Chemistry Chapter 11 Thermochemistry

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Heat Capacity

The amount of heat required to raise the temperature of a specified amount of a substance by 1°C or 1 K.

Thermochemical Equation

a chemical equation that includes the enthalpy change

Calorimeter

a measuring instrument that determines quantities of heat

Endothermic Process

a process that absorbs heat from the surroundings

Exothermic Process

a process that releases heat to its surroundings

System

a specific portion of matter in a given region of space that has been selected for study during an experiment or observation

Chemical Potential Energy

energy stored in chemical bonds

Surroundings

everything outside the system

Hess's Law of Heat Summation

if you add two or more thermochemical equations to give a final equation, then you also add the heats of reaction to give the final heat of reaction

Joule

the SI unit of energy, 4.184 Joules = 1 calorie

Heat of Fusion

the amount of heat absorbed by one mole of a solid substance as it melts to a liquid at a constant temperature

Specific Heat Capacity

the amount of heat energy required to raise the temperature of one gram of substance by one degree celcius

Molar Heat of Solidification

the amount of heat lost by one mole of a liquid as it solidifies at a constant temperature

Molar Heat of Vaporization

the amount of heat necessary to vaporize one mole of a given liquid

Molar Heat of Condensation

the amount of heat released by one mole of a vapor as it condenses to a liquid at a constant temperature

Energy

the capacity of a physical system to do work

Standard Heat of Formation

the change in enthalpy that accompanies the formation of one mole of a compound from its elements with all substances in their standard states at 25 degrees celsius

Molar Heat of Solution

the enthalpy change caused by dissolution of one mole of substance in one liter of water.

Heat of Reaction

the enthalpy change for a chemical equation exactly as it is written

Law of Conservation of Energy

the fundamental principle of physics that the total energy of an isolated system is constant (is not created or destroyed) despite internal changes

Enthalpy (H)

the heat content of a system at constant pressure

Heat of Combustion

the heat of reaction for the complete burning of one mole of a substance

Specific Heat

the heat required to raise the temperature of one gram of a substance one degree centigrade

Heat

the movement of thermal energy from a substance at a higher temperature to one at a lower temperature

Calorimetry

the precise measurement of heat flow out of a system for chemical and physical processes

Thermochemistry

the study of the transfers of energy as heat that accompany chemical reactions and physical changes

Calorie

unit of heat defined as the quantity of heat required to raise the temperature of 1 gram of water by 1 degree centigrade at atmospheric pressure


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