles of solute/liters of solution

The defining equation for the molarity concentration unit is

moles solute/L solution

HCl would be an example of

monoprotic acid

HNO3 would be an example of

monoprotic acid

one proton per molecule transferred in an acid-base reaction

monoprotic acid

pyruvic acid, which is produced in metabolic reactions, is C3H4O3 Would you predict that this acid is a mono-, di-, tri-, or tetraprotic acid? Give your reasoning.

monoprotic bc only 1 H atom is involved in polar bond

more H ions

more acidic

Higher the pH,

more basic

More stuff = [as far as chemical reaction rate]

more chance of collision

High temperature increases energy of collision

more collisions & more chances of successful collision

as the temperature and kinetic energy increases,

more gas can escape from solution

stronger acid =

more product

Use the given Keq value and the terminology in Table 9-2 to describe the relative amounts of reactants and products present in each of the following equilibrium situations. H2(g) + Br2(g) <=> 2HBr(g) Keq at 25 degrees celsius = 2.0 x 10^9

more products than reactants

if Value of Keq is large (10^10) what is Relative Amount of Products and Reactants & Description of Equilibrium Position

more products than reactants & to the right

if Value of Keq is small (10^−10) what is Relative Amount of Products and Reactants & Description of Equilibrium Position

more reactants than products & to the left

Dilution is the process in which

more solvent is added to solution to lower its concentration

If energy goes down

more stable

alpha particles are the

most damaging if get inside bc big

Decreasing pressure

moves reaction to left

a decomposition reaction must have

multiple products but only one reactant

Solute and solution volumes

must always be expressed in same units when percent by volume units are used

In a redox reaction the substance oxidized

must be a reactant

Osmotic pressure is the pressure that

must be applied to prevent net flow of solvent through semipermeable membrane from lower to higher solute concentration

The largest source of radiation exposure from all sources, for the average American, is

natural sources

#1 source of exposure to radioactive is

natural world [radon gas]

radon gas is!

naturally occuring

on the periodic table, the ...

naturally occuring are dark filled in ones

What is background radiation?

naturally occuring ionizing radiation

Tell me about this: HF + H2O <=> H3O^+ + F^-

need more F but not more H so add NaF

the "p" in pH

negative log

the "p" in pKa

negative log

beta particle is like

negatively charged particle

Indicate if the following is a Brønsted-Lowry acid, base or neither. Mg^+

neither

how will the gas-phase equilibrium CH4(g) + 2H2S(g) + heat -> CS2(g) + 4H2(g) be affected by each of the following? The addition of CS2(g)

shift to left

how will the gas-phase equilibrium CH4(g) + 2H2S(g) + heat -> CS2(g) + 4H2(g) be affected by each of the following? An increase in the temperature

shift to right

how will the gas-phase equilibrium CH4(g) + 2H2S(g) + heat -> CS2(g) + 4H2(g) be affected by each of the following? An increase in the volume of the container (a decrease in pressure)

shift to right

how will the gas-phase equilibrium CH4(g) + 2H2S(g) + heat -> CS2(g) + 4H2(g) be affected by each of the following? The removal of H2(g)

shift to right

Increasing the pressure does what

shifts equilibrium in direction that decreases number of molecules in gas phase & thus decreases pressure.

CoCl4^2- + 6H2O -> Co(H2O)6^2+ + 4Cl^- + heat what happens if you cool the mixture (remove heat)?

shifts equilibrium to right

Decreasing the volume [Le Chatelier & pressure]

shifts equilibrium toward side w fewer moles of gas.

in equations, strong electrolytes

show formation of 100% ions in aqueous(aq) solutions

What happens in hypertonic solution?

shrink

Will red blood cells swell, remain the same size, or shrink when placed in 0.28 M NaCl

shrink

Will red blood cells swell, remain the same size, or shrink when placed in 0.28 M in both glucose and sucrose

shrink

Will red blood cells swell, remain the same size, or shrink when placed in 5.0%(m/v) NaCl solution

shrink

Crenation

shrinking of RBC

When red blood cells are placed in a concentrated sodium chloride solution,

shrivel [crenation]

Use the given Keq value and the terminology in Table 9-2 to describe the relative amounts of reactants and products present in each of the following equilibrium situations. COCl2(g) <=> CO(g) + Cl2(g) Keq at 395 degrees celsius = 0.046

significant amounts of both reactants & products

Use the given Keq value and the terminology in Table 9-2 to describe the relative amounts of reactants and products present in each of the following equilibrium situations. SO2(g) + NO2(g) <=> NO(g) + SO3(g) Keq at 460 degrees celsius = 85.0

significant amounts of both reactants & products

if Value of Keq is near unity (between 10^3 and 10^−3) what is Relative Amount of Products and Reactants & Description of Equilibrium Position

significant amounts of both reactants and products & neither to the right nor to the left

Chlorides, bromides, and iodides are soluble in water except for those of

silver, lead & mercury

Predict whether the following solutes are very soluble or slightly soluble in water. AgCl [an ionic solid]

slightly soluble

Predict whether the following solutes are very soluble or slightly soluble in water. CBr4 [a nonpolar liquid]

slightly soluble

Predict whether the following solutes are very soluble or slightly soluble in water. O2 [a nonpolar gas]

slightly soluble

During a bombardment reaction the particles colliding with target nuclei are

small and traveling very fast

Energy changes in chemical reactions are

small compared to those in nuclear reactions.

Why are the radionuclides used for diagnostic procedures usually gamma emitters?

so radiation can be detected externally

Identify the solute and the solvent in solutions composed of the following: 5.00 g of sodium chloride (table salt) and 50.0 g of water

sodium chloride solute; water solvent

Henry's law states that

solubility of gas in liquid is directly proportional to partial pressure of gas over liquid

Indicate whether each of the following solutes will be soluble in the indicated solvent (in parentheses) CH3OH mixed with water (H2O)

soluble

Indicate whether each of the following solutes will be soluble in the indicated solvent (in parentheses) N2 mixed with methane (CH4)

soluble

Indicate whether each of the following solutes will be soluble in the indicated solvent (in parentheses) NH3 mixed with water (H2O)

soluble

Consider two solutions, A and B, separated by an osmotic semipermeable membrane that allows only water to pass through Based on each of the following identities for solutions A and B, indicate whether the liquid level in compart- ment A, with time, will increase, decrease, or not change. A = 2.0 M KCl solution and B = 2.0 M KNO3 solution

not change

catalysts do

not change anything about bonds in reaction

Strong acids will!

not create buffers because there is no equilibrium

Equilibrium is like

not static, but is highly dynamic situation.

Nonacidic hydrogen atoms are

not written at front of chemical formula

So nuclear chemistry =

now protons & neutrons are getting involved

theraputic criteria

now we want to destroy [not protect]

bombardment reaction

nuclear reaction brought about by bombarding stable nuclei w small particles traveling at very high speeds.

Transmutation reaction

nuclear reaction in which nuclide of 1 element is changed into nuclide of another element.

Radioactive nuclide/radionuclide

nuclide w unstable nucleus from which radiation is spontaneously emitted.

Transuranium elements

occur right after uranium on periodic table [elements 93 to 118]

Ionization

occurs when radiation carries enough energy to remove an electron from atom or molecule.

in a chemical reaction, Different isotopes

of an element have identical chemical properties

in a nuclear reaction, Different isotopes

of element have diff nuclear properties

in a nuclear equation, the elemental symbols

on both sides of equation frequently are not same

the effect of 1 mole of NaCl

on colligative properties will be twice that of 1 mole of glucose

in a nuclear reaction, the number

on left & right have to add up

For chemical equilibrium

on molecular level, there is frantic activity

[osmosis] Because there is a greater concentration of solute molecules

on one side of membrane than on other, flow rates differ.

if two cups have same amount but diff concentration [diff amount of water]

one is concentrated & one is dilute

What would be considered large for equilibrium constant?

one million

A conjugate acid has...

one more H in formula & increase in charge by one unit

alpha decay =

one of products is 4He2

Pressure influences an equilibrium

only if 1 or more of substances involved is a gas

pH and sig figs

only place sig figs show up in pH is after the decimal

A change in temperature is

only thing that leads to new equilibrium constant K

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other NaCl

other

OILRIG

oxidation is loss; reduction is gain

Redox reactions involve a change in

oxidation state for one or more elements

Loss of electrons

oxidized

Mg -> MgO

oxidized so is reducing agent

The substance that causes the oxidation is

oxidizing agent

in S(s) + O2(g) -> SO2(g) oxygen

oxidizing agent

Match each of the following statements about the dis- solving of the ionic solid NaCl in water with the term hydrated ion, hydrogen atom, or oxygen atom. The portion of a water molecule that is attracted to a Na+ ion

oxygen atom

Combustion reactions are always characterized by

oxygen being one of the reactants

Anytime there is

oxygen in reaction, will be combustion

For the following reaction, identify which element is reduced 2C2H6 + 7O2 -> 4CO2 + 6H2O

oxygen is reduced

pH =

pH = -log[H3O^+]

When acid or base is added to buffer,

pH change is small

if have glass with NaOH & pH 7 if you add base,

pH go up

the more H ions [more acidic]

pH value gets lower

if have glass with HCl & pH 7 if you add acid,

pH will go down

The defining equation for the calculation of a pKa value is

pKa = −log Ka

acidic hydrogen atoms do what?

participate in acid-base reactions

alpha particle

particle in which 2 protons & 2 neutrons are present that is emitted by certain radioactive nuclei

conjugate base =

partner base

The term osmosis implies

passage of solvent only.

Tell me what osmosis is

passage of solvent through semipermeable membrane separating dilute solution [or pure solvent] from more concentrated solution

Number of digits [pH]

past decimal in pH value determines number of sig figs in [H3O+] or [OH-]

Beta Particle Effects can

penetrate much deeper than alpha particles & can cause severe skin burns if source remains in contact w skin for appreciable amount of time

If you dissolve HCl in water,

precedes 100% to right

Why is the vapor pressure of a solution that contains a nonvolatile solute always less than that of pure solvent?

presence of solute molecules decreases ability of solvent molecules to escape

solvent

present in greatest amount

solute

present in lesser amount; substance being dissolved

It is the total number of particles (ions or molecules

present in solution that determines magnitude of colligative property effect.

What is the effect of pressure on liquids?

pressure has little effect on solubility of liquids in water

What is the effect of pressure on solids?

pressure has little effect on solubility of solids in water

What is the effect of pressure on gases?

pressure has major effect on solubility of gases in water

Buffer do what?

prevent major changes in solution pH when small amounts of acid or base are added to it

Chemical reaction is

process in which at least 1 new substance is produced as result of chemical change

supersaturated solution will

produce crystals rapidly, often in dramatic manner, if slightly disturbed or if "seeded" w tiny crystal of solute

bronsted-lowry acid and Bronsted-lowry base

production must occur simultaneously [can't have one without other]

What circumstances have to exist for 2 things to react & make new thing?

properties have to bump into each other/collide at right orientation & need exactly right energy

Brønsted-Lowry base

proton acceptor

Brønsted-Lowry acid

proton donor

Conjugate base is the species formed when

proton is accepted by Bronsted-Lowry base

Catalysts increase reaction rates by

providing alternative reaction pathways that have lower activation energies than original, uncatalyzed pathway

"ionize" =

pull electrons off of it

gamma ray is like

pure energy

Non - ionizing radiation

radiation w insufficient energy to remove electron from atom or molecule

in ionizing radiation, after the radiation removes electron from atom or molecule

radiation w slightly decreased energy will interact w another atom

"spontaneous emission of either energy of a particle =

radioactivity

Radioactive nuclide aka

radionuclide

The largest source of background radiation exposure, for the average American, is

radon gas

Solution formation occurs more

rapidly as temp is increased.

How will the following action affect a reaction rate? decrease the concentration of a reactant

rate decreases

How will the following action affect a reaction rate? decrease the surface area of a solid reactant

rate decreases

How will the following action affect a reaction rate? add a catalyst

rate increases

Predict the solubility of each of the following solutes in the solvent indicated. AgNO3 (an ionic solid) in water

soluble

Classify each of the following reactions using one selection from the choices redox and nonredox combined with one selection from the choices combination, decomposition, displacement, exchange, and combustion Zn + Cu(NO3)2 -> Zn(NO3)2 + Cu

redox & displacement

Fe (s) + Cu2+ (aq) -> Fe2+ (aq) + Cu (s)

redox bc change in ion charges

C6H12O6 + 6O2 -> 6CO2 + 6H2O

redox reaction

Fe(s) + Cu^2+ -> Fe^2+ Cu(s)

redox reaction

Loss of oxygen

reduced

For each of the following NaOh solutions, the volume of the solution and its molarity are given. Calculate the number of moles of NaOh present in each solution. 0.800 L solution, 0.100 M

0.0800 moles

What is the mass-volume percent glucose concentration in blood plasma if the glucose concentration is known to be 92 mg/dL?

0.092% (m/v) glucose

Name some acids

1) Acetic acid [vinegar] 2) citric acid [tartness in lemons]

Name some bases

1) Bleach 2) Drano

What are the group IIA strong hydroxide bases?

1) Ca(OH)2 2) Sr(OH)2 3) Ba(OH)2

Diagnostic: criteria

1) Low concentration 2) Short half life 3) Know mechanism for eliminations 4) Known chemical properties

Collision theory involves

1) Molecular Collisions 2) Collision Orientation 3) Activation Energy

In a molarity problem you need 2 things:

1) Moles of solute 2) Liters of solution

What are the conjugate acid-base pairs in the reaction NH3(g) + H2O(l) <=> NH4^+(aq) + OH^-(aq)

1) NH3 and NH4^+ 2) H2O and OH^-

What is the molarity of the solution prepared by concentrating, by evaporation of solvent, 2212 mL of 0.400 M K2SO4 solution to a volume of 853 mL?

1.04 M

What is the hydrogen ion concentration of a solution with pH = 10.75?

1.8 x 10^-11

How many grams of KCl are present in 250.0 grams of a 7.50 % (m/m) KCl solution?

1.88 x 10^1 g KCl

What is the osmolarity of the following solution? 2 M CaCl2

6 osmol

What is the osmolarity of the following solution? 2 M in both NaCl and glucose

6 osmol

The dL volume unit is equivalent to

100 mL

What is the pH of a solution of 0.0100 M NaOH?

12.00

how many grams of sucrose (table sugar, C12H22O11) are present in 185 mL of a 2.50 M sucrose solution?

158 g C12H22O11

Give me a conversion factor for the percent concentration 15%(m/m) NaCl solution

15g NaCl/100g solution

how many grams of NaCl are present in 50.0 mL of a 7.50%(m/v) NaCl solution?

3.75 g

Calculate the number of moles of solute in 26.75 mL of 0.1405 M K2Cr2O7(aq)

3.77 x 10^-3 mol

How many grams of solute are present in 725 mL of 0.460 M KBr?

