Chemistry Lab Midterm

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7.32 x 10^-4

0.000732

4.65 x 10^-3

0.00465

How many kilometers is 2013.5 cm?

0.020135 km 2013.5 cm x (1 x 10^-2) m/1 cm x 1km/(1X10^3) m = 0.020135 km

How many liters is 32.5 mL?

0.0325 liters 32.5 mL x (1 x 10^-3) L/ 1 mL = 0.0325 liters

A block has a mass of 4.465 g and a volume of 132.8 cm3. Calculate the density in g/cm3.

0.03362 g/cm3 d = m/v d = 4.465 g/132.8 cm3

Predict the products of hydrochloric acid reacting with zinc metal.

1. ZnCl2 2. H2 The balanced equation is: Zn + 2HCl -> ZnCl2 + H2

Identify the common indicators that a chemical reaction has occurred.

1. a color change 2. precipitate being formed 3. a change in temperature 4. bubbles being produced

Fill in the words to complete each step in liquid spill cleanup. 1. Surround the area with BLANK, then cover the spill. 2. Scoop up the material and place in a BLANK. 3. Place the bagged waste in a BLANK. 4. Wipe down the area with BLANK.

1. absorbent material 2. plastic bag 3. solid waste container 4. detergent and water

What parts are present in every chemical equation?

1. an arrow 2. at least one product 3. at least one reactant

A BLANK is a number to the left of a formula and it applies to BLANK.

1. coefficient 2. the entire formula it precedes

In the context of a balanced chemical equation, a BLANK is a number to the lower right of an element or ion within formula and it applies to BLANK.

1. subscript 2. only the part of the formula it follows

A 2.67 g piece of zinc (density = 7.14 g/mL) is added to a graduated cylinder that contains 12.13 mL H2O. What will be the final volume reading on the graduated cylinder, in mL?

12.50 v = m/d v = 2.67 g/7.14 g/mL = 0.3739 + volume of water 12.13 mL

Suppose you are titrating an acid of unknown concentration with a standardized base. At the beginning of the titration, you read the base titrant volume as 2.61 mL. After running the titration and reaching the endpoint, you read the base titrant volume as 15.17 mL. What volume, in mL, of base was required for the titration?

12.56 mL To find the volume of titrant used in any titration, subtract the starting volume reading from the final volume reading.

A graduated cylinder contains 10.00 mL water. A 14.74 g piece of aluminum is added to the water, and the volume rises to 15.46 mL. What is the density of the aluminum in g/mL?

2.70 g/mL d = m/v d = 14.74 g/5.46 mL = 2.70 g/mL

Knowing that one day is 24 hours, how many days is 66.9 hours?

2.79 days 66.9 x 1 day/24 hours = 2.79 days

Balance C2H2 + O2 -> CO2 + H2O

2C2H2 + 5O2 -> 4CO2 + 2H2O

Balance C2H6 + O2 -> CO2 + H2O

2C2H6 + 7O2 -> 4CO2 + 6H2O

Magnesium + oxygen equation

2Mg + O2 -> 2MgO(s)

A 24.5 g sample of solution has a density of 0.768 g/mL. What is the sample volume (in mL)?

31.9 mL v = m/d v = 24.5g/0.768 g/mL = 31.9 mL

How many oxygen atoms are in four unit of Ca3(PO4)2?

32 atoms 1 unit has O: 4 x 2 = 8 So, 4 units has 8 x 4 = 32

A series of measurements in the lab led to an experimental result of 32.9 mL, with a calculated standard deviation of 0.3 mL. What is the standard way to report this result?

32.9 +- 0.3 mL

In a technique to separate 3.1502 grams of a combined sample of SiO2, NH4Cl, and NaCl, none of the sample was lost. What is the percent recovery of NaCL if at the end of the separation process, 0.6215 grams of SiO2 and 1.4005 grams of NH4Cl were recovered?

