ch.3
Which of the following best describes the flow of information in eukaryotic cells? A) DNA RNA proteins B) RNA proteins DNA C) proteins DNA RNA D) RNA DNA proteins E) DNA proteins RNA
A
disaccharide & ex
A double sugar with two monosaccharides joined by dehydration synthesis, example sucrose
1:2:1 meaning
1 carbon: 2 hydrogens: 1 oxygen what all carbohydrates have
Protein structure:
1. Primary 2. Secondary 3. Tertiary 4. Quaternary
polypeptide
100-300 amino acids linked together by peptide bonds
How many structural isomers are possible for a substance having the molecular formula C4H10?
2
How many electron pairs does carbon share in order to complete its valence shell?
4
Acccronym for functional groups
All Cats Can Hide My Purple Socks
What are the functional groups?
Amino Acids, Carbonyl, Carboxyl, Hydroxy, Methyl, Phosphate, Sulfhydryl
Accronym for macromolecules
Can Lacey Play Next
Macromolecules (4)
Carbohydrates, Lipids, Proteins, Nucleic acids
types of nucleic acids?
DNA, RNA
out of all the functional groups which is nonpolaR?
Methyl
difference between monosaccharide, dissacharide, polysaccharides
Mono- 1, di-2, poly- more than 2
Carboxyl Polar or nonpolar? Acidic or basic? Hydrophilic or phobic? Found? Ex?
Polar, acidic, hydrophilic, acids(vinegar), COOH
how r some proteins (amino acids) polar and non polar?
R group
The structural level of a protein least affected by a disruption in hydrogen bonding is the A) primary level. B) secondary level. C) tertiary level. D) quaternary level. E) All structural levels are equally affected.
a
Which of the following is not a polymer? A) glucose B) starch C) cellulose D) chitin E) DNA
a
Which of the following is true of both starch and cellulose? A) They are both polymers of glucose. B) They are geometric isomers of each other. C) They can both be digested by humans. D) They are both used for energy storage in plants. E) They are both structural components of the plant cell wall.
a
monosaccharide & ex
a simple sugar that is a carbohydrate, example glucose
Misfolding of polypeptides is a serious problem in cells. Which of the following diseases are associated with an accumulation of misfolded proteins?
alhtimers, parkinsons
31) The hydrogenation of vegetable oil results in which of the following? A) saturated fats and unsaturated fats with trans double bonds B) an increased contribution to artherosclerosis C) the oil (fat) being a solid at room temperature
all
Altering which of the following levels of structural organization could change the function of a protein?
all
What is produced in secondary protein structure due to
alpha helix and beta pleated sheet due to hydrogen bonds
7) Which chemical group is most likely to be responsible for an organic molecule behaving as a base?
amino
A chemist wishes to make an organic molecule less acidic. Which of the following functional groups should be added to the molecule in order to do so?
amino
Which of the following contains nitrogen in addition to carbon, oxygen, and hydrogen
amino acid such as glycine
what do amino acids do in the primary protein structure?
amino acids combine to form polypeptides
Polysaccharides, lipids, and proteins are similar in that they
are synthesized from monomers in dehydration rxn
All of the following contain amino acids except A) hemoglobin. B) cholesterol. C) antibodies. D) enzymes. E) insulin.
b
If one strand of a DNA molecule has the sequence of bases 5ʹATTGCA3ʹ, the other complementary strand would have the sequence A) 5ʹTAACGT3ʹ. B) 3ʹTAACGT5ʹ. C) 5ʹUAACGU3ʹ. D) 3ʹUAACGU5ʹ. E) 5ʹUGCAAU3ʹ.
b
The molecular formula for glucose is C6H12O6. What would be the molecular formula for a molecule made by linking three glucose molecules together by dehydration reactions? A) C18H36O18 B) C18H30O15 C) C6H10O5 D) C18H10O15 E) C3H6O3
b
What is the structural feature that allows DNA to replicate? A) sugar-phosphate backbone B) complementary pairing of the nitrogenous bases C) disulfide bonding (bridging) of the two helixes D) twisting of the molecule to form an helix E) three-component structure of the nucleotides
b
Which of the following is a diverse group of hydrophobic molecules? A) carbohydrates B) lipids C) proteins D) nucleic acids
b
Which of the following statements about the 5ʹ end of a polynucleotide strand of DNA is correct? A) The 5ʹ end has a hydroxyl group attached to the number 5 carbon of ribose. B) The 5ʹ end has a phosphate group attached to the number 5 carbon of ribose. C) The 5ʹ end has thymine attached to the number 5 carbon of ribose. D) The 5ʹ end has a carboxyl group attached to the number 5 carbon of ribose. E) The 5ʹ end is the fifth position on one of the nitrogenous bases.