3.97 x 10^1 g

Determine the %(m/m) of glucose when 10.0 g of ethanol is added to 40.0 g of water

20.0

For each of the following aqueous NaCl solutions, the mass of solute and the mass of solvent present are given. Calculate the mass percent of NaCl present in each solution. 10.0 g NaCl, 40.0 g H2O

20.0% (m/m)

for a solute to dissolve in a solvent

2 types of interparticle attractions must be overcome [solute-solute attractions & solvent-solvent attractions]

If [H3O^+] = 1.00 x 10^-8, then pH=

8

For the following reaction, indicate which substance is oxidized and which substance is reduced. Identify the oxidizing and reducing agents. Ca + Cl2 → CaCl2

Ca is oxidized [reducing agent] and Cl2 is reduced [oxidizing agent]

Give the conjugate base for the acid below: H3PO4

H2PO4^-

Write the chemical formula of each of the following. The conjugate base of H3PO4

H2PO4^-

Write an equation for each of the following buffering actions. The response of H2PO4^−/HPO4^2− buffer to the addition of h3O+ ions

H2PO4^2- + H3O^+ -> HPO4^- + H2O

Identify which substance is the oxidizing agent and which substance is the reducing agent in each of the redox reactions 3H2SO3 + 2HNO3 -> 2NO + H2O + 3H2SO4

H2SO3 reducing agent; HNO3 oxidizing agent

Give the formula for the conjugate acid of HSO4^-

H2SO4

Write the balanced molecular equation for the neutralization reaction between H2SO4 and KOH in aqueous solution

H2SO4 + 2KOH -> K2SO4 + 2H2O

Le Chatelier's Principle

If stress is applied to system in equilibrium, system will readjust in direction that best reduces stress imposed on system

synthetic elements

Over 2000 bombardment produced radionuclides are known.

Assign an oxidation number to each element in the following compounds or polya- tomic ions. P2O5

P = +5, O = -2

Two liquids react faster than a liquid and a gas

More contact between the reactants.

Which of the following will be soluble in Hexane (C6H12) C2H6 More than one correct answer N2 CH3OH

More than one correct answer

When acid is added to this buffer H3O^+ + C2H3O2^- ⇔ HC2H3O2 + H2O

Most of H3O^+ added is converted to HC2H3O2 and pH changes very little.

When base is added to this buffer HC2H3O2 + OH^- ⇔ C2H3O2^- + H2O

Most of OH^- added reacts w acid & is converted to H2O and pH changes very little.

Which of the following aqueous solutions would give rise to a greater osmotic pressure? 7.00 g of NaCl in 775 mL of solution or 6.00 g of NaBr in 275 mL of solution

NaBr

NaCl has...

Na^+ and Cl^-

NH3 (aq)+H2O(l)→NH4+ (aq)+OH- (aq) here water is

acid

Using the Arrhenius theory, classify the following as either an acid or a base: CH3NH3^+

acid

Acid A has a pKa value of 4.23, and acid B has a pKa value of 3.97. Which of the two acids is stronger?

acid B

in buffers,

acid absorbs the base & vice versa

What is constantly changing for a system in a state of chemical equilibrium?

actual reactant molecules present

to create a conjugate acid,

add hydrogen

This results in a decreased vapor pressure for the solution

adding solute to solvent

Which of the following chemical equations is that for an acid-base neutralization reaction? a. H2SO4 +Zn -> ZnSO4 +H2 b. HNO3 +KOH -> KNO3 + H2O c. AgNO3 + NaCl -> AgCl + NaNO3 d. no correct response

b

ionizing radiation =

bad; makes them die

Cl^- is

base bc can accept

Strong acids/bases are

better electrolytes than weak acids/bases bc strong acids come completely apart when put in water

Chemical Reactions occur

between electrons

All nuclides of all elements

beyond bismuth [Z = 83] in periodic table are radioactive

if the number on top is

big & bottom is small, equilibrium constant will be big

alpha particle size

big [so can't go very fast]

14N7 + 4α2 -> 17O8 + 1p1

bombardment reaction

Combustion reaction

chemical reaction between substance & oxygen [usually from air] that proceeds w evolution of heat & light [usually from flame]

HClO3

chloric acid

Classify each of the following reactions as a combination, decomposition, displacement, exchange, or combustion reaction. K2CO3 -> K2O + CO2

decomposition

Classify the following reaction: Ba(ClO3)2 -> BaCl2 + 3O2

decomposition

What general reaction type is characterized by there being a single reactant?

decomposition

Classify each of these reactions: Ba(ClO3)2 -> BaCl2 + 3O2

decomposition & redox

2H2O -> 2H2 + O2

decomposition reaction

BaCO3(s) -> BaO(s) + CO2(g) is what type of reaction?

decomposition reaction

XY -> X + Y

decomposition reaction

Indicate to which of the following types of reactions each of the statements listed applies: combination, decomposi- tion, displacement, exchange, and combustion. More than one answer is possible for a given statement. An element may be a product.

decomposition, displacement

Consider two solutions, A and B, separated by an osmotic semipermeable membrane that allows only water to pass through Based on each of the following identities for solutions A and B, indicate whether the liquid level in compart- ment A, with time, will increase, decrease, or not change. A = 1.0 M NaCl solution and B = 2.0 M NaCl solution

decrease

Consider two solutions, A and B, separated by an osmotic semipermeable membrane that allows only water to pass through Based on each of the following identities for solutions A and B, indicate whether the liquid level in compart- ment A, with time, will increase, decrease, or not change. A = 1.0 M glucose solution and B = 1.0 M NaCl solution

decrease

Indicate whether each of the following actions will increase or decrease the rate of dissolving of a sugar cube in water. Cooling the sugar cube-water mixture

decrease

Will the changes listed increase or decrease the rate of the following chemical reaction? 2CO + O2 -> 2CO2 Lowering the temperature of the reaction mixture

decrease

Will the changes listed increase or decrease the rate of the following chemical reaction? 2CO + O2 -> 2CO2 removing some CO from the reaction mixture

decrease

Indicate the effect of the following on the rate of this reaction: 3H2 (g) + N2 (g) -> 2NH3 (g) Decrease concentration of N2

decrease rate

When red blood cells are placed in a hypotonic solution

hemolysis occurs

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 0.92%(m/v) glucose solution

hemolyze

Why does adding solute increase boiling point?

higher temp will be needed to raise depressed vapor pressure of solution to atmospheric pressure

A solution is

homogeneous mixture of 2 or more substances

proticity

how many H an acid has

generally in a solution

dissolved solutes are present as individual particles [molecules, atoms or ions]

for mass-volume percent, "volume of solution" goes on bottom

do not add together on bottom bc diff units

Most molecular solutes

do not produce ions or charged particles when dissolved in water

For percent by mass & percent by volume,

do not put 100% in calculator [put percent in answer]

Increasing the pressure associated with an equilibrium system by adding an inert gas (a gas that is not a reactant or a product in the reaction)

does not affect position of equilibrium.

Dilution with water

does not alter numbers of moles of solute present

Nonpolar oil

does not interact w polar water

Value of Ka

does not tell you if acid is dangerous

Adding an inert gas

doesn't affect the equilibrium.

Kw value

doesn't change bc it's a constant

in a reaction, catalyst

doesn't move you to left or right

Strong acids...

don't exist in equilibrium

oil and water

don't mix

in HF + H2O <=> H3O^+ + F^- HF

donates H to water molecule

in terms of electron transfer: oxidizing agent

electrons gained

in terms of electron transfer: reducing agent

electrons lost

CO2 + H2O + heat -> C6H12O6 + O2 is example of

endothermic reaction

What is happening in an endothermic reaction?

energy is absorbed

In an exothermic reaction,

energy is product of reaction [ex: burning of fuel]

in an endothermic reaction,

energy is reactant in reaction [ex: photosynthesis in plants]

What is happening in an exothermic reaction?

energy is released

The charge-balance requirement for a solution of ions requires that

equal equivalents of positive and negative ions are present

[osmosis] The net transfer of solvent across the membrane continues From this point on, there is

equal flow of solvent in both directions across membrane & volume of liquid on each side of membrane remains constant.

If 25.0 mL of 1.0 M NaOh is needed to completely react with 25.0 mL of a monoprotic acid in an acid-base titration, the molarity of the acid is

equal to 1.0 M

in equation with weak electrolytes

equilibrium between undissociated form & ions in aqueous(aq) solutions

Keq =

equilibrium constant

acid ionization constant

equilibrium constant for reaction of weak acid w water.

Kw

equilibrium constant for water

for weak acids, the

equilibrium constant is really small

Products high

equilibrium constant really high; reactions go to right

HF + H2O <=> H3O^+ + F^- if H3O^+ on right side goes down

equilibrium goes to right; pH stays same

Tell me about the equilibrium in H2O(l) + H2O <=> H3O^+ + OH^-

equilibrium lies really far to left

HF + H2O <=> H3O^+ + F^- is

equilibrium process

The reaction between nitrogen and hydrogen to produce ammonia is described as

equilibrium reaction

If you add acid or base to water,

equilibrium will shift so product will always be 1.0 x 10^-14

H2CO3(aq) + H2O(l) <=> HCO3^-(aq) + H3O^+(aq) What will happen to the equilibrium if the amount of carbonic acid is decreased?

equilibrium will shift to left

H2CO3(aq) + H2O(l) <=> HCO3^-(aq) + H3O^+(aq) What will happen to the equilibrium if the concentration of bicarbonate ion is decreased?

equilibrium will shift to right

if Value of Keq is very large (10^30) what is Relative Amount of Products and Reactants & Description of Equilibrium Position

essentially all products & far to the right

ethanol is a polar solvent and carbon tetrachloride is a nonpolar solvent. In which of these two solvents are each of the following solutes more likely to be soluble? NaCl, ionic

ethanol

ethanol is a polar solvent and carbon tetrachloride is a nonpolar solvent. In which of these two solvents are each of the following solutes more likely to be soluble? Sugar, polar

ethanol

true or false? if the energy of the products is higher than the energy of the reactants, the reaction is exothermic

false [if product energy is higher, it's endothermic]

A very small value for an equilibrium constant characterizes a chemical reaction where the equilibrium position lies

far to the left

"smaller"

faster reaction

Two liquids react

faster than a liquid and a gas

nuclear medicine

field of medicine in which radionuclides are used for diagnostic & therapeutic purposes

How much product do you make before you start going backward?

find out by measuring concentrations

for example if this is the problem: Determine the pH of the following solution: 1.0 × 10^-4 M OH^-

first find H3O^+ then find pH

To go from pH to

hydrogen of concentration, use 10^ button on calculator

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 0.28 M NaCl

hypertonic

causes cells to hemolyze/burst

hypotonic

osmotic pressure relative to body fluids is less than

hypotonic

Polar vs nonpolar

if same, will mix

DISSOCIATION: The process whereby,

in aqueous solution, positive & negative ions are released from ionic compound.

Like dissolves like works

in general

Indicate whether each of the following actions will increase or decrease the rate of dissolving of a sugar cube in water. Crushing the sugar cube to give a granulated form of sugar

increase

Indicate whether each of the following actions will increase or decrease the rate of dissolving of a sugar cube in water. Stirring the sugar cube-water mixture

increase

Oxidation involves

increase in oxidation number.

Indicate the effect of the following on the rate of this reaction: 3H2 (g) + N2 (g) -> 2NH3 (g) Increase concentration of H2

increase rate

What is the effect of temperature on gases?

increase temp = gas solubilities in water decrease

The more you increase

increase temperature, more soluble [for solids in liquids]

In general, the solubilities of gaseous solutes in water

increase with increasing pressure

Decreased volume

increased pressure

The rate at which a chemical reaction occurs decreases as the activation energy

increases

Increased available surface area

increases likelihood of reactant collisions.

dilution has

indirect relationship

Predict whether the following compound is soluble or insoluble in water: AgI

insoluble

in osmosis, the rate of flow

into concentrated solution is greater than rate of flow in other direction

In an aqueous solution of a weak acid, HA, the concentration of A^− ion

is equal to that of H^+

in a nuclear reaction, The nuclear reactivity of an element

is independent of state of chemical combination.

Mixing an ionic substance with a nonpolar substance

is like mixing polar w nonpolar

What actually changes when acid or base is added to this buffer: HC2H3O2/C2H3O2^-

is proportion of HC2H3O2 to C2H3O2^-

Not every compound

is soluble in water bc the ionic bonds are too strong

Indicate whether the osmotic pressure of a 0.1 M NaCl solution will be less than, the same as, or greater than that of each of the following solutions. 0.1 M MgCl2

less

The mass of solute per 100 mL of solution is abbreviated as

m/v

Hydrocarbons

made of only hydrogen & carbon

Group 1 and ammonium

makes bond weak

little p

makes things backward [pH, pKa]

Mass of solution =

mass of solute + mass of solvent

%(m/v)

mass of solute(g)/volume of solution(mL) x 100

%(m/m)

mass of solute/mass of solution x 100

The percent concentration unit most often encountered in a hospital (medical) setting is

mass-volume percent

As [H3O+] goes down

means less hydrogen ions so pH goes up [more basic]

The largest source of radiation exposure from human activities, for the average American, is

medical X-rays

Semi-permeable membrane is what?

membrane that allows certain types of molecules to pass through it but prohibits passage of other types of molecules

Salt =

metal & nonmetal

The more you stir it,

more soluble

hypertonic solution will cause the

net transfer of water from tissues to blood

Nonacidic hydrogen atoms do

not participate in acid-base reactions

The presence of water is

not prerequisite for a solution

Nonelectrolytes do

not produce ions in water [do not conduct an electric current]

Acids do...

not react w other acids

Indicate whether each of the following solutes will be soluble in the indicated solvent (in parentheses) CCl4 mixed with water (H2O)

not soluble

Acid A is weaker than acid B if, at equal concentrations,

percent ionization of A is less than that of B

HClO4

perchloric acid

HCl has

permanent dipole

For which of the following types of ionic compounds are most examples insoluble in water? a. nitrates b. phosphates c. acetates d. no correct response

phosphates

Chemical equilibrium is similar to

physical equilibrium of evaporation & condensation of liquid in closed container

colligative properties

physical property of solution that depends only on number of solute particles [molecules or ions]present in given quantity of solvent & not on their chemical identities

geiger counters only

pick up gamma rays

Is H2O polar or nonpolar? Why?

polar bc angular/bent molecular geometry

NH3 gas is

polar gas [much more soluble in H2O [polar liquid] than is O2 gas [nonpolar gas]

Water is a

polar molecule

Like dissolves like works in general

polarity of water [+ & - ends] suggests all ionic compounds would be soluble

How will the following action affect a reaction rate? increase the temperature

rate increases

What condition must be met in order for a system to be in a state of chemical equilibrium?

rate of forward reaction = rate of reverse reaction

If the concentration of a reactant increases,

rate of forward reaction increases until equilibrium is reestablished

If the concentration of a product decreases,

rate of reverse reaction increases until equilibrium is reestablished

chemical reaction rate is what?

rate which reactants are consumed or products produced in given time period in chemical reaction

Enzymes control

rates of reaction

Liquid & gas

react faster than solid & gas

equilibrium constant for C(s) + h2O(g) -> CO(g) + h2(g) is [CO][H2]/[H2O]

reactant carbon (C) is solid so will not appear in equilibrium constant expression.