35.81% original mass: 3.1502 g mass of SiO2 + NH4Cl = 0.6215 g + 1.4005 g = 2.022 g mass of NaCl = original mass - 2.022 g --> 3.1502 g - 2.022 g = 1.1282 g To find the percent recovery: % recovery of NaCl = (1.1282/3.1502) x 100% = 35.81%

Identify the section in which each type of information can be found on a Safety Data Sheet. recommended personal protective equipment (PPE)

Exposure Controls/Personal Protection

Identify the section in which each type of information can be found on a Safety Data Sheet. recommendations in case of accidental contact with the chemical

First Aid Measures

What practice will not help you make an accurate volume reading on a buret at the beginning of a titration?

Make sure that the meniscus starts exactly at 0.00 mL

After clamping a buret to a ring stand, you notice that the set-up is tippy and unstable. What should you do to stabilize the set-up?

Move the buret clamp to a ring stand with a larger base.

When sodium chloride is mixed with silver nitrate, what is or are the products?

NaCl + AgNO3 -> NaNO3 + AgCl Because NaCl + AgNO3 + - + - So, Na goes with NO3 & Ag goes with Cl.

Sodium bicarbonate + hydrochloric acid equation

NaHCO3 + HCl -> NaCl + CO2 + H2O

Most laboratory chemical spills are cleaned up in a similar manner, but acid and base spills require an extra step. What is this extra step?

Neutralize the spill before cleaning it up.

Potassium iodide + lead (II) nitrate equation

Pb(NO3)2 + KI -> PbI2 + 2KNO3

A football field is 120 yards by 53.333 yards. What is the area of the football field in acres if 1 acre=43560 ft2? Use correct significant figures when answering this question.

Solution: 1.3 Convert yards to feet: 120 yds x 3ft/1yd = 360 ft 53.333 yds x 3ft/1yd = 159.9999 ft Find the area in feet: 360 ft x 159.9999 ft = 57596.4 ft^2 Then, convert to acres: 57596.4 ft^2 x 1 acre/43560 ft^2 = 1.32223 acres Only two sig figs in 120 yards so 1.3 acres

a. funnel b. primary container c. waste label d. secondary container

Using the letters on the image, identify each component of the liquid waste set-up.

40.5 mL

What is the correct reading for the graduated cylinder in the close-up?

40.5 mL Note that volume markings increase going up the graduated cylinder. Therefore, with the meniscus above the 40 mL line, the correct volume is slightly greater than 40 mL. The bottom of the meniscus falls right in the middle of the space between the tick mark for 40 mL and 41 mL. Therefore, a good estimate of the volume is 40.5 mL.

What is the correct reading for the graduated cylinder in the close-up?

39.95 mL Note that volume markings increase going down the buret. Therefore, with the meniscus above the 40 mL line, the correct volume is less than 40 mL. The bottom of the meniscus falls right in the middle of the space between the tick mark for 39.9 mL and 40.0 mL. Therefore, a good estimate of the volume is 39.95 mL.

What is the correct reading of the volume in the pictured buret?

15.60 cm

What is the correct way to report the length of the rectangle in centimeters?

Name the compound Zn3(PO4)2

Zinc (II) Phosphate

Zinc metal + hydrochloric acid equation

Zn + HCl -> ZnCl2 + H2

Identify the precautions to take with exits in the lab. Select one or more: a) Do not block a door with an EXIT sign. b) Keep the exit door locked at all times. c) Locate the exits prior to the start of lab. d) Make sure lab windows are always open.

a) Do not block a door with an EXIT sign. c) Locate the exits prior to the start of lab.