b
what is true about hydroxyl A) It lacks an asymmetric carbon, and it is probably a fat or lipid. B) It should dissolve in water. C) It should dissolve in a nonpolar solvent. D) It wonʹt form hydrogen bonds with water. E) It is hydrophobic.
b
in proteins an amino acid structure has
beta carbon= hydrogen, amino group, carboxyl group, R group
Enzymes are A) carbohydrates. B) lipids. C) proteins. D) nucleic acids.
c
Organic chemistry is a science based on the study of A) functional groups. B) vital forces interacting with matter. C) carbon compounds. D) water and its interaction with other kinds of molecules.
c
Which of the following descriptions best fits the class of molecules known as nucleotides? A) a nitrogenous base and a phosphate group B) a nitrogenous base and a pentose sugar C) a nitrogenous base, a phosphate group, and a pentose sugar D) a phosphate group and an adenine or uracil E) a pentose sugar and a purine or pyrimidine
c
A molecule with the chemical formula C6H12O6 is probably a
carbohydrate, monosaccharide, lipid
carbon atom joined to an oxygen by a double covalent bond
carbonyl group
Amino acids are acids because they always possess which functional group?
carboxyl
Which two functional groups are always found in amino acids?
carboxyl and amino
Which functional groups can act as acids?
carboxyl and phosphate
What is the term used for a protein molecule that assists in the proper folding of other proteins?
chaperonin
Which of the following polymers contain nitrogen?
chitin
The difference between the sugar in DNA and the sugar in RNA is that the sugar in DNA
contains 1 less oxygen atom
A carbon atom is most likely to form what kind of bond(s) with other atoms?
covalent
32) Which of the following is a false statement concerning amino groups? A) They are basic in pH. B) They are found in amino acids. C) They contain nitrogen. D) They are nonpolar. E) They are components of urea.
d
Which of the following hydrocarbons has a double bond in its carbon skeleton? A) C3H8 B) C2H6 C) CH4 D) C2H4 E) C2H2
d
Which of the following is an example of hydrolysis? A) the reaction of two monosaccharides, forming a disaccharide with the release of water B) the synthesis of two amino acids, forming a peptide with the release of water C) the reaction of a fat, forming glycerol and fatty acids with the release of water D) the reaction of a fat, forming glycerol and fatty acids with the utilization of water E) the synthesis of a nucleotide from a phosphate, a pentose sugar, and a nitrogenous base with the production of a molecule of water
d
Which of the following store and transmit hereditary information? A) carbohydrates B) lipids C) proteins D) nucleic acids
d
2 monomers linking together to form covalent bond, lose water is
dehydration reaction
formation of polymers?
dehydration reaction
how are dissacharides formed and make what?
dehydration reaction forming covalent bonds
What is the chemical mechanism by which cells make polymers from monomers?
dehydration rxn
monomers join to form polymers and water is released in
dehydration rxn
A strong covalent bond between amino acids that functions in maintaining a polypeptideʹs specific three-dimensional shape is a (an)
disulfide bond
The element nitrogen is present in all of the following except A) proteins. B) nucleic acids. C) amino acids. D) DNA. E) monosaccharides.
e
T/F Dehydration reactions can occur only after hydrolysis.
false
T/F Hydrolysis creates monomers, and dehydration reactions break down polymers.
false
T/F cellulose is a major structural component of animal cell plasma membranes.
false
T/F cellulose is a polymer composed of sucrose monomers.
false
T/F cellulose is a storage polysaccharide for energy in animal cells.
false
T/F cellulose is a storage polysaccharide for energy in plant cells.
false
T/F lipids are soluable in water
false
T/F saturated fats have multiple double bonds in the carbon chains of their fatty acids.
false
T/F saturated fatty acids are the predominant fatty acid in corn oil.
false
T/F saturated fatty acids are usually liquid at room temperature.
false
T/F saturated fatty acids are usually produced by plants
false
T/F saturated fatty acids have double bonds between carbon atoms of the fatty acids
false
A molecule with the formula C18H36O2 is probably a
fatty acid
alpha helix
flexible, bends on itself
sucrose, maltose, lactose are combined by
glycocidic bond
In the double helix structure of nucleic acids, cytosine hydrogen bonds to
guanine
whats non polar in proteins?
hydrocarbon R group
Which type of interaction stabilizes the alpha () helix and the beta () pleated sheet structures of proteins?