Molecular collisions is like

reactant molecules, ions or atoms must come in contact [collide] w one another in order for any chemical change to occur

You can think of heat as

reactant or product whose increase or decrease stresses equilibrium just as change in reactant or product concentration does

HA(aq) + H2O(l) ⇔ H3O+(aq) + A-(aq) tell me about this reaction

reactants high; products low [equilibrium lies far to left]

Le Chatelier's Principle says When disruption causes more

reactants to form, equilibrium has shifted to left

in equilibrium,

reaction hasn't stopped [just doing at same rate in both directions]

Nuclear reaction is

reaction in which changes occur in nucleus of atom

combustion:

reaction of anything w O2

When reactants are all the same physical state,

reaction rate is generally faster

When the particle size of a solid is extremely small,

reaction rates can be so fast that explosion results.

Most Acid Base

reactions reach equilibrium

"same state"

reacts faster

Unstable nucleus

readily undergoes change

Concentrations are

really small

By using oxidation numbers, determine whether the following reaction is a redox reac- tion or a nonredox reaction. 4NH3 + 3O2 -> 2N2 + 6H2O

redox

Classify each of the following reactions as (1) a redox reaction (2) a nonredox reaction or (3) "can't classify" because of insufficient information A combination reaction in which one reactant is an element

redox

Classify each of the following reactions as (1) a redox reaction (2) a nonredox reaction or (3) "can't classify" because of insufficient information A decomposition reaction in which one of the products is an element

redox

Classify each of the following reactions as (1) a redox reaction (2) a nonredox reaction or (3) "can't classify" because of insufficient information A decomposition reaction in which the products are all elements

redox

Fe2O3 (s) + 3 CO (g) → 2 Fe (s) + 3 CO2 (g)

redox

Classify each of the following reactions using one selection from the choices redox and nonredox combined with one selection from the choices combination, decomposition, displacement, exchange, and combustion CH4 + O2 -> CO2 + 2H2O

redox & combustion

Different isotopes of an element have

same chemical properties but different nuclear properties

isotonic =

same concentration inside and outside

Tell me a rule for solubility

same polarity = soluble

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 0.14 M in both glucose and sucrose

same size

The processes of replacing body fluids and supplying nutrients to the body intravenously require

use of isotonic solutions

example: What is the molarity (M) of a solution prepared by diluting 0.180 L of 0.600 M HNO3 to 0.540 L? "of" = they go together on one side

so .180 and .600 go on same side

According to Le Chatelier, pressure

system will shift away from added gaseous component [If component is removed, opposite effect occurs]

in equilibrium constant expressions!

take coefficient & add as exponent

Identify the solute and the solvent in solutions composed of the following: 2.00 mL of water and 20.0 mL of ethyl alcohol

water solute; ethyl alcohol solvent

As the amount of solute & solvent changes,

way it conducts electricity will be very diff

Most solutions

we encounter fall under category of unsaturated solution

HF is very

weak [almost all reactant; very small concentration of product]

HA + H2O <——- ->H3O^+ + A^- is showing

weak acid

Identify each of the following as a strong or weak acid or base. HNO2

weak acid

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other H3PO4

weak acid

One mole of any molecular solute raises the boiling point of one kilogram of water by the same amount,

which is 0.51°C

Decreasing the surface area

will allow fewer particles to collide, decreasing the reaction rate

A crushed aspirin tablet

will dissolve in water more rapidly than a whole aspirin tablet.

Water is the

universal solvent

A radionuclide has a half-life of 6.0 hr. What fraction of the atoms in a sample of this radionuclide will remain undecayed after the following times? a. 12 hr b. 36 hr c. 3 half-lives d. 6 half-lives

a) 1/4 b) 1/64 c) 1/8 d) 1/64

Calculate the ph of solutions with the following hydroxide ion concentrations. a. 1.00 × 10^−4 M b. 1.00 × 10^−10 M c. 1.11 × 10^−3 M d. 6.05 × 10^−7 M

a) 10.000 b) 4.000 c) 11.045 d) 7.782

lodine-125 has a half-life of 60 days. How long, in days, will it take for the radiation level of an iodine-125 sample to drop to a. one-fourth its original level b. 1/16 its original level

a) 120 days b) 240 days

Ca + Cl2 -> CaCl2

Ca -> Ca^2+ and Cl2 -> 2Cl^-

H3O^+ is the conjugate acid of

H2O

Colligative molarity of Al(NO3)3 using: solution A = 0.10 M Al(NO3)3 (aq)

4(0.10 M) = 0.40 M

if the original pH problem says: "1.0 x 10^-4" and answer is 4. How should you write it?

4.00

The defining equation for percent-by-volume concentration is

(volume solute/volume solution) × 100

polarity of water

+ and - ends

Determine the oxidation number of the indicated ele- ment in each of the following ions. Al in Al^3+

+3

pKa =

-log Ka

Iodine-131 is a radionuclide that is frequently used in nuclear medicine. Among other things, it is used to detect fluid buildup in the brain. The half-life of iodine-131 is 8.0 days. How much, in grams, of a 0.16-g sample of iodine-131 will remain undecayed after a period of 32 days?

.010 g

What is the oxidation number of S in each of the following molecules? S2

0

What is the molarity of the solution prepared by diluting 25.0 mL of 0.220 M NaCl to each of the following final volumes? 457 mL

0.0120 M

What is the molarity of the solution prepared by diluting 25.0 mL of 0.220 M NaCl to each of the following final volumes? 75.0 mL

0.0733 M

What is the molarity of the solution prepared by diluting 25.0 mL of 0.220 M NaCl to each of the following final volumes? 30.0 mL

0.183 M

What is the molarity (M) of a solution prepared by diluting 0.180 L of 0.600 M HNO3 to 0.540 L?

0.200 M

Calculate the mass percent of solute in the following solutions. 0.0032 g of NaOH dissolved in 1.2 g of H2O

0.27% (m/m)

For each of the following NaOh solutions, the volume of the solution and its molarity are given. Calculate the number of moles of NaOh present in each solution. 1.35 L solution, 0.300 M

0.405 moles

how many grams of Na2CO3 are needed to prepare 25.0 mL of a 2.00%(m/v) Na2CO3 solution?

0.500 g

If you have a 0.250 M solution of CaCl2 what is the concentration of Cl^- ions?

0.500 moles Cl^-

For each of the following NaOh solutions, the volume of the solution and its molarity are given. Calculate the number of moles of NaOh present in each solution. 875 mL solution, 0.600 M

0.525 moles

For each of the following hCl solutions, the moles or grams of solute present and the total solution volume are given. Calculate the molarity of each solution. 30.0 g HCl, 1.45 L solution

0.567 M

how many equivalents of Ca2+ ion are present in a solution that contains 0.30 mole of Ca2+ ion?

0.60 Eq

The osmolarity of a 0.40 molar NaCl solution is

0.80

2 Things Can Happen to an Electron Subjected to Radiation

1 Excitation 2) Ionization

1 g/dL =

1 g/100 mL = 1%(m/v)

The density of water is approximately

1 g/mL

The results of dissolving these solutes in water are: CaCl2

1 mole of CaCl2 produces 3 moles of particles [ions] when dissociation occurs.

Two moles of ions are produced from

1 mole of NaCl

Kw = what?

1.0 × 10^-14

For each of the following aqueous NaCl solutions, the mass of solute and the mass of solvent present are given. Calculate the mass percent of NaCl present in each solution. 5.00 g NaCl, 355 g H2O

1.39% (m/m)

The pH of a solution is 5.85. What is the [H3O+] for this solution? [H3O+] = 10^-pH

1.4 x 10^-6

The ph of a solution is 6.80. What is the molar hydronium ion concentration for this solution?

1.6 x 10^-7

How many grams of Na2CO3 are present in 35.0 mL of 5.00 % (m/v) solution?

1.75 g Na2CO3

If a weak acid has a pKa value of 8.73, what is the value of Ka for the acid?

1.9 x 10^-9

After three half-lives have elapsed, the amount of a radioactive sample which has not decayed is which of the following?

1/8 the original amount

Write equilibrium constant expressions for the following reactions. Ca(s) + Cl2(g) -> CaCl2(s)

1/[Cl2]

Write equilibrium constant expressions for the following generalized reactions. 2X(g) + 3Y(g) -> 2Z(s)

1/[X]^2 [Y]^3

how many grams of sucrose must be added to 375 g of water to prepare a 2.75%(m/m) solution of sucrose?

10.6 g sucrose

how many liters of a 0.100 M solution can be prepared from 60.0 g of each of the following solutes? KOH

10.7 L

92mg glucose/1 dL solution x 10^-3 g glucose/1 mg glucose x 1 dL solution/100 mL solution

100 in 100 mL is not used in obtaining numerical answer bc definition for mass-volume percent is g solute/100 mL solution.

A 2.0%(m/v) NaCl solution contains 2.0 g of NaCl per

100.0 mL solution

What is the boiling point of a solution that contains 0.25 mole of the ionic solute NaBr per one kilogram of water?

100.26 degrees celsius

What is the boiling point of a solution that contains 1.00 kg of water and each of the following quantities of solute? 3.00 moles of NaCl (an ionic compound)

103.06 degrees celsius

What is the boiling point of a solution that contains 1.00 kg of water and each of the following quantities of solute? 3.00 moles of Na3PO4 (an ionic compound)

106.12 degrees celsius

[H3O^+] =

10^- pH

How many milliliters of ethanol are needed to prepare 125 mL of a 8.5% (v/v) solution?

11 mL ethanol

Strontium-90 is a nuclide found in radioactive fallout from nuclear weapon explosions. Its half-life is 28.0 years. How long, in years, will it take for 94% (15/16) of the strontium-90 atoms present in a sample of material to undergo decay?

112 years

How many grams of CaCl2 are needed to make 276.4 g of a solution that is 41.5% (m/m calcium chloride in water?

115 g CaCl2

Calculate pH for each H3O^+ concentration: [H3O^+] = 1 x 10^-13 M

13.0

What is the (v/v) % of a solution if 15.0 mL of ethanol is added to 95.0 mL of water?

13.6% (v/v)

If the half-life of a 2.0-gram sample of a radionuclide is 14 hours, then the half-life of a 1.0 gram sample of the same radionuclide would be

14 hours

how many liters of a 0.100 M solution can be prepared from 60.0 g of each of the following solutes? LiCl

14.2 L

How many grams is 15 mL of water?

15 g

What volume of a 2.00% (m/v) HCl solution can be prepared by diluting 25.0 mL of 14.0% (m/v) HCl solution

175 mL

What is the percent by volume of isopropyl alcohol in an aqueous solution made by diluting 22 mL of pure isopropyl alcohol with water to give a volume of 125 mL of solution?

18% (v/v)

For each of the following solutions, how many milliliters of water should be added to yield a solution that has a concentration of 0.100 M? 2.00 mL of 1.00 M NaCl

18.0 mL

How many ions per the formula unit NaNO3

2

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) in this acid-base reaction, there are

2 conjugate acid-base pairs related by loss/gain of H^+

A solution contains

2 or more components

What is the osmolarity of the following solution? 2 M glucose

2 osmol

Diprotic acids supply

2 protons [H+ ions] during acid- base reaction

Colligative molarity of NaNO3 using: solution B: 0.20 M NaNO3 (aq)

2(0.20 M) = 0.40 M

Calculate pH for each H3O^+ concentration: [H3O^+] = 0.01 M

2.0

Sufficient acidic solute is added to a quantity of water to produce a solution with [H3O+] = 4.0 × 10^−3. What is the [OH−] in this solution?

2.5 x 10^-12

Calculate the molarity of a 10.0%(m/v) NaOH solution.

2.50 M

A 0.0100 M solution of an acid, HA, is 15% ionized. Calculate the acid ionization constant for this acid.

2.6 x 10^-4

What is the concentration of a solution made by diluting 35 mL of 6.0 M HCl to a final volume of 750 mL?

2.8 x 10^-1 M

The bombardment reaction involving 23Na11 and 2H1 gives two products, one of which is 1H1. The other product is

24Na11

Triprotic acids supply

3 protons [H+ ions] during acid-base reaction

Calculate the molarity of: 0.650 mol of NaOH in 1.85 L of solution

3.51 x 10^-1 M

Calculate the molarity of: 15.7 g of NaCl in 749 mL of solution

3.59 x 10^-1 M

After all of the water is evaporated from 10.0 mL of a CsCl solution, 3.75 g of solid CsCl remains. Calculate the original concentration of the CsCl solution in the following units. mass-volume percent

37.5% (m/v)

How many milliliters of a 5.75% (v/v) ethanol solution can be prepared from 2.25 mL of ethanol?

39.1 mL solution

Finish the reaction: 3H2 + N2

3H2 + N2 <=> 2NH3

How many ions per the formula unit Al(NO3)3

4

If [H3O^+] = 1.00 x 10^-4, then pH=

4

2 M NaCl =

4 mol NaCl/2 L solution

What is the osmolarity of the following solution? 2 M NaCl

4 osmol

Determine the final concentration of each of the following solutions after 20.0 mL of water has been added. 30.0 mL of 7.5 M NaCl solution

4.5 M

Calculate the volume percent of solute in each of the following solutions. 4.00 mL of bromine in enough carbon tetrachloride to give 87.0 mL of solution

4.60% (v/v)

A 0.00300 M solution of an acid is 12% ionized. Calculate the acid ionization constant Ka.

4.9 x 10^-5

Calculate the number of grams of NaOH needed to prepare each of the following amounts of solution. 1.00 L of 1.00 M NaOH

40.0 g

A nurse wants to prepare a 1.0%(m/v) silver nitrate solution from 24 mL of a 3.0%(m/v) stock solution of silver nitrate. how much water should be added to the 24 mL of stock solution?

48 mL

Write a balanced chemical equation for a totally gaseous equilibrium system that would lead to the following equi- librium constant expression Keq = [N2]^2[H2O]^6/[NH3]^4[O2]3

4NH3(g) + 3O2(g) <=> 2N2(g) + 6H2O(g)

What is the osmolarity of the following solution? 2 M in NaCl and 1 M in glucose

5 osmol

Consider the solution of KCl made by dissolving 100.0 g of solute in 250.0 mL of solution. Calculate the molarity.

5.370 M

For each of the following pairs of solutions, select the solution for which solute solubility is greatest. Ammonia gas in water with P = 1 atm and T = 50°C Ammonia gas in water with P = 1 atm and T = 90°C

50 degrees Celsius

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) what is the base?

H2O

Contrast alpha and beta particles in terms of how far they can travel in air before their energy is dissipated

6 cm vs 1000 cm

Calculate pH for each H3O^+ concentration: [H3O^+] = 1 x 10^-6 M

6.0

What is the (m/v) % of a solution of 5.8 g of KCl in 85 mL of solution?