Which types of signs are posted to convey information about chemical storage? Select one or more: a) Hazard signs such as "Flammable," "Oxidizer," and "Corrosive" b) National Fire Protection Association (NFPA) diamond c) Gas Cylinder sign d) Exit sign e) Safety equipment signs such as "Safety Shower" and "Eyewash Station"

a) Hazard signs such as "Flammable," "Oxidizer," and "Corrosive" b) National Fire Protection Association (NFPA) diamond c) Gas Cylinder sign

Which signs are typically posted in areas of active lab work? Select one or more: a) Personal protective equipment (PPE) sign b) Safety equipment signs c) Chemical storage signs d) Sign prohibiting food and drink

a) Personal protective equipment (PPE) sign b) Safety equipment signs c) Chemical storage signs d) Sign prohibiting food and drink

In general, which characteristics are necessary for a location to be suitable for chemical storage? Select one or more: a) dark b) poorly-ventilated c) dry d) cool e) warm

a) dark c) dry d) cool

Identify tools that are ideal for cleaning glassware.

brushes & detergent and water

Identify the types of information that are necessary to communicate with emergency responders. Select one or more: a) The history of safety incidents in the lab b) How the incident happened c) Any chemicals involved in an incident d) Any other hazards present in the lab

c) Any chemicals involved in an incident d) Any other hazards present in the lab

Under what conditions should a student inform the instructor of a lab injury? Select one: a) The instructor should be alerted only if the lab injury appears different from injuries the student has experienced previously. b) The instructor should be alerted only if the injury involves broken skin. c) The instructor must be informed of all laboratory injuries. d)The instructor needs to be alerted only if he or she needs to call 911.

c) The instructor must be informed of all laboratory injuries.

Name the compound CF4

carbon tetrafluoride

Potassium thiocyanate + iron (III) nitrate proof of reaction

change in color - when mixed the solution becomes dark red color and resembles fake blood

Potassium iodide + lead (II) nitrate proof of reaction

change in color and production of a precipitate (ppt); when liquids are mixed a bright yellow substance is produced

A precipitate is formed from two solutions.

chemical change

A solution heats up upon mixing with another.

chemical change

Bubbles are produced upon mixing two solutions.

chemical change

The color of a substance changes over time.

chemical change

Mixtures are characterized by two fundamental properties: 1. Each of the substances in the mixture retains its BLANK identity. 2. Mixtures are separable into these components by BLANK means.

chemical; physical

Only BLANK should be added or changed when balancing chemical equations.

coefficients

Potassium thiocyanate (KSCN) appearance

colorless liquid

hydrochloric acid appearance

colorless, liquid

What are the substances making up a mixture called?

components

Identify each described physical separation technique. A liquid is carefully poured out, leaving the solid behind in the container.

decantation

This is the process of separating a liquid from a solid (sediment) by gently pouring the liquid from the solid so as not to disturb the solid.

decantation

Name the compound N2O3

dinitrogen trioxide

How can a solid dissolved in water be separated from the water?

evaporation

Identify each described physical separation technique. A solvent is added to dissolve only one mixture component and then the liquids are separated.

extraction

Which process is used to separate soluble compounds from insoluble compounds?

extraction

Identify the safety equipment designed to deal with each emergency listed. Choices: first aid kit fire extinguisher fire blanket eyewash station safety shower chemicals in eyes

eyewash station

Identify each described physical separation technique. A solid is caught on paper or a membrane while the liquid passes through.

filtration

This is the process of separating a solid from a liquid by means of a porous material.

filtration

Identify the safety equipment designed to deal with each emergency listed. Choices: first aid kit fire extinguisher fire blanket eyewash station safety shower fire on a person

fire blanket

Identify the safety equipment designed to deal with each emergency listed. Choices: first aid kit fire extinguisher fire blanket eyewash station safety shower large fire on the benchtop

fire extinguisher

Identify the safety equipment designed to deal with each emergency listed. Choices: first aid kit fire extinguisher fire blanket eyewash station safety shower cute or minor burns

first aid kit

Magnesium Mg appearance

flat dull silver ribbon

Zinc metal + hydrochloric acid proof of reaction

gas produced - bubbles are produced in the test tube and zinc color changes and becomes darker/black

Sodium bicarbonate + hydrochloric acid proof of reaction

gas produced only

Capable of measuring a range of volumes of liquid

graduated

Which procedure cannot be performed on a hot plate, requiring a Bunsen burner instead?

heating a crucible to remove water from a hydrate

What are minor components in a mixture called?

impurities

When a vinegar and oil salad dressing separates into two layers, the oil floats on top of the vinegar. The density of the oil BLANK the density of the vinegar.

