MTIOC FINALS ALKANES, ALKENES, ALKYNES
Carbon Monoxide
"incomplete combustion" will also yield
Vinyl Chloride
- is used in the manufacture of floor tiles, raincoats, fabrics, furniture covers and polyvinyl chloride (PVC) a plastic
Isomerization
- rearrangement of molecular structures
mineral oil
However, mixtures of high-molecular-weight liquid alkanes, sold in drugstores under the name ______ ______, soften and moisten skin, like Petroleum jelly
dehydrogenation
Hydrogen is lost from an organic compound during
ethene
IUPAC name of ethylene
Chlorination
If the specific halogen used in the reaction of halogenation is "chlorine", the reaction
colorless, odorless, and tasteless
In any state, alkanes are ________ _______ _______organic compounds.
Halogenation of Alkanes
In this type of reaction, a "halogen" is substituted for a hydrogen atom.
Coal
It consists of a complex mixture of mostly high-molecular alicyclic, heterocyclic, saturated, unsaturated, and aromatic hydrocarbons formed from the original residues of plant matter.
meth,eth,prop,but,pent,hex,hept,oct,non,dec,undec,dodec,tridec,tetradec, pentadec,hexodec,heptadec
Recite the prefixes for 1-17
2 billion years ago
The oldest reservoir discovered up to now was formed about _____ _______ ______concurring with the existence of primitive life forms.
ethylene
The simplest alkene is
do not vomit
What you should do if you swallowed liquid alkanes
homologous series
When each member of a series differs from the next member by a CH2 group, the series is called a
Alkanes
are straight- or branched-chain hydrocarbons with only single covalent bonds between the carbon atoms
Alkenes
are unsaturated hydrocarbons that contain at least one (1) carbon-to-carbon double bond
Cracking
breaking up large molecules Alkane to form smaller ones (Alkane + Alkene).
1/Primary
carbon is bonded to one other carbon
3- Tertiary
carbon is bonded to three other carbons
4- Quaternary
carbon is bonded to three other carbons
2- Secondary
carbon is bonded to two other carbons
Kerosene
contains about C10 to C14, boiling range 200 - 275C
Fuel Oil and Diesel Fuel
contains about C14 to C18, boiling range 275 - 350C
Lubricating Oil
contains about C16 to C20, boiling higher than 350C
Gasoline
contains about C4 to C12, boiling range 20 - 200C
Liquid alkanes
dissolve these oils and cause the skin to dry out.
Alkanes
each carbon atom is joined to four other atoms by four single covalent bonds.
Cyclooctene
has been shown to exist in both cis and trans-forms.
RX
indicates a halogen atom attached to an alkyl group
SUFFIX
indicates the family of the carbon compound or the name ending of the compound.
STEM
indicates the number of carbon atoms in the "backbone" or the "parent chain" of the molecule. It answers the question: "how many carbons are present"?
Elimination Reaction
is a reaction in which a single reactant is split into two products, and one of the products is eliminated.
Substitution Reaction
is a reaction wherein one atom in a molecule is exchanged by another atom or group of atoms.
Coal
is an additional source of some hydrocarbons.
Natural Gas
is formed by the anaerobic decay of plants and animals (putrefaction).
methane
is generated from organic matter by fermentation or putrefaction.
crude oil
is mostly found in sedimentary rocks, such as limestone, sandstone and clay, which are part of ocean sediments
Vaseline
is one brand a mixture of solid and liquid hydrocarbons also used to protect skin.
Methane
is the first member of the alkane series
Propane
is the main component of liquified gas which, compressed in steel bottles, is being used as heating fuel
Halogenation
is used extensively in the manufacture of petrochemicals
X
letter that is commonly used to indicate a "halogen" atom.
methane
main component of natural gas
Trans
means two groups on opposite side
Cis
means two groups on the same side
Residue (used for greases, tars, and asphalt)
more than C20
Crude oil or petroleum
not a pure compound but a mixture of hundreds of compounds of which hydrocarbons represent the majority
cyclic
other name of alipathic
Monosubstitution
refers to a type of substitution reaction where one hydrogen atom in an organic molecule is substituted by another atom or by a group of atoms.