6.8% (m/v)

For each of the following solutions, how many milliliters of water should be added to yield a solution that has a concentration of 0.100 M? 75.0 mL of 0.110 M NaCl

7.5 mL

After the addition of a small amount of acid, a solution that is buffered at a ph of 8.0 will have an approximate ph of

8.0

What is the osmolarity of each of the following solutions? 2.0 M in both KNO3 and NaCl

8.0 OsM

Calculate the ph for each of the following solutions. [OH−] = 1.0 × 10^−6

8.00

Determine the pH of the following solutions: 3.2 x 10^-6 M OH^-

8.51

For HF + H2O <=> H3O^+ + F^-

99.9% HF; 0.01% F^-

Soluble ionic compounds do!

dissociate into ions in solution.

Arrhenius theory says an acid

dissociates in water to produce hydrogen ions

Nonelectrolytes do what?

dissolve as molecules in water [does not dissociate]

Aqueous is like

dissolved in water

Substances burn

more rapidly in pure oxygen than in air

As the value of Ka gets bigger,

more reactant dissociates [equilibrium moves to right]

Synthetic radionuclides?

outnumber naturally occurring nuclides by a 7-to-1 ratio.

Hydroxide ions (the basic species) are produced through dissociation.

Arrhenius base

Metals tend

to lose electrons

HF(aq)+H2O(l)⇔H3O+ (aq)+F- (aq)

Acid base equilibrium

Consider the reaction shown below. CH4 + 2 H2S + heat <---> CS2 + 4 H2 What action will increase the amount of CH4?

Add H2 to the reaction

Freezing-point depression

Adding a nonvolatile solute to solvent lowers freezing point of resulting solution below that of pure solvent.

Identify the solute in: a solution containing 3.0 g of AgNO3 and 15 mL of water

AgNO3

AlCl3 has...

Al^3+ and 3Cl^-

bombardment reaction is

Always 2 reactants and 2 products.

Hydrogen ions (the acidic species) are produced through ionization.

Arrhenius acid

Consider this aqueous reaction: HNO3(aq) + Ba(OH)2(aq) -> What is the formula for the salt that forms?

Ba(NO3)2

Rank these compounds by their expected solubility in hexane, C6H14 from most to least soluble H2O, C2H6, C2H5OH

C2H6, C2H5OH, H2O

The chemical reaction that occurs when a hCN/CN− buffer system responds to the addition of a small amount of acid is

CN^− +H3O^+ -> H2O + HCN

3Ni^2+(aq) + 2Co(s) -> 2Co^3+(aq) + 3Ni(s) What is the reducing agent?

Co

3Ni^2+(aq) + 2Co(s) -> 2Co^3+(aq) + 3Ni(s) Which substance gets oxidized?

Co

Mg(s) + Cl2(g) -> Mg^2+(aq) + 2Cl^-(aq) What is the oxidizing agent?

Cl2

Mg(s) + Cl2(g) -> Mg^2+(aq) + 2Cl^-(aq) Which substance gets reduced?

Cl2

The physical properties of a solution that depend only on the concentration of solute particles in a given quantity of solute, not on the chemical identity of the particles.

Colligative properties of solutions

Acetic Acid/Sodium Acetate Buffer

Common laboratory buffer

To write Keq, it's the

Concentration of products divided by concentration of reactants

Cu(s) + 2AgNO3(aq) -> 2Ag(s) + Cu(NO3)2(aq) What is the reducing agent?

Cu

Cu(s) + 2AgNO3(aq) -> 2Ag(s) + Cu(NO3)2(aq) Which substance gets oxidized?

Cu

For the following reaction, indicate which substance is oxidized and which substance is reduced. Identify the oxidizing and reducing agents. Cu (s) + Pt2+ (aq) -> Cu 2+ (aq) + 2 Pt (s)

Cu is oxidized [reducing agent] and Pt is reduced [oxidizing agent]

Cu (s) + Pt2+ (aq) -> Cu 2+ (aq) + 2 Pt (s) What is happening to Cu and Pt here?

Cu lost 2 electrons; Pt^2+ gained 2 electrons

Fe(s) + Cu^2+(aq) -> Fe^2+(aq) + Cu(s) What is the oxidizing agent?

Cu^2+

Identify the Bronsted-Lowry base in the following reaction HF + H2O -> H3O^+ + F^-

H2O

What is the acid in H2O + NH3 → OH^- + NH4^+

H2O

the Addition of Catalysts

Do not change position of equilibrium but equilibrium is established more quickly

What is the base in HCl + H2O → Cl^- + H3O^+

H2O

Write the conjugate acid of each of the following: OH^-

H2O

If a reaction has

H2O(l), concentration can't change

Gamma ray

Form of high energy radiation without mass or charge that is emitted by certain radioactive nuclei.

Write equilibrium constant expressions for the following reactions. 2NOCl(g) -> 2NO(g) + Cl2(g)

[NO]^2[Cl2]/[NOCl]^2

Because self ionization is

an equilibrium, can write equilibrium constant [Kw = [H3O+] [OH-]

Write the equilibrium constant expression for each of the following reactions. C(s) + h2O(g) -> CO(g) + h2(g)

[CO][H2]/[H2O]

Which of the following pairs of substance could function as a buffer in aqueous solution? a. hCl and hF b. h2CO3 and NahCO3 c. Na2CO3 and NahCO3 d. no correct response

H2CO3 and NaHCO3

Fe(s) + Cu^2+(aq) -> Fe^2+(aq) + Cu(s) What is the reducing agent?

Fe

Fe(s) + Cu^2+(aq) -> Fe^2+(aq) + Cu(s) Which substance gets oxidized?

Fe

For the redox reaction FeO+CO -> Fe+CO2 identify the: oxidizing agent

FeO

Write the chemical formula of each of the following. The conjugate acid of HC2O4^−

H2C2O4

In N2(g) + 3H2(g) <- ——> 2NH3(g)

Here, increasing pressure favors product [2 moles of gas vs 4 moles of gas]

Physical nature of the reactants

Includes physical state of each reactant [s, l or g] & particle size

Which of the following is the correct equilibrium constant expression for the reaction 2D(s) -> 2E(s) + F(g)

[F]

Salt is like a what?

Ionic compound containing metal or polyatomic ion as positive ion & nonmetal or polyatomic ion [except hydroxide] as negative ion

in weak acids...

Ionization equilibrium lies far to the left

in strong acids...

Ionization equilibrium lies far to the right.

Suppose a reaction occurs that is at equilibrium, shown below A + B <---> C It is observed that the concentration of C in the mixture is much larger (100x) than the concentrations of A and B. What is true regarding the equilibrium constant [K] for this reaction?

K will have value much greater than 1

Assign an oxidation number to each element in the following compounds or polya- tomic ions. KMnO4

K= +1, Mn = +7, O =-2

Identify which substance is oxidized and which substance is reduced in each of the following redox reactions. Cl2 + 2KI -> 2KCl + I2

KI oxidized; Cl2 reduced

Identify the solute in: a solution containing 10.0 g of LiBr and 100.0 g of water

LiBr

Mg(s) + Cl2(g) -> Mg^2+(aq) + 2Cl^-(aq) What is the reducing agent?

Mg

Assign an oxidation number to each element in the following compounds or polya- tomic ions. NO3−

N = +5, O = -2

3Ni^2+(aq) + 2Co(s) -> 2Co^3+(aq) + 3Ni(s) What is the oxidizing agent?

Ni^2+

Identify the solute in: air (a solution of 78% N2, 21% O2 and various other gases)

O2

What situations describes a basic aqueous solution?

[H3O+] is less than [OH−]

Radioactivity

Radiation spontaneously emitted from unstable nucleus.

Background radiation

Radiation that comes from natural sources to which living organisms are exposed on continuing basis.

Example of theraputic criteria

Radiation therapy

The most efficient buffer will have

[HA] approximately equal to [A^-]

S (s) + O2 (g) → SO2 (g) What is happening here?

S gains oxygen

Write the equilibrium expression for the following H2 (g) + I2 (g) -> 2 HI (g)

[HI]^2/[H2][I2]

The general expression for the acid ionization constant for a weak acid, HA, is

[H^+][A^−]/[HA]

For each solute, identify the better solvent: water or carbon tetrachloride I2

carbon tetrachloride (CCl4)

nuclear reaction is when you're

changing # of protons & neutrons

H2 + I2 <=> 2HI

This reaction is at equilibrium

Half-life

Time required for 1/2 of given quantity of radioactive substance to undergo decay

Strong acid does what?

Transfers 100% of its protons to water

Write the equilibrium constant expression for each of the following reactions. I2(g) + Cl2(g) -> 2ICl(g)

[ICl]^2/[I2][Cl2]

What does the value of Ka tell us about the strength of an acid?

Weak acid has small value for Ka

oil requires

a nonpolar solvent

Which of the following is always a product of an acid-base neutralization reaction? a. an acid b. a base c. a salt d. no correct response

a salt

What does potassium iodide (KI) do when dissolved in water?

dissociates to potassium and iodide ions

Write balanced nuclear equations for the alpha decay of each of the following nuclides. a) 200Po84 b) Curium-240 c) 244Cm96 d) uranium-238

a) 200Po84 -> 4a2 + 196Pb82 b) 240Cm26 -> 4a2 + 236Pu94 c) 244Cm96 -> 4a2 + 240Pu94 d) 238U92 -> 4a2 + 234Th90

238U92 a) 238 is b) 92 is

a) mass number b) atomic number

in HNO3 and H2SO4

all hydrogen atoms are acidic

in NH3 and CH4

all hydrogen atoms are nonacidic

Electrolyte

anything that comes apart in solution

How do the neutron-to-proton ratios compare for stable nuclei of low atomic number and stable nuclei of high atomic number?

approx 1 to 1 ratio for low atomic numbered stable nuclei & 3 to 2 ratio for higher atomic numbered stable nuclei

polar + polar

dissolve

A solution is made by dissolving 34.0 g of NaCl in 100 g of h2O at 0°C. Based on the data in Table 8-1, should this solution be characterized as dilute or concentrated

concentrated

[for colligative property]The number of solute particles present in a solution

depends on concentration of solute present & whether solute breaks up [dissociates] into ions once in solution.

pKa is calculated

from Ka in exactly same way pH is calculated from [H3O^+]

In the process of osmosis, solvent passes through a semipermeable membrane

from a dilute solution to a more concentrated solution

in terms of electron transfer: reduction

gain of electrons

in Cu(s) + Pt^2+(aq) -> Cu^2+(aq) + 2Pt(s)

gained Pt so reduced [oxidizing agent]

the oxidizing agent does what?

gains electrons

The term radioactive nuclide designates an atom whose nucleus

is unstable

Has no effect on cell size.

isotonic

element 118, the highest-atomic-numbered laboratory-produced element, has a half-life measured in

milliseconds

Lower the pH,

more acidic

Which substance is the reducing agent in the following redox reaction? CO+H2O -> CO2 +H2 a. h2O b. CO2 c. h2 d. no correct response

no correct response

The numerical value for a colligative property is dependent on the

number of solute particles present

When the forward and reverse reaction

occur at same rate, write equation w arrow pointing in both directions.

With pH, the sum

of exponents has to be -14

Gain of oxygen

oxidized

Keq=

products/reactants

Classify each of the following reactions using one selection from the choices redox and nonredox combined with one selection from the choices combination, decomposition, displacement, exchange, and combustion 2CuO -> 2Cu + O2

redox & decomposition

H2O+H2O ⇔ H3O+ +OH- is an example of

self-ionization

Solutions can be!

separated by physical means

10^ button on calculator

shift log

what is a nonaqueous solution?

solution in which substance other than water is solvent

How do you know how far the reaction goes to the right or left?

the equilibrium constant

Why does the Reaction rate increase as the temperature of the reactants increase?

the faster particles fly around, higher the chance of effective collision

Generally, solutions are

transparent [clear]

How does energy relate to gas & bbq

won't turn to fire until light it [flame you provide is activation energy]

Acidic hydrogen atoms are!

written at front of chemical formula

is O2 soluble in water?

yes

1 M NaCl =

•1 mol NaCl/1 L solution •2 mol NaCl/2 L solution •0.5 mol NaCl/0.5 L solution

Weak acids do what?

Transfers small % of its protons to water.

define self-ionization

Water molecules in pure water interact w one another to form ions

What is the general chemical equation for Combination reaction

X + Y -> XY

What is the general chemical equation for each of the following types of chemical reactions? Displacement reaction

X + YZ -> Y + XZ

What is the correct equilibrium constant expression for the reaction 3C(g) -> A(g) + 2B(g)

[A][B]^2/[C]^3

Write the Keq of: 4NH3(g) + 7O2(g) -> 4NO2(g) + 6H2O(g)

[NO2]^4 [H2O]^6/[NH3]^4 [O2]^7

Write equilibrium constant expressions for the following reactions. 4NH3(g) + 5O2(g) -> 4NO(g) + 6H2O(g)

[NO]^4[H2O]^6/[NH3]^4[O2]^5

In general, it is found that the

greater the diff in solute-solvent polarity, less soluble

Strong vs weak

has nothing to do w toxicity or danger [for acids]

The reactant, O2, is an element and thus

has oxidation number of zero (rule 1).

"which produces a beta particle" =

has to be on right side

When we dissolve 1 mole of NaCl in 1 liter of water,

have 1 mole of chemical & 2 moles of charge [1 mole Na^+ & 1 mole Cl^-]

When we dissolve 1 mole of CaCl2 in 1 liter of water,

have 1 mole of chemical & 3 moles of charge [1 mole of Na^+ & 2 moles of Cl^-]

Solutions of equal osmolarity

have equal osmotic pressures.

For strong hydroxide bases,

have group IA hydroxides and group IIA hydroxides

in N2(g) + 3H2(g) <—— -> 2NH3(g) + Heat

heat is product [exothermic reaction] so adding heat shifts equilibrium to left.