hydrogen bond
What maintains the secondary structure of a protein?
hydrogen bonds
deformation of polymers?
hydrolysis
process of breaking down polymer by using water
hydrolysis
bond of polymers are broken by water and turned into monomers in
hydrolysis rxn
whats polar in proteins?
hydroxyl R group
Which macromolecule is not a polymer?
lipids
polysaccharide & ex
long polymer chain made up of simple sugar monomers, starch of cellulose
types of carbohydrates
monosaccharide, dissacharide, polysaccharides
Methyl Polar or nonpolar? Acidic or basic? Hydrophilic or phobic? Found? Ex?
nonpolar, both, hydrophobic, CH3 (1 carbon bonded with 3 hydrogens)
Beta pleated sheet
not flexible, strong
what macromolecule stores and communicates genetic info
nucleic acids
carboxyl group reacts with amino group and releases water in dehydration run forming a _____ bond in what macromolecule
peptide bond in proteins
Which bonds are created during the formation of the primary structure of a protein?
peptide bonds
Phosphate Polar or nonpolar? Acidic or basic? Hydrophilic or phobic? Found? Ex?
polar, acidic, hydrophilic, ATP, PO4H2
Carbonyl Polar or nonpolar? Acidic or basic? Hydrophilic or phobic? Found? Ex?
polar, acidic, hydrophilic, formaldehyde, CHO
Hydroxyl Polar or nonpolar? Acidic or basic? Hydrophilic or phobic? Found? Ex?
polar, base, hydrophilic, in alcohol, OH
Amino Acids Polar or nonpolar? Acidic or basic? Hydrophilic or phobic? Found? Ex?
polar, basic, hydrophilic,ammonia, NH2
Sulfhydrl Polar or nonpolar? Acidic or basic? Hydrophilic or phobic? Found? Ex?
polar,neither, hydrophilic, rubber, SH
many identical monomers are linked together by covalent bonds
polymers
amino acids linked together is a
polypeptide
which carbohydrate is best storage of energy (starch and glycogen)
polysaccharide
which carbohydrate contains chitin
poylsaccharide
which macromolecule speeds rxns, transports substances and provides structural support
proteins
Tertiary structure
r group interactions inside one polypeptides
The bonding of two amino acid molecules to form a larger molecule requires
release of water molecule
Lipid types
saturated, unsaturated, monounsaturated, polyunsaturated
The helix and the pleated sheet are both common polypeptide forms found in which level of protein structure?
secondary
Quaternary structure
several polypeptides interacting with each other
Large organic molecules are usually assembled by polymerization of a few kinds of simple subunits. Which of the following is an exception to this statement?
steroids
Nucleic acids function
stores and communicates genetic info
Lipids function
stores energy and provides steroids
Carbohydrates function
stores energy and provides structural support
molecules with the same molecular formula have bonded together in different orders
structural isomer
67) Of the following functions, the major purpose of RNA is to
synthesis of protein
At which level of protein structure are interactions between the side chains (R groups) most important?
tertiary
unique three-dimensional shape of the fully folded polypeptide is what protein structure step
tertiary
where does the protein have functionality--finally have the ability to perform its function
tertiary structure
which level of protein structure created 3D shape
tertiary strucure
why are hydrocarbons insoluble in water
the majority of their bonds are non polar covalent carbon to hydrogen links
Why are human sex hormones considered to be lipids?
they r steroids, not soluable in water
Proteins function
transport substances, speeds reactions, structural support
a lipid made with three fatty acids and glycerol
triacglycerol
T/F carbons derived from co2
true
T/F carbons were incorporated into organic molecules by plants.
true
T/F carbons were processed into sugars through photosynthesis
true
T/F cellulose is a major structural component of plant cell walls.
true
T/F lipids are an important constituent of cell membranes
true
T/F lipids are not true polymers
true
T/F lipids contain more energy than proteins and carbohydrates.
true
T/F lipids contain waxes and steroids.
true
T/F saturated fats are more common in animals than in plants.
true
T/F saturated fats are one of several factors that contribute to atherosclerosis.
true
T/F saturated fats contain more hydrogen than saturated fats having the same number of carbon
true
T/F saturated fats generally solidify at room temperature.
true
T/F saturated fatty acids are the principal molecules in lard and butter.
true
carbohydrates philic or phobic?
very hydrophilic
A carbon skeleton is covalently bonded to both an amino group and a carboxyl group. When placed in water it
would function as both an acid and a base because R group
is protein a polymer?
yes