Chemistry Final

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Starting with cyclopentene, indicate which of the following reactants would produce the product listed HO/\ a.) H2SO4 \/ \ --------> \_ _/ / HO / \ b.) H2, Pt / \ -------> \_ _/ /\ c.) Br2 / \____ Br -------> \_ _/ Cl /\ d.) HCl \/ \ -------> \_ _/ / Cl

/ \ b.) H2, Pt / \ -------> \_ _/

Which of the following is the structural formula of 1-bromo-2,2-dimethylpropane? CH3 | a.) CH3-C-CH2Br | CH3 b.) CH3-CH-CH2Br | CH3 c.) CH3-CHCH2Br-CH3 | CH2Br CH3 | d.) CH3-CH-CHBr | CH3

CH3 | a.) CH3-C-CH2Br | CH3

Select the product of the following reaction CH3 | __ CH3-CH-C=CH+2HBr --> CH3 | a.) CH3-CH-CBr=CH2 CH3 | b.) CH3-CH-CBr2-CH3 CH3 | c.) CH3-CH-CH=CHBr CH3 | d.) CH3-CH-CHBr-CH2Br

CH3 | b.) CH3-CH-CBr2-CH3

What are the products of this reaction? NH2 | + H2O <-------> /\ NH2 | a.) /\ + H2 | OH | OH b.) /\ / + H2 N H O | c.) /\ + NH3 NH3 + | d.) /\ + OH -

NH3 + | d.) /\ + OH -

Which of the following will react with Tollens' Reagent? O || a.) CH3-CH2-C-H O || b.) CH3-C-CH3 c.) |>=O OH | d.) CH3-CH-CH3

O || a.) CH3-CH2-C-H

An unkown compound undergoes no change under oxidizing conditions but reacts readily with hydrogen in the presence of a Pt catalyst. Which of the following might be this unknown compound? O || a.) CH3-CH2-CH2-C-CH3 O || b.) CH3-CH2-CH2-C-H c.) CH3-CH2-CH2-CH2-OH d.) CH3-CH2-CH2-CH=CH2

O || a.) CH3-CH2-CH2-C-CH3

What is the product of the following reaction? O || H+, heat /\ + H3C-OH ----------> OH O O || || a.) /\ / O OH O | || b.) /\ / O O || c.) /\ / O d.) /\/\ OH

O || c.) /\ / O

Oxidation of CH3CH2CH2CH2OH produces CH3CH2CH2CHO, which may be further oxidized to which of the following? a.) CH3-CH2-CH2-CH2-OH O || b.) CH3-CH2-CH2-C-OH c.) CH3-CH2-CH=CH2 d.) CH3-CH2-CH=CH-OH

O || b.) CH3-CH2-CH2-C-OH

Which of the following would you expect to have the highest boiling point? a.) /\/ || O O || b.) /\/ O || c.) /\/\ OH d.) /\/\ OH

O || c.) /\/\ OH

Which of the following compounds upon hydrolysis would yield CH3CH2OH and CH3CH2CHO? OH | a. CH3-CH2-CH-O-CH2-CH2-CH3 OH | b.) CH3-CH2-CH-O-CH2-CH3 OH | c.) CH3-CH-O-CH2-CH3 OH CH3 | | d.) CH3-CH-O-CH2-CH2

OH | b.) CH3-CH2-CH-O-CH2-CH3

Select the major product that would result from the reaction below H2SO4 CH3-CH=CH2 + H2O ---------> a.) CH3CH(OH)CH3 b.) CH3CH2CH2OH c.) CH3CH2CH3 d.) CH3CH2CH2SO4

a.) CH3CH(OH)CH3

Three physical properties shown below beside different alkane series. Which of the series is(are) listed in the order of increase (lowest to highest) for the corresponding property? a.) Density: C4H10 < C5H12 < C8H18 b.) Melting Point: C8H18 < C5H12 < C4H10 c.) Boiling Point: C5H12 < C4H10 < C8H18 d.) all are correctly ranked

a.) Density: C4H10 < C5H12 < C8H18

The following compound would be named (blank) -1, 2-dimethylcyclopropane H H | | C----------C | \ / | Ch3 C CH3 a.) cis b.) trans c.) either cis or trans d.) neither cis nor trans

a.) cis

One feature of the fluid mosaic model of membrane structure is called the a.) lipid bilayer b.) hydrophilic sheet c.) pleated sheet d.) microfilament

a.) lipid bilayer

What type of hybridization is associated with alkyne bonding? a.) sp b.) sp2 c.) sp3 d.) sp4

a.) sp

Isomers always have the same molecular formula a.) true b.) false

a.) true

Which of the following is an acetal? CH3 | a.) CH3-C-O-CH3 | CH3 b.) CH3-CH2-CH2-O-CH3 c.) HO-CH2-CH2-CH2-OH CH3 | d.) CH3-O-CH-O-CH3

b.) CH3-CH2-CH2-O-CH3

Which of the following compounds would you expect to be foul smelling? a.) CH3CH2CH2OH b.) CH3CH2CH2SH c.) CH3CH2CH2CH3 d.) CH3CH2CH2CHO

b.) CH3CH2CH2SH

What is a major difference between inorganic and organic compounds? a.) there are many more inorganic compounds than organic compounds b.) organic compounds contain carbon; few inorganic compounds do c.) organic compounds are never ionic d.) organic compounds tend to be more polar than inorganic compounds

b.) organic compounds contain carbon; few inorganic compounds do

What is the IUPAC name for the compound shown below? CH3-C=CH-CH=CH2 | CH3 a.) 2-methyl-1, 4-pentadiene b.) 2-methyl-2, 4-dipentene c.) 4-methyl-1, 3-pentadiene d.) 4-methyl-2, 4-pentadiene

c.) 4-methyl-1, 3-pentadiene

What is the IUPAC name for the compound shown below? O CH3 || | CH3-C-CH2-CH-CH3 a.) 2-methyl-2-pentanone b.) 2-methyl-4-pentanone c.) 4-methyl-2-pentanone d.) 2-methol-4-pentanol

c.) 4-methyl-2-pentanone

Which of the following correctly shows what is produced as a result of increased oxidation of carbon? a.) alcohol > alkene > ketone > aldehyde b.) alcohol > aldehyde > ketone > carboxylic acid c.) alkene > alcohol > aldehyde > carboxylic acid d.) ketone > alcohol > carboxylic acid > aldehyde

c.) alkene > alcohol > aldehyde > carboxylic acid

What is the correct IUPAC name for the compound shown? /\ CH3 / \/ \_ _/ \ OH a.) 2-ethyl-1-pentanol b.) 1-ethylpentanol c.) 1-ethylcyclopentanol d.) 2-methylcyclopentanol

d.) 2-methylcyclopentanol

How would the following structure be best classified? O || / \ / \/\=/\/\COOH \_ _/ \=\/\/\/CH3 | OH a.) sphingolipid b.) fatty acid c.) wax d.) prostaglandin

d.) prostaglandin


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