Will red blood cells crenate, hemolyze, or remain unaffected when placed in 2.3%(m/v) glucose solution

hemolyze

unstable =

high energy

for therapy, you want

high energy & a short half life

Geiger counters

high energy ionizing radiation

Match each of the following statements about the dis- solving of the ionic solid NaCl in water with the term hydrated ion, hydrogen atom, or oxygen atom. A Cl− ion surrounded with water molecules

hydrated ion

Match each of the following statements about the dis- solving of the ionic solid NaCl in water with the term hydrated ion, hydrogen atom, or oxygen atom. A Na+ ion surrounded with water molecules

hydrated ion

HBr

hydrobromic acid

HCl

hydrochloric acid

Match each of the following statements about the dis- solving of the ionic solid NaCl in water with the term hydrated ion, hydrogen atom, or oxygen atom. The portion of a water molecule that is attracted to a Cl− ion

hydrogen atom

Anything with

hydrogen bonds will be soluble in water

How does water interact with sodium?

hydrogen interacts w the chlorine; oxygen interacts w the sodium

HI

hydroiodic acid

Which of the following statements concerning acidic and basic solutions is correct? a. Acidic solutions have positive ph values and basic solutions have negative ph values. b. Acidic solutions have a ph greater than 7 and basic solution have a ph less than 7. c. hydronium and hydroxide ions are present in both acidic and basic solutions. d. no correct response

hydronium and hydroxide ions are present in both acidic and basic solutions.

any base besides

hydroxide is weak

the strong bases are

hydroxides of groups IA and IIA [metal hydroxides]

Causes cells to crenate (shrink).

hypertonic

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 0.28 M in both glucose and sucrose

hypertonic

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 5.0%(m/v) NaCl solution

hypertonic

osmolarity relative to body fluids is greater than

hypertonic

osmotic effect on cells is: net flow of water out of cells

hypertonic

osmotic pressure relative to body fluids is greater than

hypertonic

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 0.92%(m/v) glucose solution

hypotonic

Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? 2.3%(m/v) glucose solution

hypotonic

osmolarity relative to body fluids is less than

hypotonic

osmotic effect on cells is: net flow of water into cells

hypotonic

Tell me something about H2(g) + I2(g) <=> HI(g)

if add more product, reaction will move toward left

How do you know if you can donate a hydrogen?

if hydrogen is written at the beginning

Crenation occurs

in concentrated sodium chloride solution [a hypertonic solution]

Hemolysis occurs

in pure water [a hypotonic solution]

Solution is a homogeneous mixture of two or more substances

in which each substance retains its chemical identity

inert

inactive

When you combine an acid and a base, there is

no conjugate acid & base bc they neutralize

At 24°C, the ion product constant for water has the value a. 1.00 × 10^−7 b. 1.00 × 10^−10 c. 1.00 × 10^−13 d. no correct answer

no correct answer

After four half-lives have elapsed, the amount of a radioactive sample that has decayed is which of the following? a. 1/4 the original amount b. 3/4 the original amount c. 1/16 the original amount d. no correct response

no correct response

For which of the following solutions is the concentration 1.0 molar? a. 3.0 moles of solute in 1.5 L of solution b. 2.0 moles of solute in 500.0 mL solution c. 1.0 mole of solute in 100.0 mL solution d. no correct response

no correct response

In a solution containing 15 mL of water and 25 mL of isopropyl alcohol a. the water is the solvent b. the alcohol is the solute c. both the water and alcohol are considered to be solvents d. no correct response

no correct response

What is the [H3O+] in a neutral solution? a. zero b. equal to 1.00 × 10^−5 c. greater than 1.00 × 10^−7 d. no correct response

no correct response

Which of the following does not affect the rate at which a solute dissolves in a solvent? a. state of subdivision of the solute b. temperature of the solvent c. stirring during the dissolving process d. no correct response

no correct response

Which of the following effects will occur if the pressure on the following equilibrium system is decreased? 2NO2(g) -> N2(g) + 2O2(g) a. NO2 concentration increases b. N2 concentration remains the same c. O2 concentration decreases d. no correct response

no correct response

Which of the following general equations is a representation for a displacement reaction? a. X + Y -> XY b. XY -> X + Y c. AX + BY -> AY + BX d. no correct response

no correct response

Which of the following statements concerning the conduction of electricity by an aqueous solution is correct? a. All electrolytes produce strongly conducting solutions. b. All nonelectrolytes produce weakly conducting solutions. c. All soluble salts produce weakly conducting solutions. d. no correct response

no correct response

Which of the following types of radioactive emissions has a mass of 2 amu? a. alpha particle b. beta particle c. gamma radiation d. no correct response

no correct response

Consider the following system at equilibrium: 2SO2(g) + O2(g) <=> 2SO3(g) How will adding a catalyst shift the equilibrium?

no effect

C6H6(g) + 3H2(g) -> C6H12(g) + heat Indicate if the following will shift the equilibrium to the right or left. Also indicate if the changes will change the value of Keq. Adding a catalyst

no effect on equilibrium or Keq

C2H4 has...

no ions

H2O2 has...

no ions

gamma ray has ?

no mass [that's how is diff from alpha & beta]

A semipermeable membrane separates two aqueous solutions at 20 degrees Celsius. Name the solution into which a net flow of water (if any will occur). Assume 100% dissociation for electrolytes, meaning ion-pairing can be ignored. solution A: 0.10 M Al(NO3)3 (aq) solution B: 0.20 M NaNO3 (aq)

no net flow

A semipermeable membrane separates two aqueous solutions at 20 degrees Celsius. Name the solution into which a net flow of water (if any will occur). Assume 100% dissociation for electrolytes, meaning ion-pairing can be ignored. solution A: 0.10 M NaCl (aq) solution B: 0.10 M KBr (aq)

no net flow

A semipermeable membrane separates two aqueous solutions at 37 degrees Celsius. For the following case, name the solution into which a net flow of water (if any) will occur. solution A: 0.20 M KCl (aq) solution B: 0.20 M NaCl (aq)

no net flow

If the colligative concentrations on each side of the membrane are equal,

no net flow of water

A substance that does not produce ions when dissolved in water

nonelectrolyte

Classify the following substance & description as an electrolyte or nonelectrolyte a substance that forms an aqueous solution that does not conduct electricity

nonelectrolyte

Classify the following substance & description as an electrolyte or nonelectrolyte methanol, CH3OH

nonelectrolyte

Classify the following substance & description as an electrolyte or nonelectrolyte most molecular solutes

nonelectrolyte

Classify the following substance & description as an electrolyte or nonelectrolyte table sugar

nonelectrolyte

Sucrose(s) -> sucrose(aq)

nonelectrolyte

Hydrocarbons are

nonpolar

Is CH4 polar or nonpolar?

nonpolar

Is N2 polar or nonpolar?

nonpolar

is CCl4 polar or nonpolar? Why?

nonpolar bc symmetrical

Classify each of the following reactions using one selection from the choices redox and nonredox combined with one selection from the choices combination, decomposition, displacement, exchange, and combustion NaCl + AgNO3 -> AgCl + NaNO3

nonredox & exchange

beta particle is!

not an electron bc coming out of nucleus

Molecular ([covalent]) solutes do

not break up to produce ions in solution.

What two factors determine whether a collision between two reactant molecules will result in a reaction?

total kinetic energy of colliding reactants; collision orientation

By definition, what happens to a substance when it is oxidized?

substance loses electrons [oxidation number increases]

reducing agent aka

substance oxidized

the reducing agent and

substance oxidized are always same

oxidizing agent aka

substance reduced

Tell me what a catalyst is

substance that increases chemical reaction rate without being consumed in chemical reaction.

The solute is the

substance that is dissolved

the conjugate base [of weak acid] that buffer contains is bc they need

substance to react w & remove added acid

the weak acid that buffers contain is bc they need

substance to react w & remove added base

What's an electrolyte?

substance whose aqueous solution conducts electricity

Identify the solute and the solvent in solutions composed of the following: 4.00 g of sucrose (table sugar) and 1000 g of water

sucrose solute; water solvent

H2SO4

sulfuric acid

Classify each of the following solutions as saturated, unsaturated, or supersaturated based on the following observations. Agitation of the solution produces a large amount of solid crystals.

supersaturated

If addition of a small crystal of NaCl to an NaCl solution causes additional crystals to form then the original solution was

supersaturated

Will red blood cells swell, remain the same size, or shrink when placed in 0.92%(m/v) glucose solution

swell

Will red blood cells swell, remain the same size, or shrink when placed in 2.3%(m/v) glucose solution

swell

When red blood cells are placed in pure water,

swell up & rupture [hemolysis]

What happens in hypotonic solution?

swells or burst

in a nuclear equation, the

symbols stand for nuclei rather than atoms

no lone pairs =

symmetrical [so can't be polar]

combination reaction aka

synthesis reaction

According to Le Chatelier, concentration

system will shift away from added component [If component is removed, opposite effect occurs]

Le Châtelier's principle states that if an equilibrium is disturbed

system will shift such that equilibrium is reestablished

"determine pH"

take negative log of hydrogen ion concentration

A solution with high osmotic pressure will

take up more water [more pressure must be applied to prevent osmosis]

The "most used" radionuclide in diagnostic medicine is

technetium-99m

You can't increase

temp in humans to make reactions go faster [so we use catalysts; enzymes in humans]

Contrast how factors such as temperature, pressure, and catalysts affect reaction rate for nuclear and chemical reactions.

temp, pressure & catalysts affect chemical reaction rates but do not affect nuclear reaction rates

in a chemical reaction, Reaction rates are influenced by

temp, pressure, catalysts & reactant concentrations.

Reaction rates in chemical reactions are

temperature dependent but those in nuclear reactions are not

Reactants high, products low

tend to stay to left

in a chemical reaction, Energy changes

that accompany chemical reactions are relatively small.

the smaller the pH value

the higher the concentration of hydrogen ions

In the notation carbon-14, the number 14 is

the mass number of the carbon atom

The oxidizing agent and

the substance reduced are always same

in a chemical reaction, Elements retain

their identity in chemical reactions.

If you dissolve base in water,

then water becomes the acid

The implantation of a radionuclide in living tissue is a common procedure in

therapeutic, but not diagnostic, medicine

3 protons per molecule transferred in an acid-base reaction

triprotic acid

H3PO4 would be an example of

triprotic acid

Indicate whether each of the following statements about the general properties of solutions is true or false. A solution may contain more than one solute.

true

Indicate whether each of the following statements about the general properties of solutions is true or false. All solutions are homogeneous mixtures.

true

Indicate whether each of the following statements about the general properties of solutions is true or false. every part of a solution has exactly the same properties as every other part.

true

Is the following statement concerning a saturated solution true or false? undissolved solute may or may not be present

true

Is the following statement concerning a saturated solution true or false? undissolved solute, if present, is in equilibrium with dissolved solvent

true

true or false: Solutes remain uniformly distributed throughout the solution.

true

true or false: Solutions can contain more than one solute

true

true or false: Solutions in which both solute and solvent are in the solid state are not possible.

true

true or false: at equilibrium, reactants are still being converted to products & vice versa

true

true or false: at equilibrium, the concentrations of reactants and products remain constant

true

true or false: at equilibrium, the rates of the forward & reverse reactions are equal

true

true or false: solutions are homogeneous mixtures.

true

true or false: solutions have a variable composition.

true

true or false: to determine whether a collision between 2 reactant molecules will result in a reaction, the particles must be in the correct orientation upon impact

true

true or false: to determine whether a collision between 2 reactant molecules will result in a reaction, the particles must collide with enough energy to meet the activation energy of the reaction

true

true or false? decreasing the temperature decreases the kinetic energy of the reactants, and the reaction goes more slowly

true

true or false? increasing the amount of reactants increases the number of collisions & the reaction goes fastser

true

true or false? reactants must collide, with proper orientation, with energy greater than or equal to the activation energy for a reaction to occur

true

true or false? the energy of a collision between atoms or molecules must be greater than or equal to the activation energy for bonds to be broken

true

in diagnostic!!

trying to figure out what's wrong

the effect of 1 mole of NaCl on colligative properties will be twice that of 1 mole of glucose bc

twice as many particles are present even tho molar amounts of solute are same

solutes are the substances that

undergo reaction when solutions are mixed [active]

Write equilibrium constant expressions for the following reactions. AgNO3(aq) + NaCl(aq) -> AgCl(s) + NaNO3(aq)

[NaNO3]/[AgNO3][NaCl]

Write equilibrium constant expressions for the following generalized reactions. 2X(s) + 3Y(s) -> 2Z(g)

[Z]^2

Write equilibrium constant expressions for the following generalized reactions. 2X(g) + 3Y(s) -> 2Z(g)

[Z]^2/[X]^2

Write equilibrium constant expressions for the following generalized reactions. 2X(g) + 3Y(g) -> 2Z(g)

[Z]^2/[X]^2 [Y]^3

Which of the following acids contains the greatest number of acidic hydrogen atoms? a. H2SO4 b. HC3H3O3 c. HC3H5O3 d. no correct response

a

Which of the following is not a polyprotic acid? a. HCN b. H3PO4 c. H2SO4 d. no correct response

a

What does it mean to say the percent concentration is 15%(m/m) NaCl solution

there are 15g of NaCl in 100g of solution

What does it mean to say the percent concentration is 25%(m/v) sucrose solution

there are 25g of sucrose in 100 mL of solution

What does it mean to say the percent concentration is 6%(v/v) methanol solution

there are 6 mL of methanol in 100 mL of solution

If there's an acid,

there's a base [bc need base to accept proton]

Most molecular solutes do not produce ions or charged particles when dissolved in water

therefore don't allow solution to conduct electricity

How do the radionuclides used for therapeutic purposes differ from the radionuclides used for diagnostic purposes?

they are usually a or b emitters

"of"

they go together on one side

Solute is the

thing you're dissolving

Pressure has a major effect on the solubility of gases in water?

think of a can of soda

Arrhenius bases are produced

through process of dissociation

Identify the solute in: bronze (an alloy of 95% copper and 5% tin)

tin

a good buffer has

to be able to absorb acids & bases so pH doesn't change

Nonmetals tend

to gain electrons

The formula for lactic acid is preferably written as hC3h5O3 rather than as C3h6O3. explain why.

to show it is monoprotic acid

Identify which substance is oxidized and which substance is reduced in each of the following redox reactions. N2 +3H2 -> 2NH3

H2 oxidized; N2 reduced

What substances are present in the following reaction mixture when equilibrium has been obtained? 3H2 + N2 <=> 2NH3

H2, N2, NH3

Give the conjugate acid for the base below: HCO3^-

H2CO3

Identify the Bronsted-Lowry acid in the following reaction H2O + H2CO3 -> H3O^+ + HCO3^-

H2CO3

Which of the following is a Bronsted Lowy acid? H2CO3 Cl - NH3 OH -

H2CO3

A sample of 56.0 g NaBr is added to 500.0 mL of H2O. Which component represents the solvent?

H2O

Example of amphiprotic substance

H2O

Identify the Bronsted-Lowry base in the following reaction H2O + H2CO3 -> H3O^+ + HCO3^-

H2O

Which substance is reduced in the following redox reaction? CO+H2O -> CO2 +H2

H2O

in NH3 + H2O -> NH4 + OH^- what is the acid?

H2O

Which of the following is the strongest acid? a) HX,Ka = 1.0 × 10^−3 b) HY,Ka =1.0 × 10^−5 c) HZ,Ka =1.0 × 10^−7 d) all have the same strength

a

Thus a 5% NaCl solution is assumed to be

a 5%(m/m) NaCl solution.

reduction involves

a decrease in oxidation number.

What is a solution?

a homogeneous mixture

Consider the following system at equilibrium: 2SO2(g) + O2(g) <=> 2SO3(g) How will increasing the concentration of SO3 shift the equilibrium?

to the left

Consider the following system at equilibrium: 2SO2(g) + O2(g) <=> 2SO3(g) How will increasing the concentration of SO2 shift the equilibrium?

to the right

The proper assignment of oxidation numbers to the elements in the compound H2SO4 is

+1 for h, +6 for S, −2 for O

Determine the oxidation number of the indicated ele- ment in each of the following ions. N in NO3^-

+5

Determine the oxidation number of the indicated ele- ment in each of the following ions. P in PO4^3-

+5

The proper assignment of oxidation numbers to the elements in the polyatomic ion PO4^3− is

+5 for P, −2 for O

What is the oxidation number of S in each of the following molecules? SO3

+6

What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular compound) to the following amounts of water? 2000 g (2.000 kg)

-0.93 degrees celsius

What is the freezing point for a solution containing 1.00 mole of glucose (a nondissociating solute) dissolved in 1.00 kg water?