is less than

Pb(NO3)2 appearance

liquid and colorless

KI appearance

liquid and pale-yellow to colorless color

Which of the following would not be helpful in separation a mixture of sand and salt?

magnet

Most of the BLANK people encounter in everyday life consists of BLANK of different substances.

matter; mixtures

Determine the relative order of the metric prefixes of kilo-, micro-, centi-, and milli-.

micro- 10^-6 milli- 10^-3 centi- 10^-2 kilo- 10^3

BLANK are combinations of two or more substances.

mixtures

Is this an example of combustion? 2N2O5 -> 4NO2 + O2

no

Is this an example of combustion? CO2 + 4H2 -> CH4 + 2H2O

no

Iron (III) nitrate Fe(NO3)3 appearance

orange-yellow liquid

Name the compound PCl3

phosphorus trichloride

A liquid freezes into a solid.

physical change

A solid dissolves into water.

physical change

The separation of the components of a mixture is based upon the fact that each component has different BLANK properties. The components of a mixture are separated based on their BLANK properties.

physical; physical

Magnesium + oxygen proof of reaction

production of light - bright white light is produced, and Mg ribbon turns to black ash

When BLANK substances have BLANK compositions, the composition of BLANK can vary.

pure; fixed; mixtures

Identify the safety equipment designed to deal with each emergency listed. Choices: first aid kit fire extinguisher fire blanket eyewash station safety shower chemicals on clothes

safety shower

Zinc metal appearance

silver chunk, with rugged edges

Sublimation is a phase change from BLANK to BLANK. The BLANK phase is not present in this change.

solid; gas; liquid

Identify each described physical separation technique. A solid mixture is heated. One component transitions directly between solid and gas.

sublimation

press the BLANK button to cancel out mass on a balance

tare/zero

The composition of homogeneous mixtures is ______________.

uniform

The composition of heterogeneous mixtures is ______________.

variable

Designed to measure one specific volume of liquid & Used for applications in which great accuracy is needed

volumetric

Sodium bicarbonate appearance

white powdery solid

Is this an example of combustion? 2C2H6 + 7O2 -> 4CO2 + 6H2O

yes

Is this an example of combustion? 2NO + O2 -> 2NO2

yes

Is this an example of combustion? C + O2 -> CO2

yes

percent error formula

|accepted value-measured value| / accepted value x100

Changing gloves often will minimize the spread of chemicals. To properly remove gloves, first, BLANK, and then, BLANK. Then insert BLANK between the interior edge of the second glove and the skin, and remove the second glove.

1. grasp the exterior of one glove with a gloved hand 2. peel off the first glove 3. a bare finger

It is often helpful to remember the acronym PASS when using a fire extinguisher. Fill in the word that corresponds with each letter to complete the steps needed for operation of this device. 1. BLANK the pin. 2. BLANK the nozzle at the base of the fire. 3. BLANK the lever slowly. 4. BLANK the spray from side to side over the fire.

1. pull 2. aim 3. squeeze 4. sweep

When heating a solution to boiling on a hot plate, start by BLANK. Then, turn the heat to BLANK to start. If necessary, BLANK after waiting about 10 minutes without seeing boiling.

1. starting and stabilizing the stir function 2. a medium heat setting 3. turn up the heat setting

4.65 x 10^3

4650

Convert 6.5 mm to nm

6.5mm x 1m/1000mm x 10^9nm/1m = 6,500,000 nm = 6.5 x 10^6 nm

7.32 x 10^6

7320000

Zinc metal + hydrochloric acid what is the gas?

H2

Identify the section in which each type of information can be found on a Safety Data Sheet. incompatibility or reactivity with other chemicals

Handling and Storage

Identify the section in which each type of information can be found on a Safety Data Sheet. possible dangers and health effects

Hazards Identification

Identify the section in which each type of information can be found on a Safety Data Sheet. chemical name and formula

Identification

Potassium thiocyanate + iron (III) nitrate equation

KSCN + Fe(NO3)3 -> FeSCN2+


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