3.1.2 Carbohydrates

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What is a pentose sugar?

- A monosaccharide - Contains 5 carbon atoms - 5 carbon ring

What is a hexose sugar?

- A monosaccharide - Formed from 6 carbon atoms - 6 carbon ring

How is sucrose formed?

- Formed from a glucose molecule and a fructose molecule - Joined together by an alpha 1-4 glycosidic bond

How is lactose formed?

- Formed from a glucose molecule and a galactose molecule - Joined together by a beta 1-4 glycosidic bond

How is maltose formed?

- Formed from two glucose molecules - Joined together by an alpha 1-4 glycosidic bond

How are cellulose molecules adapted for their function in plants?

- Hydrogen bonding between chains - Chains form microfibrils - Microfibrils layered - Cell walls ... Strengthens ... Prevents cells from bursting when they take in too much water

Glycogen is formed from...

- Many a-glucose molecules - B-glucose branches

1) Describe the iodine test 2) What substances are used on the starch? 3) Why does this happen?

1) - If you put iodine on starch, the solution will turn blue/black 2) Iodine/Potassium iodide 3) - When iodine molecules fit down the middle of the helical structure of amylose... - It forms a polyiodide starch complex

1) What is the difference between how an alpha 1-4 glycosidic bond looks to how a beta 1-4 glycosidic bond looks? 2) Why?

1) - On an alpha 1-4 glycosidic bond, the 'O' faces downward - Whereas on a beta 1-4 glycosidic bond, the 'O' faces upward 2) - As the -OH group on an alpha hexose faces downward - Whereas the -OH group on a beta hexose faces upward

1) How are the glucose molecules arranged in cellulose? 2) Why do they have to be arranged in this way?

1) - Every other glucose molecule upside down - So that the OH group matches the OH group 2) As only one side of the beta glucose monosaccharide has the OH group facing up rather than down

What are the two main structural isomers of glucose?

1) Alpha glucose (a-glucose) 2) Beta glucose (b-glucose)

Give two main components of starch

1) Amylose 2) Amylopectin

Which three elements do all carbohydrates contain?

1) Carbon 2) Hydrogen 3) Oxygen

1) What type of reaction are both disaccharides and polysaccharides formed by? 2) What are happens during this type of reaction?

1) Condensation reactions 2) H₂O molecule is lost

Amylopectin structure

1) Glucose - A-glucose molecules - Alpha 1-4 glycosidic bonds 2) Chains - Branching ... Alpha 1-6 bonds

Amylose structure

1) Glucose - A-glucose molecules - Alpha 1-4 glycosidic bonds 2) Chains - Unbranched - Helical

Cellulose structure

1) Glucose - B-glucose - Beta 1-4 glycosidic bonds - Alternate glucose molecule upside down 2) Chains - Unbranched - Straight 3) Microfibrils

Give 3 hexose monosaccharides

1) Glucose 2) Fructose 3) Galactose

Starch structure

1) Glucose - A-glucose - Alpha 1-4 glycosidic bonds - All glucose molecules face upwards 2) Chains - Branching ... alpha 1-6 - Helical

Give 1 feature of glucose Give 2 uses of glucose in the body as a result of this feature

1) Highly soluble 2) Respiration 3) Main form of transporting carbohydrates around the body

1) What is the opposite of a condensation reaction? 2) What is this reaction?

1) Hydrolysis reaction 2) When H₂O is put in to break up disaccharides

Give 3 ways in which starch molecules are adapted for their function in plants

1) Large molecule - Can't leave cell 2) Helical - Compact ... Carbohydrate storage molecule 3) Insoluble - Doesn't affect water potential

Give 3 disaccharides

1) Maltose (malt sugar) 2) Sucrose (table sugar) 3) Lactose (milk sugar)

1) Polysaccharides are made up of... 2) What are polysaccharides?

1) Many monosaccharide molecules 2) Polymers

What are the three categories of carbohydrates?

1) Monosaccharides 2) Disaccharides 3) Polysaccharides

1) Carbohydrate monomers are called... 2) Carbohydrate polymers are called...

1) Monosaccharides 2) Polysaccharides

Give 2 features of galactose

1) Not as soluble as glucose 2) Plays an important role in the production of glycolipids and glycoproteins

1) Monosaccharides are made up of... 2) What are monosaccharides? 3) What is the general formula for monosaccharides?

1) One monosaccharide molecule 2) Simple sugars 3) (CH₂O)n, where n can be 3-7

Give 2 structural isomers of pentose

1) Ribose 2) Deoxyribose

Give 3 features of fructose

1) Soluble 2) Sweeter than glucose 3) Main sugar in in fruits and nectar

Give 3 main polysaccharides

1) Starch - In plants and animals 2) Cellulose - In plants 3) Glycogen - In animals

1) Glucose exists in different forms of... 2) Which are...

1) Structural isomers 2) Molecules with the same atoms, but different arrangements of atoms

Give 3 main stages of forming glycosidic bonds

1) The hydroxyl groups bind 2) Condensation reaction - H₂O molecule is lost 3) A 1-4 glycosidic bond is formed

1) Disaccharides are made up of... 2) What are disaccharides?

1) Two monosaccharide molecules 2) Double sugars

Cellulose - Uses in plants

Cell walls

Amylose and amylopectin...

Coexist in the same chain

What is the general formula for all carbohydrates?

Cx(H₂O)y

What is the formula for glucose?

C₆H₁₂O₆

What type of bond is found in a disaccharide?

Glycosidic bond

What type of bond is found in polysaccharides?

Glycosidic bonds

3 hexose sugars... 2 pentose sugars...

Hexose: ... Glucose ... Fructose ... Galactose Pentose: ... Ribose ... Deoxyribose

Give one feature of both ribose and deoxyribose

Important constituents of RNA and DNA

Give one property of both amylose and amylopectin

Insoluble

What is the test to test for the presence of starch?

Iodine test

What is starch formed from?

Many a-glucose molecules

Cellulose is formed from...

Many b-glucose molecules

Starch - Uses in plants and animals

Plants 1) Carbodydrate storage molecule - Stored as plastids ... Which are intracellular starch grains in organelles eg) Green chloroplasts in leaves eg) Colourless amyloplasts in potatoes Animals 1) Broken down into glucose for respiration 2) Source of carbon for producing other molecules

What is the difference between ribose and deoxyribose?

RIBOSE - The carbon 2 group has a hydrogen facing upwards, and an OH facing downwards DEOXYRIBOSE - The carbon 2 group has a hydrogen facing upwards, and an H facing downwards ... Deoxyribose has one less oxygen atom than ribose

What is the main difference between starch and cellulose?

Starch - Weak Cellulose - Strong

Why are polysaccharides polymers?

They are molecules made up of many repeating monomers/subunits


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