-1.86 degrees celsius

What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular compound) to the following amounts of water? 1000 g (1.000 kg)

-1.9 degrees celsius

What is the freezing point of the solution 3.00 moles of NaCl (an ionic compound)

-11.16 degrees celsius

What is the freezing point of an aqueous solution that contains 3.00 moles of the ionic solute CaCl2 (a deicing compound) per one kilogram of water?

-16.7 degrees celsius

Determine the oxidation number of the indicated ele- ment in each of the following ions. S in S^2-

-2

What is the oxidation number of S in each of the following molecules? H2S

-2

What is the freezing point of the solution 3.00 moles of Na3PO4 (an ionic compound)

-22.32 degrees celsius

Which member of each of the following pairs of compounds has the higher boiling point? 1.0 M NaCl or 1.0 M Na2SO4

1.0 M Na2SO4

Which member of each of the following pairs of compounds has the higher boiling point? 2.0 M glucose or 1.0 M Na2SO4

1.0 M Na2SO4

Which member of each of the following pairs of compounds has the higher boiling point? 1.0 M glucose or 1.0 M NaCl

1.0 M NaCl

If pH = 4.00 then [H3O+] =

1.0 x 10^-4

The percent-by-mass concentration of a solution containing 5.0 g of NaCl in 500.0 g of solution is

1.0% (m/m)

A 0.200 M solution of NaCl which contains 0.200 mole of NaCl would have a volume of

1.00 L

[H3O^+] [OH^-] =

1.00 x 10^-14

Determine the pH of the following solutions: 1.0 × 10^-4 M OH^-

1.00 x 10^1

What is the [OH−] in an aqueous solution in which [H3O+] is 1.00 × 10^−5?

1.00 × 10^−9

A solution of hydrogen peroxide (H2O2) in water with a volume of 70.0 mL is diluted by adding 50.0 mL of water. Calculate the solution's new concentration given the following original concentrations. (Addition of 50.0 mL of water is equivalent to adding 50.0 g of water since the density of water is 1.00 g/mL.) 2.0 M

1.17 M

A solution of hydrogen peroxide (H2O2) in water with a volume of 70.0 mL is diluted by adding 50.0 mL of water. Calculate the solution's new concentration given the following original concentrations. (Addition of 50.0 mL of water is equivalent to adding 50.0 g of water since the density of water is 1.00 g/mL.) 2.0%(m/m)

1.17% (m/m)

A solution of hydrogen peroxide (H2O2) in water with a volume of 70.0 mL is diluted by adding 50.0 mL of water. Calculate the solution's new concentration given the following original concentrations. (Addition of 50.0 mL of water is equivalent to adding 50.0 g of water since the density of water is 1.00 g/mL.) 2.0%(m/v)

1.17% (m/v)

A solution of hydrogen peroxide (H2O2) in water with a volume of 70.0 mL is diluted by adding 50.0 mL of water. Calculate the solution's new concentration given the following original concentrations. (Addition of 50.0 mL of water is equivalent to adding 50.0 g of water since the density of water is 1.00 g/mL.) 2.0%(v/v)

1.17% (v/v)

Sodium hydroxide is extremely soluble in water. At a certain temperature, a saturated solution contains 563 g of NaOH(s) per liter of solution. Calculate the molarity of this saturated NaOH(aq) solution

1.41 x 10^1 M

Determine the final concentration of each of the following solutions after 20.0 mL of water has been added. 60.0 mL of 2.0 M NaCl solution

1.5 M

What is the osmolarity of each of the following solutions? 2.0 M KNO3

4.0 OsM

The [H3O+] concentration of a solution is 2.5 x 10^-4 Calculate the [OH^-]

4.0 x 10^-11

The [H3O+] concentration of a solution is 2.5 x 10^-9 Calculate the [OH^-]

4.0 x 10^-6

Calculate the pH for the following solutions. 1.0 x 10^-4 M H3O^+

4.00

Calculate the volume percent of solute in each of the following solutions. 20.0 mL of methyl alcohol in enough water to give 475 mL of solution

4.21% (v/v)

Determine the pKa for acetic acid, hC2h3O2, given that Ka for this acid is 1.8 × 10^-5.

4.74

Calculate the value of the equilibrium constant for the reaction N2O4(g) <=> 2NO2(g) if the concentrations of the species at equilibrium are [N2O4] = 0.213 and [NO2] = 0.0032

4.8 x 10^-5

The pKa for an acid whose Ka is 1.0 × 10^−5 is

5.0

Calculate the pH for the following solutions. 3.2 x 10^-6 M H3O^+

5.49

Calculate the molarity of 0.850 mol of Na2S in 1.50 L of solution

5.67 x 10^-1 M

Determine the molarities of the following solutions. 4.35 moles of KMnO4 are dissolved in enough water to give 750 mL of solution.

5.80 moles KMnO4/L solution

What is the osmolarity of each of the following solutions? 2.0 M Na2SO4

6.0 OsM

What is the osmolarity of each of the following solutions? 2.0 M in both KNO3 and glucose

6.0 OsM

A solution is 0.0030 M in hpO42− ion. What is this ion concentration in meq/L?

6.0 mEq/L

Which of the following solutions is hypertonic with respect to red blood cells? a. 2.0%(m/v) glucose b. 4.0%(m/v) glucose c. 6.0%(m/v) glucose d. no correct response

6.0%(m/v) glucose

Calculate the ph for each of the following solutions. [H3O+] = 1.0 × 10^−6

6.00

The ph for a solution with [h3O+] = 1.0 × 10^−6 is

6.00

Calculate the mass percent of solute in the following solutions. 2.31 g of LiBr dissolved in 35.0 g of H2O

6.19% (m/m)

What is the percent-by-mass concentration of glucose in a solution made my dissolving 5.5 g of glucose in 78.2 g of water?

6.6%

Calculate the molarity of 30.3 g of MgS in 787 mL of solution

6.82 x 10^-1 M

Indicate whether or not each of the following changes would affect the value of a system's equilibrium constant. a. removal of a reactant from the equilibrium mixture b. Decrease in the system's total pressure c. Decrease in the system's temperature d. Addition of a catalyst to the equilibrium mixture

A) no b) no c) yes d) no

Which of the following statements concerning electrolytes is correct? a. All strong acids are strong electrolytes. b. All salts are weak electrolytes. c. Some, but not all, molecular substances are strong electrolytes. d. no correct response

All strong acids are strong electrolytes

vapor-pressure lowering

Adding a nonvolatile solute to solvent lowers vapor pressure of resulting solution below that of pure solvent at same temp

Boiling point elevation

Adding a nonvolatile solute to solvent raises boiling point of resulting solution above that of pure solvent.

Cu(s) + 2AgNO3(aq) -> 2Ag(s) + Cu(NO3)2(aq) What is the oxidizing agent?

Ag^+

Cu(s) + 2AgNO3(aq) -> 2Ag(s) + Cu(NO3)2(aq) Which substance gets reduced?

Ag^+

Which of the following will have the largest effect on freezing point depression or boiling point elevation •NaCl •C2H4 •AlCl3 •H2O2

AlCl3

Equilibrium says

All reactions are reversible in theory [can go in either direction]

Write the chemical formulas for the products formed when each of the following hydrocarbons undergoes complete combustion. C6H6

CO2, H2O

Write the chemical formulas for the products formed when each of the following hydrocarbons undergoes complete combustion. CH4

CO2, H2O

Dilution formula

CSVS = CDVD

Ca -> Ca^2+

Ca loses 2 electrons [Ca is oxidized = reducing agent]

What is the missing reactant in the following decomposition reaction? ? -> CaO(s) + CO2(g)

CaCO3

CaCl2 ->

Ca^2+ + 2Cl^−

For the following reactions, indicate which substance is oxidized and which substance is reduced. Identify the oxidizing and reducing agents. Cl2 (g) + 2NaBr (aq) -> Br2 (aq) + 2NaCl (aq)

Br is oxidized [reducing agent] and Cl is reduced [oxidizing agent]

Cl2 (g) + 2NaBr (aq) -> Br2 (aq) + 2NaCl (aq) What is happening to Br and Cl here?

Br loses 1 electron; Cl gains 1 electron

Write the conjugate base of each of the following: HBr

Br^-

A proton donor

Bronsted-Lowry acid

A proton acceptor

Bronsted-Lowry base

What are the major species in solution after the reaction of hydrochloric acid and sodium hydroxide (hydrochloric acid has H+ and Cl^-) (sodium hydroxide has Na^+ and OH^-)

H2O, Na^+ and Cl^-

Label each reactant and product in this reaction as a Bronsted acid or base CH3OH + OH^- <=> CH3O^- + H2O

CH3OH [acid], OH^- [base], CH3O^- [base], H2O [acid]

For the redox reaction FeO+CO -> Fe+CO2 identify the: reducing agent

CO

For the redox reaction FeO+CO -> Fe+CO2 identify the: substance oxidized

CO

2CO(g) + O2(g) <=> 2CO2(g) if you decrease the volume of the system, how will the concentration then change to reach equilibrium?

CO goes down, O2 goes down, CO2 goes up

2CO(g) + O2(g) <=> 2CO2(g) if you increase the concentration of CO, how will the concentration then change to reach equilibrium?

CO goes down, O2 goes down, CO2 goes up

2CO(g) + O2(g) <=> 2CO2(g) if you increase the concentration of CO2, how will the concentration then change to reach equilibrium?

CO goes up, O2 goes up, CO2 goes down

Identify the solute in: CO2(g) in water

CO2

Write the chemical formulas for the products formed when each of the following hydrocarbons undergoes complete combustion. C4H10

CO2, H2O

Write the chemical formulas for the products formed when each of the following hydrocarbons undergoes complete combustion. C4H6

CO2, H2O

Cl2 -> 2Cl^-

Cl2 gains 2 electrons [Cl2 is reduced = oxidizing agent]

Identify which substance is the oxidizing agent and which substance is the reducing agent in each of the redox reactions Cl2 + 2KI -> 2KCl + I2

Cl2 oxidizing agent; KI reducing agent

Fe(s) + Cu^2+(aq) -> Fe^2+(aq) + Cu(s) Which substance gets reduced?

Cu^2+

For the triprotic acid h3pO4, the reactant in the second proton-transfer step is

H2PO4^-

Identify which substance is oxidized and which substance is reduced in each of the following redox reactions. 3H2SO3 + 2HNO3 -> 2NO + H2O + 3H2SO4

H2SO3 oxidized; HNO3 reduced

Which of the following effects will occur if the temperature of the following equilibrium system is increased? H2(g) + F2(g) -> 2HF(g) + heat a. the equilibrium shifts to the right b. hF concentration increases c. h2 and F2 concentrations increase d. no correct response

H2 and F2 concentrations increase

CO(g) + 2H2(g) <- ——> CH3OH(g) if CO increases

H2 decreases & CH3OH increases [but Keq stays constant]

HC2H3O2/C2H3O2^- common lab buffer [acetic acid/sodium acetate buffer]

Equal amounts of acetic acid [weak acid] & its weak conjugate base [acetate ion]

If reactants are high & Keq is small [< 10 - 3]

Equilibrium lies to left (not much product)

If products are high and Keq is large [larger than 103]

Equilibrium lies to right (lots of product)

ADDING REACTANT

Equilibrium shifts to product side

REMOVING PRODUCT

Equilibrium shifts to product side

INCREASING TEMPERATURE in an endothermic reaction

Equilibrium shifts to product side for an endothermic reaction

DECREASING TEMPERATURE in an exothermic reaction

Equilibrium shifts to product side for exothermic reaction

ADDING PRODUCT

Equilibrium shifts to reactant side

REMOVING REACTANT

Equilibrium shifts to reactant side

DECREASING TEMPERATURE in an endothermic reaction

Equilibrium shifts to reactant side for endothermic reaction

INCREASING TEMPERATURE in an exothermic reaction

Equilibrium shifts to reactant side for exothermic reaction

INCREASING PRESSURE

Equilibrium shifts to side that has fewest moles of gas

DECREASING PRESSURE

Equilibrium shifts to side that has greatest moles of gas

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) what is the conjugate base?

F^-

For the redox reaction FeO+CO -> Fe+CO2 identify the: substance reduced

FeO

Label each reactant and product in this reaction as a Bronsted acid or base H2Y^- + H2Z <=> H3Y + HZ^2-

H2Y^- [base], H2Z^- [acid], H3Y [acid], HZ^2- [base]

H2O is the conjugate base of

H3O^+

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) what is the conjugate acid?

H3O^+

HF + H2O <=> H3O^+ + F^- if you put OH in

H3O^+ goes down

Which acid in the choices below is an example of a triprotic acid? H3PO4 HCl HC2H3O2 H2SO4

H3PO4

Which of the following is a weak acid? HCN HCl HI HNO3

HCN

Write an equation for each of the following buffering actions. The response of HCN/CN− buffer to the addition of OH− ions

HCN + OH^- -> CN^- + H2O

Label each reactant and product in this reaction as a Bronsted acid or base HCN + NH2^- <=> CN^- + NH3

HCN [acid], NH2^- [base], CN^- [base], NH3 [acid]

Give the conjugate acid for the base below: CO3^2-

HCO3^-

Write the conjugate base of each of the following: H2CO3

HCO3^-

What is the acid in HCl + H2O → Cl^- + H3O^+

HCl

HCl + H2O -> H3O^+ + Cl

HCl + H2O is dissolving acid in water

The chemical formula for the conjugate acid of ClO^− is

HClO

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) what is the acid?

HF

Identify the Bronsted-Lowry acid in the following reaction HF + H2O -> H3O^+ + F^-

HF

Which of the following pairs is a buffer. HF and F - HCl and NaCl H2SO4 and Na2SO4 NH3 and NH4+

HF and F^-

Which pair of molecules will mix together to form a homogeneous solution? Hydrogen fluoride (HF) and water (H2O) Pentane (C5H12) and methanol (CH3OH) Benzene (C6H6) and water (H2O) Formaldehyde (CH2O) and hexane (C6H14)

HF and H2O

HF + H2O how do you know which is acid and which is base?

HF can only be acid; H2O can be either

Write the conjugate acid of each of the following: NO2^-

HNO2

For the buffer system hNO2/NO2−, do the concentra- tions of hNO2 and NO2− increase or decrease when a small amount of strong acid is added to the buffer?