Methane
simplest organic compound. It is one of the gases arising from marshes
1957
the International Union of Pure and Applied Chemistry (IUPAC) came up with a systematic way of naming organic compounds known as the IUPAC System of Nomenclature.
PREFIX
the attachments to the longest continuous carbon chain or "backbone". They are the side chains or substituents. The substituents present in organic compounds are indicated by the prefix. In alkanes, the substituents or side-chains are called "alkyl group
When carbon atoms are reduced
they often form additional bonds to "hydrogen".
When carbon atoms are oxidized
they often form additional bonds to "oxygen" to form "carbon dioxide" and "water"
Geneva, Switzerland in 1892
A meeting in _______ _____ ________ initiated the development of an international system for naming compounds
Petroleum (crude oil)
A. is a thick (viscous) black liquid found underground consisting of a mixture of hundreds to thousands of different alkanes with varying amounts of sulfur-, oxygen-, and nitrogen- containing organic compounds.
insoluble
Alkanes are _____ in water
non-polar
Alkanes are non-polar or polar?
liquids
Alkanes from 6 to 17 carbons, are ______
saturated
Alkanes is saturated or unsaturated
partial oxidation of methane.
An alternate commercial preparation of alkyne is by the
increase
Both melting and boiling points of saturated hydrocarbons ________ with increasing molecular weight.
Vinyl
CH2=CH (Vinyl of allyl)
Allyl
CH2=CHCH2 (Vinyl of allyl)
oxidation-reduction reactions
Carbon like most elements can undergo ______-______ reactions
alkanes and cycloalkanes
Crude oil are mainly composed of
Alicyclic
Cycloalkanes are called
less
Each liquid alkane has a slightly different density, but all are _______ dense than water
CnH2n+2
General Formula of Alkanes
CnH2n
General Formula of Alkene
CnH2n+1
General formula for alkyl groups
CnH2n
General formula of Cycloalkanes
solid
Larger alkanes are (17 and above carbons)
lungs and skin
Liquid alkanes can cause damage to _____ and ______
gases
Low molecular weight alkanes, including cycloalkanes, up to about 5 carbons, are ______ at room temperature.
International Union of Pure and Applied Chemistry
Meaning of IUPAC
Combustible
Nearly all alkanes are?
secondary deposits
Oil reservoirs such formed represent 80% of total crude oil deposits. The areas of these deposits are called
Paraffins which means little affinity
Other name of Alkanes
olefins or vinyl compounds
Other name of Alkenes
marsh gas or biogas
Other names of methan
Alkyl halides
RX represents class of compound called?
Carbon Dioxide and Water
The "complete combustion" of alkane gives only two products: ___________ and ________
unsaturated
The Alkenes and Alkynes and even Aromatic Compounds (saturated or unsaturated)
"chemically inert" (very volatile).
The chief chemical property of alkanes (including cycloalkanes) is that they are
cycloalkanes, or cycloparaffins, or naphthenes
The first of this category of organic compounds are the cyclic, or closed-chain alkanes which are called
"burn", a property called "combustion".
The most important chemical property of alkanes is that they ________ _______ ______
Alkenes
These compounds occur abundantly in nature, and many have important biological roles.
Carbon Monoxide
a colorless, odorless, but highly poisonous gas because it strongly combines with hemoglobin and prevents the transport of oxygen to the tissues.
Addition Reaction
a reaction wherein two reactants are added together to form a single product. Addition reaction can be thought of as the "reverse" of elimination reaction.
Alkanes
aliphatic compound
top/ it floats
alkanes stay at the _____ of the water
methane
also one of the gases produced from intestinal putrefaction
not poisonous
are alkenes poisonous or not
Isoparaffins
are branched-chain alkanes.
Stereoisomers
are compounds that have the same structural formulas but different three-dimensional shapes
Alkanes
are found in nature mainly in natural gas and crude oil from which they are produced on a technical scale in large amounts by distillation and extraction
dehydrogenation, cracking, and isomerization
are of great importance in the production of motor fuels and petrochemicals
Cycloalkanes
are represented by polygons in skeletal drawings