HNO2 increases & NO2^- decreases

Write the chemical formula of each of the following. The conjugate acid of NO3^−

HNO3

Write the conjugate base of each of the following: H2S

HS^-

What is happening when you go from: F^- to HF

H^+ gain

What is happening when you go from: H2O to H3O^+

H^+ gain

In an Arrhenius acid-base theory context, the acidic species in an aqueous solution is the

H^+ ion

What is happening when you go from: H3O^+ to H2O

H^+ loss

What is happening when you go from: HF to F^-

H^+ loss

What is the acid ionization constant of: HA(aq) + H2O(l) ⇔ H3O+(aq) + A-(aq)

Ka = [H3O^+] [A^-]/[HA]

If [Products] is high then

Keq will be large >103

If [Reactants] is high then

Keq will be small < 10 - 3

In neutral, acidic, or basic solutions,

Kw is always 1.0 x 10^-14

In all three possible situations [neutral, acidic or basic]

Kw= 1.00 x 10^-14 = [H3O^+] x [OH^-]

M1 x V1=

M2 x V2

Write the chemical formula of each of the following. The conjugate base of HSO4^−

SO4^2-

Identify which substance is the oxidizing agent and which substance is the reducing agent in each of the redox reactions Sb2O3 + 3Fe -> 2Sb + 3FeO

Sb2O3 oxidizing agent; Fe reducing agent

Identify which substance is oxidized and which substance is reduced in each of the following redox reactions. Sb2O3 + 3Fe -> 2Sb + 3FeO

Sb2O3 reduced; Fe oxidized

Mg(s) + Cl2(g) -> Mg^2+(aq) + 2Cl^-(aq) Which substance gets oxidized?

Mg

Why is the following reaction a displacement reaction? Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)

Mg displaces H

2 Mg (s) + CO2(g) -> 2 MgO (s) + C (s) You can also see this as

Mg gains oxygen [oxidized] and carbon loses oxygen [reduced]

For the following reaction, indicate which substance is oxidized and which substance is reduced. Identify the oxidizing and reducing agents. 2 Mg (s) + CO2(g) -> 2 MgO (s) + C (s)

Mg is oxidized [reducing agent] and C is reduced [oxidizing agent]

2 Mg (s) + CO2(g) -> 2 MgO (s) + C (s) What is happening to Mg and C here?

Mg loses 2 electrons; C gains 4 electrons

Activation energy is like

Minimum combined kinetic energy that colliding reactant particles must possess for their collision to result in chemical reaction

Identify the solvent in: air (a solution of 78% N2, 21% O2 and various other gases)

N2

Identify which substance is the oxidizing agent and which substance is the reducing agent in each of the redox reactions N2 +3H2 -> 2NH3

N2 oxidizing agent; H2 reducing agent

Consider the following equilibrium system. N2(g) + O2(g) <=> 2NO(g) Write the chemical equation for the forward reaction.

N2(g) + O2(g) -> 2NO(g)

For the chemical reaction N3^− + H2O -> HN3 + OH^−, the Brønsted-Lowry base is

N3^-

Give the conjugate base for the acid below: NH4^+

NH3

What is the base in H2O + NH3 → OH^- + NH4^+

NH3

in NH3 + H2O -> NH4 + OH^- what is the base?

NH3

Give the conjugate acid for the base below: NH3

NH4^+

Write the conjugate acid of each of the following: NH3

NH4^+

in NH3 + H2O -> NH4 + OH^- what is the conjugate acid?

NH4^+

Consider the reaction below. HNO3 + H2O <----> H3O+ + NO3- Which substance is the conjugate base of HNO3?

NO3^-

At a given temperature, which of the two aqueous solutions 1.0 M glucose or 1.0 M NaCl has the higher boiling point

NaCl

At a given temperature, which of the two aqueous solutions 1.0 M glucose or 1.0 M NaCl has the higher osmotic pressure

NaCl

Which of the following aqueous solutions would give rise to a greater osmotic pressure? 8.00 g of NaCl in 375 mL of solution or 4.00 g of NaBr in 155 mL of solution

NaCl

In which of the following pairs of compounds are both members of the pair strong electrolytes? a. NaOh and NaCl b. Nh3 and hCl c. NaCN and hCN d. no correct response

NaOH and NaCl

What is the base and what is the acid? NaOH + HCl -> H2O + NaCl

NaOH is base; HCl is acid

NaCl ->

Na^+ + Cl^-

in self-ionization,

Net effect is formation of equal amounts of hydronium & hydroxide ions

3Ni^2+(aq) + 2Co(s) -> 2Co^3+(aq) + 3Ni(s) Which substance gets reduced?

Ni^2+

for acid ionization constant

Notice water does not appear in equilibrium expression [pure substance]

in NH3 + H2O -> NH4 + OH^- what is the conjugate base?

OH^-

For each of the following pairs of solutions, select the solution for which solute solubility is greatest. Carbon dioxide gas in water with P = 2 atm and T = 50°C Carbon dioxide gas in water with P = 1 atm and T = 50°C

P =2

Give the conjugate base for the acid below: HPO4^2-

PO4^3-

beta particle

Particle whose charge & mass are identical to those of electron that is emitted by certain radioactive nuclei.

Molecular Collisions [collision theory]

Particles have to collide in order to react.

Activation Energy [collision theory]

Particles have to have enough energy to react

Collision Orientation [collision theory]

Particles have to have right orientation in order to react

Keq is Concentration of products divided by concentration of reactants

Raised to power of coefficient from balanced equation

How does temperature affect chemical reaction rate?

Reaction rate increases as temp of reactants increase

Collision orientation is like

Reaction rates are sometimes very slow bc reactant molecules must be orientated in certain way for collisions to lead successfully to products

Gamma radiation effects can

Readily penetrate deeply into organs, bone & tissue

For the following reactions, indicate which substance is oxidized and which substance is reduced. Identify the oxidizing and reducing agents. S (s) + O2 (g) → SO2 (g)

S is oxidized [reducing agent] and oxygen must be reduced in this reaction

Give the formula of the conjugate base of HSO4^-

SO4^2-

Write equations for the following nuclear bombardment processes. a. Beryllium-9 is bombarded with an alpha particle, and a neutron is a product. b. Sodium-23 is bombarded with hydrogen-2, and neon-21 is a product. c. Bombardment of cadmium-113 with a small particle produces cadmium-114 and a gamma ray. d. Bombardment of a nuclide with an alpha particle produces phosphorus-30 and a neutron.

a) 9Be4 + 4a2 -> 1N0 + 12C6 b) 23Na11 + 2H1 -> 21Ne10 + 4a2 c) 113Cd48 + 1N0 -> 114Cd48 + 0Y0 d) 27Al13 + 4a2 -> 30P15 + 1N0

Classify each of the following as a property of an Arrhenius acid or the property of an Arrhenius base. a. has a sour taste b. has a bitter taste

a) Arrhenius acid b) Arrhenius base

Write a balanced equation for the dissociation into ions of each of the following soluble salts in aqueous solution. a. Ba(NO3)2 b. Na2SO4 c. CaBr2 d. K2CO3

a) Ba(NO3)2 -> Ba^2+ + 2NO3^- b) Na2SO4 -> 2Na^+ + SO4^2- c) CaBr2 -> Ca^2+ + 2Br^- d) K2CO3 -> 2K^+ + CO3^2-

Write chemical equations showing the individual proton- transfer steps that occur in aqueous solution for each of the following acids. a. h2CO3 (carbonic acid) b. h2C3h2O4 (malonic acid)

a) H2CO3 + H2O -> HCO3^- + H3O^+; HCO3^- + H2O -> CO3^2- + H3O^+ b) H2C3H2O4 + H2O -> HC3H2O4^- + H3O^+; HC3H2O4^- + H2O -> C3H2O4^2- + H3O^+

Write a balanced molecular equation for the preparation of each of the following salts, using an acid-base neutralization reaction. a. Li2SO4 (lithium sulfate) b. NaCl (sodium chloride) c. KNO3 (potassium nitrate) d. Ba3(pO4)2 (barium phosphate)

a) H2SO4 + 2LiOH -> Li2SO4 + 2H2O (b) HCl + NaOH -> NaCl + H2O (c) HNO3 + KOH -> KNO3 + H2O d) 2H3PO4 + 3Ba(OH)2 -> Ba3(PO4)2 + 6H2O

Using the acid ionization constant information given in Table 10-3, indicate which acid is the stronger in each of the following acid pairs. a. h3pO4 and hNO2 b. hCN and hF c. h2CO3 and hCO3− d. hNO2 and hCN

a) H3PO4 b) HF c) H2CO3 d) HNO2

Identify the two "active species" in each of the following buffer systems. a. hCN and KCN b. h3pO4 and Nah2pO4 c. h2CO3 and KhCO3 d. NahCO3 and K2CO3

a) HCN and CN^- b) H3PO4 and H2PO4^- c) H2CO3 and HCO3^- d) HCO3^- and CO3^2-

Identify the buffer system(s)--the conjugate acid-base pair(s)--present in a solution that contains equal molar amounts of the following: a. hCN, KCN, hClO, and NaClO2 b. h2CO3, Na2CO3, NaNO2, and hNO2

a) HCN/CN^- b) HNO2/NO2^-

The ion hCO3− is an amphiprotic ion. Write the chemi- cal equation to describe its behavior in aqueous solution when it functions as a a. Brønsted-Lowry base b. Brønsted-Lowry acid

a) HCO3^- + H2O -> H2CO3 + OH^- b) HCO3^- + H2O -> CO3^2- + H3O^+

Write a balanced chemical equation to represent each of the following acid-base neutralization reactions. a. hCl and NaOh b. hNO3 and KOh c. h2SO4 and LiOh d. Ba(Oh)2 and h3pO4

a) HCl + NaOH -> NaCl + H2O b) HNO3 + KOH -> KNO3 + H2O c) H2SO4 + 2LiOH -> Li2SO4 + 2H2O d) 2H3PO4 + 3Ba(OH)2 -> Ba3(PO4)2 + 6H2O

Write equations depicting the behavior of the following Arrhenius acids and bases in water. a. hI (hydroiodic acid) b. hClO (hypochlorous acid) c. LiOh (lithium hydroxide) d. CsOh (cesium hydroxide)

a) HI -> H^+ + I^- b) HClO -> H^+ + ClO^- c) LiOH -> Li^+ + OH^- d) CsOH -> Cs^+ + OH^-

Write chemical equations that show the indicated behavior in aqueous solution for each of the following chemical species. a) HOCl behaves as a Brønsted-Lowry acid b) NH3 behaves as a Brønsted-Lowry base c) H2PO4^− behaves as a Brønsted-Lowry acid d) CO3^2− behaves as a Brønsted-Lowry base

a) HOCl + H2O -> OCl^- + H3O^+ b) NH3 + H2O -> NH4^+ + OH^- c) H2PO4^- + H2O -> HPO4^2- + H3O^+ d) CO3^2- + H2O -> HCO3^- + OH^-

Which of the four species Cl−, hpO42−, CO32−, and h2SO3 have the following properties? a. amphiprotic b. does not hydrolyze in water c. hydrolyzes in water to give a basic solution d. can function as a buffer system component

a) HPO4^2- b) Cl^- c) HPO4^2-, CO3^2- d) HPO4^2-, CO3^2-, H2SO3

Write the formula of each of the following. a. conjugate base of h2SO3 b. conjugate acid of CN− c. conjugate base of hC2O4^− d. conjugate acid of hpO4^2−

a) HSO3^- b) HCN c) C2O4^2- d) H2PO4^-

In Arrhenius acid-base theory, what ion is responsible for the properties of a. acidic solutions b. basic solutions

a) H^+ b) OH^-

Write the acid ionization constant expression for the ionization of each of the following monoprotic acids. a. hF (hydrofluoric acid) b. hC2h3O2 (acetic acid)

a) Ka= [H^+][F^-]/[HF] b) Ka = [H^+][C2H3O2^-]/[HC2H3O2]

Write a balanced chemical equation for the dissociation in water of each of the salts listed in a) NaCl b) Mg(NO3)2 c) K2S d) NH4CN

a) NaCl -> Na^+ + Cl^- b) Mg(NO3)2 -> Mg^2+ + 2NO3^- c) K2S -> 2K^+ + S^2- d) NH4CN -> NH4^+ + CN^-

What is the oxidation number of each element present in the following compounds or ions? a) SiF4 b) H2SO4 c) Na3PO4 d) Cr2O7^2−

a) Si: +4, F: -1 b) H: +1, S: -6, O: -2 c) Na: +1, P: +5, O: -2 d) Cr: +6, O: -2

Is the monoprotic acid Y or the monoprotic acid Z the stronger acid in each of the following situations? a. At equal concentrations, Y dissociates to a greater extent than Z in water. b. Ka for Z is larger than Ka for Y. c. The equilibrium position for the dissociation of Y lies farther to the right than that for Z. d. proton transfer to water occurs to a lesser extent for Z than for Y.

a) Y b) Z c) Y d) Y

Write the base ionization constant expression for the ionization of each of the following bases. In each case, the nitrogen atom accepts the proton. a. NH3 (ammonia) b. C6H5NH2 (aniline)

a) [NH4^+][OH^-]/[NH3] b) [C6H5NH3^+][OH^-]/[C6H5NH2]

Indicate whether the first listed reactant in each of the following Brønsted-Lowry acid-base reactions is func- tioning as an acid or a base. a) HF + H2O -> H3O^+ +F^− b) CN^− + H2O -> HCN + OH^− c) HCN + NO2^− -> HNO2 + CN^− d) NH3 + HNO3 -> NH4^+ + NO3^−

a) acid b) base c) acid d) base

Classify each of the following substances as an acid, a base, or a salt. a. hBr b. NaI c. Nh4NO3 d. Ba(Oh)2

a) acid b) salt c) salt d) base

Consider the following chemical system at equilibrium. CO(g) + H2O(g) + heat <=> CO2(g) + H2(g) For each of the following adjustments of conditions, indicate the effect (shifts left, shifts right, or no effect) on the position of equilibrium. a. refrigerating the equilibrium mixture b. Adding a catalyst to the equilibrium mixture c. Adding CO to the equilibrium mixture d. Increasing the size of the reaction container

a) left b) no effect c) right d) no effect

Classify each of the following acids as monoprotic, diprotic, or triprotic. a. hClO3 (chloric acid) b. hC3h5O4 (glyceric acid) c. h3C6h5O7 (citric acid) d. h3pO4 (phosphoric acid)

a) monoprotic b) monoprotic c) triprotic d) triprotic

predict whether each of the following pairs of substances could function as a buffer system in aqueous solution. a) hCl and NaCl b) hCN and KCN c) hCl and hCN d) NaCN and KCN

a) no b) yes c) no d) no

predict whether each of the following pairs of substances could function as a buffer system in aqueous solution. a. hNO3 and NaNO3 b. hF and NaF c. KCl and KCN d. h2CO3 and NahCO3

a) no b) yes c) no d) yes

Indicate whether each of the following reactions is an acid-base neutralization reaction. a. NaCl+AgNO3 -> AgCl+NaNO3 b. hNO3 + NaOh -> NaNO3 + h2O c. hBr+KOh -> KBr+h2O d. h2SO4 + pb(NO3)2 -> pbSO4 + 2hNO3

a) no b) yes c)yes d) no

What would be the expected effect of each of the following short-term, whole-body radiation exposures? a. 10 rems b. 150 rems

a) no detectable effects b) nausea, fatigue, lowered blood cell count

In each of the following changes is the reactant undergoing oxidation or reduction? (The given equation for the change is not a complete chemical equation.) a) SO2 -> SO3 b) N2O -> NO c) Cr^3+ -> Cr^2+ d) S2− -> S

a) oxidation b) oxidation c) reduction d) oxidation

Should heat be added as a reactant or as a product to each of the following equations for chemical reactions based on the given thermicity for the reaction? a. H2 + Cl2 -> 2HCl (exothermic) b. 4NO + 6H2O -> 4NH3 + 5O2 (endothermic) c. 2H2O + 2Cl2 -> 4HCl + O2 (endothermic) d. 2H2O -> 2H2 + O2 (exothermic)

a) product b) reactant c) reactant d) product

Classify each of the following reactions as a redox reac- tion or a nonredox reaction. a) 2Cu + O2 -> 2CuO b) K2O + H2O -> 2KOH c) 2KClO3 -> 2KCl + 3O2 d) CH4 +2O2 -> CO2 +2H2O

a) redox b) nonredox c) redox d) redox

Classify each of the acids as a strong acid or a weak acid. a. hClO3 (chloric acid) b. hC3h5O4 (glyceric acid) c. h3C6h5O7 (citric acid) d. h3pO4 (phosphoric acid)

a) strong acid b) weak acid c) weak acid d) weak acid

For each of the following pairs of acids, indicate whether the first member of the pair is a stronger or weaker acid than the second member of the pair. a. hNO3 and hNO2 b. hF and hBr c. h2CO3 and hClO3 d. hCN and hCl

a) stronger b) weaker c) weaker d) weaker

Classify each of the following compounds as a strong electrolyte or a weak electrolyte. a. h2CO3 b. KOh c. NaCl d. h2SO4

a) weak b) strong c) strong d) strong

Which of the terms weak, strong, monoprotic, diprotic, and triprotic characterize(s) each of the following acids? More than one term may apply in a given situation. a. h3pO4 b. h3pO3 c. hBr d. hC2h3O2

a) weak, triprotic b) weak, triprotic c) strong, monoprotic d) weak, monoprotic

Indicate whether or not both members of each of the following pairs of substances are salts. a. KCN and NaCN b. hCl and LiCl c. Na2SO4 and NaOh d. Al(NO3)3 and Ca(NO3)2

a) yes b) no c) no d) yes

For each of the following pairings of nuclear notations indicate whether the two members of the pair denote the same nuclide? a. nitrogen-14 and 14N7 b. Al-27 and 28Al 13 c. chlorine-35 and Cl-35 d. O-18 and (18 protons + 18 neutrons)

a) yes b) no c) yes d) no

Based on charge-balance considerations, indicate whether it would be possible to prepare solutions with each of the following total compositions. a. 75 meq Na+, 25 meq K+, 95 meq Cl−, and 5 meq NO3− b. 73 eq K+, 55 eq Cl−, and 25 eq C2h3O2− c. 750 meq Na+ and 0.750 eq Cl− d. 0.025 mole Na+, 0.025 mole Ca2+ and 0.075 mole Cl−

a) yes b) no c) yes d) yes

Indicate whether or not the two members of each of the following pairs of substances constitute a conjugate acid-base pair. a. HCl and Cl− b. Nh4+ and Nh3 c. h2CO3 and CO3^2- d. h2pO4^− and hpO4^2−

a) yes b) yes c) no d) yes

For each of the following pairings of acid and base indicate whether both the acid and the base are classified as strong? a. h2SO4 and KOh b. hCl and NaOh c. hClO4 and Sr(Oh)2 d. hF and Ba(Oh)2

a) yes b) yes c) yes d) no

Write an equation for each of the following buffering actions. a. the response of a hF/F− buffer to the addition of h3O+ ions b. the response of a h2CO3/hCO3− buffer to the addition of Oh− ions c. the response of a hCO3−/CO32− buffer to the addition of h3O+ ions d. the response of a h3pO4/h2pO4− buffer to the addition of Oh− ions

a)F^- + H3O^+ -> HF + H2O b) H2CO3 + OH^- -> HCO3^- + H2O c) CO3^2- + H3O^+ -> HCO3^- + H2O d) H3PO4 + OH^- -> H2PO4^- + H2O

The half-life of Na-24 is 15.0 hours. a. How many grams of Na-24 in a 4.00 g sample of this nuclide will have decayed after 60.0 hours? b. How many hours are required to reduce the amount of Na-24 present in a 28.0 mg sample to 7.0 mg?

a. 3.75 g b. 30.0 hours

a Bronsted-lowry base is a substance that can

accept proton [H^+ ion] from some other substance

HF(aq) + H2O(l) <=> F^-(aq) + H3O^+(aq) in this acid-base reaction, a base H2O

accepts H^+ to form its conjugate acid H3O^+

in HCl + H2O -> Cl^- + H3O^+ H2O

accepts proton

in a nuclear reaction, Energy changes that

accompany nuclear reactions are much larger than those in chemical reactions.

For endothermic chemical reactions the energy needed to break reactant chemical bonds is

greater than that released in product chemical bond formation

you use isotopic notation

for elements in nuclear reactions

in water, weak electrolytes

forms solution of few ions & mostly undissociated molecules

Effect of concentration changes

forward & reverse reaction rates adjust until are again equal & equilibrium is re-established

What statement is correct for a system at chemical equilibrium?

forward & reverse reaction rates are equal

What condition must occur when a chemical reaction is at equilibrium?

forward & reverse reactions are happening at equal rates

In Cl2(g) + 2NaBr(aq) -> Br2(aq) + 2NaCl(aq) Cl

gained; reducing agent

Indicate whether each of the following substances loses or gains electrons in a redox reaction. The oxidizing agent

gains

Indicate whether each of the following substances loses or gains electrons in a redox reaction. The substance undergoing reduction

gains

Which of the following correctly orders the three types of naturally occurring radiation in terms of increasing ability to produce ion pairs through radiation-matter interactions?

gamma, beta, alpha

Pressure is...

gas concentration

Classify each of the following events based on whether the solubility of the indicated gas will increase, decrease or stay the same air in the blood of a diver breathing compressed air that quickly surfaces

gas solubility decreases

Classify each of the following events based on whether the solubility of the indicated gas will increase, decrease or stay the same the temperature is increased

gas solubility decreases

Classify each of the following events based on whether the solubility of the indicated gas will increase, decrease or stay the same O2 in the blood of a person who is in a hyperbaric chamber

gas solubility increases

Classify each of the following events based on whether the solubility of the indicated gas will increase, decrease or stay the same the partial pressure of an anesthetic gas is increased

gas solubility increases

Classify each of the following events based on whether the solubility of the indicated gas will increase, decrease or stay the same the pressure of a gas over a solvent is increased

gas solubility increases

Only concentrations of

gases & substances in solution are written in equilibrium expression.

When put acid & base together,

get 2 products [salt & water]

How can you tell it's Redox when all nonmetals?

get more hydrogens or electrons = reduced

You need energy to

get reaction going [like gas & bbq]

mass/volume percent concentration % (m/v)

gives number of grams of solute as percentage of number of milliliters

At a given temperature, which of the two aqueous solutions 1.0 M glucose or 1.0 M NaCl has the higher freezing point

glucose

At a given temperature, which of the two aqueous solutions 1.0 M glucose or 1.0 M NaCl has the higher vapor pressure

glucose

Tell me about: 3H2 + N2 -> 2NH3

goes forward for while but eventually ammonia will break down if in closed container

Indicate whether the osmotic pressure of a 0.1 M NaCl solution will be less than, the same as, or greater than that of each of the following solutions. 0.050 M MgCl2

greater

Indicate whether the osmotic pressure of a 0.1 M NaCl solution will be less than, the same as, or greater than that of each of the following solutions. 0.1 M glucose

greater

The greater the concentration difference between the separated solutions,

greater magnitude of osmotic pressure.

A semipermeable membrane separates two aqueous solutions at 37 degrees Celsius. For the following case, name the solution into which a net flow of water (if any) will occur. solution A: 0.10 M NaCl (aq) solution B: 0.01 M NaCl (aq)

net flow is toward solution A

A semipermeable membrane separates two aqueous solutions at 20 degrees Celsius. Name the solution into which a net flow of water (if any will occur). Assume 100% dissociation for electrolytes, meaning ion-pairing can be ignored. solution A: 0.10 M CaCl2 (aq) solution B: 0.50 M CaCl2 (aq)

net flow is toward solution B

A semipermeable membrane separates two aqueous solutions at 37 degrees Celsius. For the following case, name the solution into which a net flow of water (if any) will occur. solution A: 0.10 M NaHCO3 (aq) solution B: 0.20 M NaHCO3 (aq)

net flow is toward solution B

When 2 solutions have different solute concentrations,

net flow of solvent will be toward more concentrated solution

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral [H^+] = 1.0 x 10^-7

neutral

The following value represents an aqueous solution at 25 degrees Celsius. Classify the solution as acidic, basic or neutral pH = 7.00

neutral

if H3O^+ is 1.0 x 10^-7 M and OH^- is 1.0 x 10^-7, type of solution is

neutral

pH = 7

neutral

[H3O+] = [OH-]

neutral solution

HCl + NaOH -> H2O + NaCl is

neutralization

H2SO4 +2KOH→K2SO4 +2H2O is an example of

neutralization reaction

HCl + NaOH → NaCl + H2O is an example of

neutralization reaction

When you put an acid & base together, they

neutralize each other & make water and salt as product

The explanation for how a beta particle is produced in the nucleus of a radionuclide and then ejected involves the conversion (in a complex series of steps) of a

neutron to a proton and a beta particle

For example: How many milliliters of a 5.75% (v/v) ethanol solution can be prepared from 2.25 mL of ethanol? How do you know which one to start with?

never start with the 5.75% v/v bc it's a conversion factor

for a solute to dissolve in a solvent, need to overcome solute-solute attractions & solvent-solvent attractions

new type of interaction forms [solute-solvent attractions]

HNO3

nitric acid

Identify whether or not the following set contains an acid-base conjugate pair HCl and ClO4^-

no

Indicate whether or not each of the following chemical reactions represents a combustion reaction. ( C + CO2 -> 2CO

no

Indicate whether or not product formation increases if the size of the reaction container is increased for each of the equilibrium systems in C2H4(g) + 3O2(g) <=> 2CO2(g) + 2H2O(g) + heat

no

Indicate whether or not product formation increases if the size of the reaction container is increased for each of the equilibrium systems in N2(g) + 2O2(g) + heat <=> 2NO2(g)

no

Indicate whether or not product formation increases if the size of the reaction container is increased for each of the equilibrium systems in heat + 2N2(g) + 6H2O(g) <=> 4NH3(g) + 3O2(g)

no

Indicate whether or not product formation increases w increasing temperature in each of the following equilibrium systems C2H4(g) + 3O2(g) <=> 2CO2(g) + 2H2O(g) + heat

no

Will the following combination make a buffer solution? H3PO4 and NaCl

no

Will the following combination make a buffer solution? HCl and KCl

no

Will the following increase the rate of reaction? cooling the reaction down to low temperatures

no

Will the following increase the rate of reaction? omitting the addition of a catalyst

no

Will the following increase the rate of reaction? using a solid, granular solid, instead of a finely powdered solid for a reactant

no

Does the following ion form a compound with Pb2+ that is soluble in water? Na^+

no [Pb^2+ and Na^+ cannot form a compound]

Identify whether or not the following set contains an acid-base conjugate pair H2CO3 and CO3^2-

no [bc differs by 2 hydrogens]

Does the following ion form a compound with Pb2+ that is soluble in water? Br^-

no [precipitates]

Does the following ion form a compound with Pb2+ that is soluble in water? SO4^2-

no [precipitates]

Which of the following solutions would have a lower freezing point than a solution containing 0.20 mole of glucose per kilogram of solvent? a. solution containing 0.10 mole of glucose per kilogram of solvent b. solution containing 0.10 mole of NaCl per kilogram of solvent c. solution containing 0.10 mole of MgCl2 per kilogram of solvent d. no correct response

solution containing 0.10 mole of MgCl2 per kilogram of solvent

what is an aqueous solution?

solution in which water is solvent

Solution vs Pure substance

solution is 2 or more components; pure substance is 1 component

what is a concentrated solution?

solution that contains large amount of solute relative to amount that could dissolve

unsaturated solution

solution that contains less than maximum amount of solute that can be dissolved under conditions at which solution exists

saturated solution

solution that contains maximum amount of solute that can be dissolved under conditions at which solution exists

what is a dilute solution?

solution that contains small amount of solute relative to amount that could dissolve

What is a hypertonic solution?

solution w higher osmotic pressure than that within cells

What is a hypotonic solution?

solution w lower osmotic pressure than that within cells

What is an isotonic solution?

solution w osmotic pressure equal to that within cells.

Osmosis is the movement of

solvent across semipermeable membrane

In dialysis & osmosis

solvents move toward areas of high concentration & solutes move toward areas of low concentration

Semipermeable means

some things go across but others can't

polarity of water [+ & - ends] suggests all ionic compounds would be soluble

sometimes ions in compound are more attracted to each other than to water molecules

for example; unstable nucleus readily undergoes change The change is

spontaneous emission of either energy or a particle

What physical manifestation indicates that an atom possesses an unstable nucleus?

spontaneous emission of radiation from nucleus of atom

In a reaction, if you

start w high energy & end w low, then exothermic reaction

What is chemical equilibrium?

state in which forward & reverse chemical reactions occur simultaneously at same rate

thick sheet of paper

stops alpha particles

aluminum [1 cm thick]

stops beta particles

lead and concrete [5 cm thick]

stops some gamma radiation]

Acid ionization constants give information about

strength of acid

100% or very nearly 100% of its protons are transferred to water

strong acid

HA + H2O <- ——> H3O^+ + A^- is showing

strong acid

Identify each of the following as a strong or weak acid or base. H2SO4

strong acid

Identify each of the following as a strong or weak acid or base. HBr

strong acid

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other HBr

strong acid

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other HNO3

strong acid

How does a buffer resist change in pH upon addition of a strong acid?

strong acid reacts w weak base in buffer to form weak acid which produces few H^+ ions in solution & therefore only little change in pH

Identify each of the following as a strong or weak acid or base. NaOH

strong base

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other Ba(OH)2

strong base

In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases or other NaOH

strong base

hydroxide bases are

strong bc ionic

Classify these compounds as strong electrolytes, weak electrolytes or nonelectrolytes HBr

strong electrolyte

Classify these compounds as strong electrolytes, weak electrolytes or nonelectrolytes Zn(NO3)2

strong electrolyte

HCl(s) + H2O(l) → H+ (aq) + Cl- (aq)

strong electrolyte

NaCl(s) + H2O(l) → Na+ (aq) + Cl- (aq)

strong electrolyte

Since salt is a

strong electrolyte, it is completely dissociated in solution

the Weaker the acid,

stronger its conjugate base

A solution with a ph of 12.0 is

strongly basic

The solvent is the

substance doing the dissolving


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